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Fused Polycyclic NHC Ligands in Gold Catalysis

Paul Teixeira , Stéphanie Bastin , Vincent César
Israel Journal of Chemistry, 2023, 63 (9), pp.e202200051. ⟨10.1002/ijch.202200051⟩
Article dans une revue hal-03826206v1

Buchwald–Hartwig Amination of (Hetero)Aryl Tosylates Using a Well-Defined N-Heterocyclic Carbene/Palladium(II) Precatalyst

Yin Zhang , Guy Lavigne , Vincent César
Journal of Organic Chemistry, 2015, 80 (15), pp.7666-7673. ⟨10.1021/acs.joc.5b01272⟩
Article dans une revue hal-02271027v1

Oxidative coupling of anionic abnormal N-Heterocyclic carbenes: Efficient access to Janus-type 4,4′-bis(2H-imidazol-2-ylidene)s

Alina A Grineva , Dmitry A. Valyaev , Vincent César , O. A. Filippov , Victor N. Khrustalev , et al.
Angewandte Chemie International Edition, 2018, 57 (27), pp.7986-7991. ⟨10.1002/anie.201801530⟩
Article dans une revue hal-01948415v1

Skeleton decoration of NHCs by amino groups and its sequential booster effect on the palladium-catalyzed buchwald–hartwig amination

Y. Zhang , Vincent César , G. Storch , Noël Lugan , Guy Lavigne
Angewandte Chemie International Edition, 2014, 53 (25), pp.6482-6486. ⟨10.1002/anie.201402301⟩
Article dans une revue istex hal-02023184v1
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N -Cyclopropenio-imidazol-2-ylidene: An N-heterocyclic carbene bearing an N -cationic substituent

Cécile Barthes , Carine Guyard-Duhayon , Yves Canac , Vincent César
Chemical Communications, 2020, 56 (22), pp.3305-3308. ⟨10.1039/d0cc00477d⟩
Article dans une revue hal-02542504v1

Synthesis of N-Heterocyclic Carbene Complexes

Mirko Ruamps , Guy Lavigne , Vincent César
Nolan, S. P. and Cazin, C. S. J. N-Heterocyclic Carbenes in Catalytic Organic Synthesis, 1.1.4, Georg Thieme Verlag KG, pp.47-53, 2017, Science of Synthesis, 978-3-132-01281-3
Chapitre d'ouvrage hal-02042510v1
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Cross-metathesis of technical grade methyl oleate for the synthesis of bio-based polyesters and polyamides

Paweł Krzesiński , Vincent César , Karol Grela , Sergio Santos , Pablo Ortiz
RSC Sustainability, 2023, 1 (8), pp.2033-2037. ⟨10.1039/d3su00305a⟩
Article dans une revue hal-04232441v1
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Towards ( C,C )‐cyclometalated N ‐(9‐alkylfluorenyl)NHC Ruthenium Complexes for Z ‐selective Olefin Metathesis

Katarzyna Gajda , Adrian Sytniczuk , Laure Vendier , Bartosz Trzaskowski , Noël Lugan , et al.
European Journal of Inorganic Chemistry, 2023, 26 (20), pp.e202300169. ⟨10.1002/ejic.202300169⟩
Article dans une revue hal-04155197v1
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Half-sandwich manganese complexes Cp(CO) 2 Mn(NHC) as redox-active organometallic fragments

Rémy Brousses , Vincent Maurel , Jean-Marie Mouesca , Vincent César , Noël Lugan , et al.
Dalton Transactions, 2021, 50 (40), pp.14264-14272. ⟨10.1039/D1DT02182F⟩
Article dans une revue hal-03403199v1

Tailoring Buchwald-type phosphines with pyrimidinium betaines as versatile aryl group surrogates

Ludovik Noël-Duchesneau , Noël Lugan , Guy Lavigne , A. Labande , Vincent César
Organometallics, 2014, 33 (19), pp.5085-5088. ⟨10.1021/om5007819⟩
Article dans une revue hal-02023150v1

Bidentate iminophosphorane-NHC ligand derived from the imidazo[1,5- a ]pyridin-3-ylidene scaffold

Karim Azouzi , Carine Guyard-Duhayon , Idir Benaissa , Noël Lugan , Yves Canac , et al.
Organometallics, 2018, 37 (24), pp.4726-4735. ⟨10.1021/acs.organomet.8b00733⟩
Article dans une revue hal-02128330v1
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Highly Emissive Red Heterobimetallic Ir III /M I (M I = Cu I and Au I ) Complexes for Efficient Light-Emitting Electrochemical Cells

Anna Bonfiglio , Pei-Wan Hsiao , Yin Chen , Christophe Gourlaouen , Quentin Marchand , et al.
Chemistry of Materials, 2022, 34 (4), pp.1756-1769. ⟨10.1021/acs.chemmater.1c03972⟩
Article dans une revue hal-03789493v1
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Reprogramming of a Malonic N‐Heterocyclic Carbene: A Simple Backbone Modification with Dramatic Consequences on the Ligand's Donor Properties

Vincent César , Noël Lugan , Guy Lavigne
European Journal of Inorganic Chemistry, 2010, 2010 (3), pp.361-365. ⟨10.1002/ejic.200901113⟩
Article dans une revue hal-03710153v1

The ambivalent chemistry of a free anionic N-heterocyclic carbene decorated with a malonate backbone: The plus of a negative charge

Vincent César , Stephane Labat , Karinne Miqueu , Jean-Marc Sotiropoulos , Rémy Brousses , et al.
Chemistry - A European Journal, 2013, 19 (50), pp.17113-17124. ⟨10.1002/chem.201303184⟩
Article dans une revue istex hal-00993532v1

Cationic and Neutral Rhodium( I ) Oxazolinylcarbene Complexes

Vincent César , Stéphane Bellemin-Laponnaz , Lutz H. Gade
European Journal of Inorganic Chemistry, 2004, 2004 (17), pp.3436-3444. ⟨10.1002/ejic.200400182⟩
Article dans une revue istex hal-03710310v1
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Imidazol-2-ylidene-4-olate: an anionic N-heterocyclic carbene pre-programmed for further derivatization

Laure Benhamou , Vincent César , Heinz Gornitzka , Noël Lugan , Guy Lavigne
Chemical Communications, 2009, 31, pp.4720-4722. ⟨10.1039/B907908D⟩
Article dans une revue hal-03710191v1

Chiral N-Heterocyclic Carbene-Based Ligands

Vincent César , Christophe Fliedel , Agnès Labande
Montserrat Diéguez. Chiral Ligands: Evolution of Ligand Libraries for Asymmetric Catalysis, 1, CRC Press, pp.195-232, 2021, 978-0-367-4-28488. ⟨10.1201/9780367855734-6⟩
Chapitre d'ouvrage hal-03230806v1

Décoration du squelette N-hétérocyclique d’un ligand carbénique : effets électroniques associés et application à l’optimisation d’un catalyseur au palladium

Vincent César , Guy Lavigne
L'Actualité Chimique, 2015, 392, pp.v-vi
Article dans une revue hal-01909560v1

Interplay between an elusive 4-(isopropylamino)imidazol-2-ylidene and its isolable mesoionic tautomer, and associated reactivities

Vincent César , Jean-Christophe Tourneux , Nadia Vujkovic , Rémy Brousses , Noël Lugan , et al.
Chemical Communications, 2012, 48 (17), pp.2349. ⟨10.1039/C2CC17870B⟩
Article dans une revue hal-02909453v1

Facile Derivatization of a “Chemo-active” NHC Incorporating an Enolate Backbone and Relevant Tuning of Its Electronic Properties

Laure Benhamou , Nadia Vujkovic , Vincent César , Heinz Gornitzka , Noël Lugan , et al.
Organometallics, 2010, 29 (11), pp.2616-2630. ⟨10.1021/om1003607⟩
Article dans une revue hal-03710100v1
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Electronic Tuning of a Carbene Center via Remote Chemical Induction, and Relevant Effects in Catalysis

Vincent César , Noël Lugan , Guy Lavigne
Chemistry - A European Journal, 2010, 16 (37), pp.11432-11442. ⟨10.1002/chem.201000870⟩
Article dans une revue hal-03709079v1

Buttressing effect as a key design principle towards highly efficient palladium/N-heterocyclic carbene Buchwald–Hartwig amination catalysts

Yin Zhang , Guy Lavigne , Noël Lugan , Vincent César
Chemistry - A European Journal, 2017, 23 (55), pp.13792-13801. ⟨10.1002/chem.201702859⟩
Article dans une revue hal-01938383v1

Olefin metathesis: Theory and practice. Edited by Karol Grela

Vincent César , Guy Lavigne
Angewandte Chemie International Edition, 2015, 54 (13), pp.3856-3857. ⟨10.1002/anie.201501009⟩
Article dans une revue istex hal-01909559v1

Efficient and versatile Buchwald-Hartwig amination of (hetero)aryl chlorides using the Pd-PEPPSI-IPr(NMe2)2 precatalyst in the presence of carbonate base

Yin Zhang , Vincent César , Guy Lavigne
European Journal of Organic Chemistry, 2015, 9, pp.2042-2050. ⟨10.1002/ejoc.201500030⟩
Article dans une revue istex hal-01909387v1

Experimental assessment of the π-acidity of anionic and neutral malonate-derived N-heterocyclic carbenes

Mirko Ruamps , Noël Lugan , Vincent César
European Journal of Inorganic Chemistry, 2017, 36, pp.4167-4173. ⟨10.1002/ejic.201700883⟩
Article dans une revue hal-01938381v1
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Synthetic Routes to N-Heterocyclic Carbene Precursors

Laure Benhamou , Edith Chardon , Guy Lavigne , Stéphane Bellemin-Laponnaz , Vincent César
Chemical Reviews, 2011, 111 (4), pp.2705-2733. ⟨10.1021/cr100328e⟩
Article dans une revue hal-03709046v1

Synthesis and structural chemistry of oxazolinyl-carbene copper(I) complexes

Nathanaelle Schneider , Vincent César , Stéphane Bellemin-Laponnaz , Lutz Gade
Journal of Organometallic Chemistry, 2005, 690 (24-25), pp.5556-5561. ⟨10.1016/j.jorganchem.2005.06.044⟩
Article dans une revue istex hal-02123138v1
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A Photocatalytic Approach for the Synthesis of L‐Shape Bicyclic NHC Ligands

Tanakorn Kittikool , Kunita Phakdeeyothin , Agustín A Morales , Cécile Barthes , Laure Vendier , et al.
ChemistryEurope, 2024, 2 (2), pp.e202300083. ⟨10.1002/ceur.202300083⟩
Article dans une revue hal-04522291v1

A cationic N-heterocyclic carbene containing an ammonium moiety

Mirko Ruamps , Noël Lugan , Vincent César
Organometallics, 2017, 36 (5), pp.1049-1055. ⟨10.1021/acs.organomet.7b00017⟩
Article dans une revue hal-01938379v1
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Nickel(II) complexes of highly σ-donating cyclic (alkyl)(amino)- and malonate-carbenes: Syntheses and catalytic studies

Mickaël Henrion , Bernardo De P. Cardoso , Vincent César , Michael J. Chetcuti , Vincent Ritleng
Organometallics, 2017, 36 (6), pp.1113-1121. ⟨10.1021/acs.organomet.6b00906⟩
Article dans une revue hal-01938384v1