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Study and applications of [3,3] sigmatropic rearrangement of allyl cyanates for the synthesis of molecules of biological interest.

Sylvain Henrion
Organic chemistry. Université de Rennes, 2017. English. ⟨NNT : 2017REN1S163⟩
Thèse tel-02918045v1
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Asymmetric synthesis of trans-4,5-disubstituted γ-butyrolactones involving a key allylboration step. First access to (-)-nicotlactone B and (-)-galbacin

S. Henrion , Aurélie Macé , M M Vallejos , Thierry Roisnel , B Carboni , et al.
Organic & Biomolecular Chemistry, 2018, 16 (10), pp.1672-1678. ⟨10.1039/c8ob00101d⟩
Article dans une revue hal-01744288v1
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1,3-Dioxa-[3,3]-sigmatropic Oxo-Rearrangement of Substituted Allylic Carbamates: Scope and Mechanistic Studies

Maddalen Agirre , S. Henrion , Ivan Rivilla , José Miranda , Fernando Cossío , et al.
Journal of Organic Chemistry, 2018, 83 (24), pp.14861-14881. ⟨10.1021/acs.joc.8b01320⟩
Article dans une revue hal-01954300v1

The Allyl Cyanate/Isocyanate Rearrangement: An Efficient Tool for the Stereocontrolled Formation of Allylic C–N Bonds

P.-A. Nocquet , S. Henrion , Aurélie Macé , B. Carboni , J.M. Villalgordo , et al.
European Journal of Organic Chemistry, 2017, 2017 (10), pp.1295--1307. ⟨10.1002/ejoc.201601316⟩
Article dans une revue hal-01515165v1

Stereospecific Synthesis of α-Amino Allylsilane Derivatives through a [3,3]-Allyl Cyanate Rearrangement. Mild Formation of Functionalized Disiloxanes

S. Henrion , B. Carboni , F.P. Cossio , T. Roisnel , J.M. Villalgordo , et al.
Journal of Organic Chemistry, 2016, 81 (11), pp.4633--4644. ⟨10.1021/acs.joc.6b00505⟩
Article dans une revue hal-01341576v1