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sebastien Tilloy

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Présentation

**Sébastien Tilloy** was born in 1972 in Douai (North, France). He received his Ph.D degree in 1998 from the University of Artois under the supervision of Pr E. Monflier. In 2000, he became «Maître de Conférences» at the University of Artois where he completed his Habilitation in 2004. In 2005, he spent six months as a postdoctoral position at the University of Amsterdam (Netherlands) with Pr. Piet van Leeuwen and Pr. Joost Reek. In 2006, he was promoted Professor. His research interests are centred on he cyclodextrins and more specifically on their supramolecular implications in the fields of aqueous biphasic catalysis in the presence of organometallic catalysis. These last years were devoted to better understand the behavior of cyclodextrins in these catalytic processes especially by spectroscopic studies of inclusion complexes between cyclodextrins and water-soluble phosphines and / or organometallic complexes.

Publications

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Curated dataset of association constants between a cyclodextrin and a guest for machine learning

Gökhan Tahil , Fabien Delorme , Daniel Le Berre , Éric Monflier , Adlane Sayede
Chemical Data Collections, 2023, 45, pp.101022. ⟨10.1016/j.cdc.2023.101022⟩
Article dans une revue hal-04056166v1
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Exploiting poly(ε-caprolactone) grafted from hydrohydroxymethylated sunflower oil as biodegradable coating material of water-soluble fertilizers

Abdelghani El Mouat , Taha El Assimi , Mustapha Raihane , Jérémy Ternel , Hervé Bricout
Progress in Organic Coatings, 2023, 179, pp.107513. ⟨10.1016/j.porgcoat.2023.107513⟩
Article dans une revue hal-04016601v1
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Continuous production of amines directly from alkenes via cyclodextrin-mediated hydroaminomethylation using only water as the solvent

Thomas Roth , Rebecca Evertz , Niklas Kopplin , Sébastien Tilloy , Eric Monflier
Green Chemistry, 2023, 25 (9), pp.3680-3691. ⟨10.1039/D2GC04847G⟩
Article dans une revue hal-04143472v1
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Unnatural cyclodextrins can be accessed from enzyme-mediated dynamic combinatorial libraries

Dennis Larsen , Michel Ferreira , Sébastien Tilloy , Eric Monflier , Sophie Beeren
Chemical Communications, 2022, 58 (14), pp.2287-2290. ⟨10.1039/D1CC06452E⟩
Article dans une revue hal-03625146v1
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Interesterification of triglycerides with methyl acetate for biodiesel production using a cyclodextrin-derived SnO@γ-Al2O3 composite as heterogeneous catalyst

Claudia Prestigiacomo , Martina Biondo , Alessandro Galia , Eric Monflier , Anne Ponchel
Fuel, 2022, 321, pp.124026. ⟨10.1016/j.fuel.2022.124026⟩
Article dans une revue hal-03637570v1
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Phosphorus-free nitrogen-containing catalytic systems for hydroformylation and tandem hydroformylation-based reactions

D.N. Gorbunov , M.V. Nenasheva , M.V. Terenina , Yu.S Kardasheva , E.R. Naranov
Applied Catalysis A : General, 2022, 647 (20), pp.118891. ⟨10.1016/j.apcata.2022.118891⟩
Article dans une revue hal-03829262v1
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Synthesis of Diols from Jojoba Oil via Rhodium-Catalyzed Reductive Hydroformylation: a Smart Way to Access Biobased Polyurethanes

Chryslain Becquet , Michel Ferreira , Hervé Bricout , Baptiste Quienne , Sylvain Caillol
Green Chemistry, 2022, 24 (20), pp.7906-7912. ⟨10.1039/D2GC02534E⟩
Article dans une revue hal-03820164v1
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Promising Recyclable Ionic Liquid-Soluble Catalytic System for Reductive Hydroformylation

Abdelghani El Mouat , Chryslain Becquet , Jérémy Ternel , Michel Ferreira , Hervé Bricout
ACS Sustainable Chemistry & Engineering, 2022, 10 (34), pp.11310-11319. ⟨10.1021/acssuschemeng.2c03302⟩
Article dans une revue hal-03901244v1
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Epimerization of isosorbide catalyzed by homogeneous ruthenium-phosphine complexes: A new step towards an industrial process

T. Vanbésien , T. Delaunay , V. Wiatz , S. Bigot , H. Bricout
Inorganica Chimica Acta Reviews, 2021, 515, pp.120094. ⟨10.1016/j.ica.2020.120094⟩
Article dans une revue hal-02987093v1
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Aqueous Biphasic Hydroaminomethylation Enabled by Methylated Cyclodextrins: Sensitivity Analysis for Transfer into a Continuous Process

Kai Künnemann , Dennis Weber , Chryslain Becquet , Sébastien Tilloy , Eric Monflier
ACS Sustainable Chemistry & Engineering, 2021, 9 (1), pp.273-283. ⟨10.1021/acssuschemeng.0c07125⟩
Article dans une revue hal-03107623v1
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Asymmetric hydrogenation of ethyl pyruvate over aqueous dispersed Pt nanoparticles stabilized by a cinchonidine-functionalized β-cyclodextrin

Sébastien Noël , Eleonora Caronia , Hervé Bricout , Iveta Chena Tichá , Stephane Menuel
Catalysis Communications, 2021, 150, pp.106272. ⟨10.1016/j.catcom.2020.106272⟩
Article dans une revue hal-03139645v1
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Hydrohydroxymethylation of Ethyl Ricinoleate and Castor Oil

Chryslain Becquet , François Berche , Hervé Bricout , Eric Monflier , Sébastien Tilloy
ACS Sustainable Chemistry & Engineering, 2021, 9 (28), pp.9444-9454. ⟨10.1021/acssuschemeng.1c02924⟩
Article dans une revue hal-03330271v1
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Reductive Hydroformylation of Isosorbide Diallyl Ether

Jérémy Ternel , Adrien Lopes , Mathieu Sauthier , Clothilde Buffe , Vincent Wiatz
Molecules, 2021, 26 (23), pp.7322. ⟨10.3390/molecules26237322⟩
Article dans une revue hal-03675976v1
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Rhodium-Catalyzed Aqueous Biphasic Olefin Hydroformylation Promoted by Amphiphilic Cyclodextrins

Aurélien Cocq , Hervé Bricout , Florence Djedaïni-Pilard , Sébastien Tilloy , Eric Monflier
Catalysts, 2020, 10 (1), pp.56. ⟨10.3390/catal10010056⟩
Article dans une revue hal-02429425v1
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Multiscale Structure of Starches Grafted with Hydrophobic Groups: A New Analytical Strategy

Chloé Volant , Alexandre Gilet , Fatima Beddiaf , Marion Collinet-Fressancourt , Xavier Falourd
Molecules, 2020, 25 (12), pp.2827. ⟨10.3390/molecules25122827⟩
Article dans une revue hal-02877848v1
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Continuous hydroformylation of 1-decene in an aqueous biphasic system enabled by methylated cyclodextrins

K. Künnemann , L. Schurm , D. Lange , T. Seidensticker , Sébastien Tilloy
Green Chemistry, 2020, 22 (12), pp.3809-3819. ⟨10.1039/D0GC00820F⟩
Article dans une revue hal-02881844v1
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Fréchet-type metallodendrons with N,P-iminophosphine Rh(I) complexes at the focal point: Synthesis and evaluation in the hydroformylation of 1-octene

Cody Williams , Michel Ferreira , Sébastien Tilloy , Eric Monflier , Selwyn Mapolie
Inorganica Chimica Acta Reviews, 2020, 502, pp.119341. ⟨10.1016/j.ica.2019.119341⟩
Article dans une revue hal-02429273v1
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Anionic Amphiphilic Cyclodextrins Bearing Oleic Grafts for the Stabilization of Ruthenium Nanoparticles Efficient in Aqueous Catalytic Hydrogenation

Aurélien Cocq , Bastien Léger , Sébastien Noël , Hervé Bricout , Florence Djedaini‐pilard
ChemCatChem, 2020, 12 (4), pp.1013-1018. ⟨10.1002/cctc.201901837⟩
Article dans une revue hal-02921867v1
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New Lipidyl-Cyclodextrins Obtained by Ring Opening of Methyl Oleate Epoxide Using Ball Milling

Estefania Oliva , David Mathiron , Sébastien Rigaud , Eric Monflier , Emmanuel Sevin
Biomolecules, 2020, Perspectives of Cyclodextrins, 10 (2), pp.1-18/339. ⟨10.3390/biom10020339⟩
Article dans une revue hal-02486048v1
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Synthesis of 2-Hydroxydodecyl Starch Ethers: Importance of the Purification Process

Alexandre Gilet , Claude Quettier , Vincent Wiatz , Hervé Bricout , Michel Ferreira
Industrial and engineering chemistry research, 2019, 58 (7), pp.2437-2444. ⟨10.1021/acs.iecr.8b02605⟩
Article dans une revue hal-02050369v1
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First Evidence of Cyclodextrin Inclusion Complexes in a Deep Eutectic Solvent

Tarek Moufawad , Leila Moura , Michel Ferreira , Hervé Bricout , Sébastien Tilloy
ACS Sustainable Chemistry & Engineering, 2019, 7 (6), pp.6345-6351. ⟨10.1021/acssuschemeng.9b00044⟩
Article dans une revue hal-02080174v1
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Oleic Acid Based Cyclodextrins for the Development of New Hydrosoluble Amphiphilic Compounds

Aurélien Cocq , Cyril Rousseau , Hervé Bricout , Estefanía Oliva , Véronique Bonnet
European Journal of Organic Chemistry, 2019, 2019 (6), pp.1236-1241. ⟨10.1002/ejoc.201801609⟩
Article dans une revue hal-02050385v1
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Highly Water-Soluble Amphiphilic Cyclodextrins Bearing Branched and Cyclic Oleic Grafts

Aurélien Cocq , Cyril Rousseau , Hervé Bricout , Estefanía Oliva , Véronique Bonnet
European Journal of Organic Chemistry, 2019, 2019 (30), pp.4863-4868. ⟨10.1002/ejoc.201900789⟩
Article dans une revue hal-02271385v1
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Unconventional media and technologies for starch etherification and esterification

Alexandre Gilet , Claude Quettier , Vincent Wiatz , Hervé Bricout , Michel Ferreira
Green Chemistry, 2018, 20 (6), pp.1152 - 1168. ⟨10.1039/C7GC03135A⟩
Article dans une revue hal-01738282v1
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New water-soluble Schiff base ligands based on β-cyclodextrin for aqueous biphasic hydroformylation reaction

Maxime Dauchy , Michel Ferreira , Jérôme Leblond , Hervé Bricout , Sébastien Tilloy
Pure and Applied Chemistry, 2018, 90 (5), pp.845 - 855. ⟨10.1515/pac-2017-1205⟩
Article dans une revue hal-01787217v1
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Robust Mesoporous CoMo/γ-Al2 O3 Catalysts from Cyclodextrin-Based Supramolecular Assemblies for Hydrothermal Processing of Microalgae: Effect of the Preparation Method

Rudina Bleta , Benedetto Schiavo , Natale Corsaro , Paula Costa , Alberto Giaconia
ACS Applied Materials & Interfaces, 2018, 10 (15), pp.12562 - 12579. ⟨10.1021/acsami.7b16185⟩
Article dans une revue hal-01787235v1

Transition Metal Complexes Coordinated by Water Soluble Phosphane Ligands: How Cyclodextrins Can Alter the Coordination Sphere?

Michel Ferreira , Hervé Bricout , Sébastien Tilloy , Eric Monflier
Molecules, 2017, 22 (1), pp.140. ⟨10.3390/molecules22010140⟩
Article dans une revue hal-01681336v1

Catalysis in Cyclodextrin-Based Unconventional Reaction Media: Recent Developments and Future Opportunities

Frédéric Hapiot , Stéphane Menuel , Michel Ferreira , Bastien Léger , Hervé Bricout
ACS Sustainable Chemistry & Engineering, 2017, 5 (5), pp.3598-3606. ⟨10.1021/acssuschemeng.6b02886⟩
Article dans une revue hal-01681343v1

Deep eutectic solvents as green absorbents of volatile organic pollutants

Leila Moura , Tarek Moufawad , Michel Ferreira , Hervé Bricout , Sébastien Tilloy
Environmental Chemistry Letters, 2017, 15 (4), pp.747 - 753. ⟨10.1007/s10311-017-0654-y⟩
Article dans une revue hal-01685431v1

Enhance the rheological and mechanical properties of clayey materials by adding starches

G. Alhaik , M. Ferreira , V. Dubois , E. Wirquin , Sébastien Tilloy
Construction and Building Materials, 2017, Construction and Building Materials, 139, pp.602-610. ⟨10.1016/j.conbuildmat.2016.11.130⟩
Article dans une revue hal-01688134v1

Water-soluble phosphane-substituted cyclodextrin as an effective bifunctional additive in hydroformylation of higher olefins

J. Leblond , J. Potier , S. Menuel , H. Bricout , C. Machut-Binkowski
Catalysis Science & Technology, 2017, 7 (17), pp.3823-3830. ⟨10.1039/c7cy01108c⟩
Article dans une revue hal-01681335v1

Cleavage of Benzyl Phosphonium Salts as Efficient Bypass for the Synthesis of Disulfonated Alkyldiphenylphosphanes Bearing an Oleum-Sensitive Alkyl Group

J. Denis , M. Ferreira , H. Bricout , C. Machut , S. Tilloy
European Journal of Organic Chemistry, 2016, European Journal of Organic Chemistry, 2016 (2020), pp.3322-3325. ⟨10.1002/ejoc.201600555⟩
Article dans une revue hal-01685309v1

?-cyclodextrins decrease cholesterol release and ABC-associated transporter expression in smooth muscle cells and aortic endothelial cells

C. Coisne , D. Hallier-Vanuxeem , M.-C. Boucau , J. Hachani , S. Tilloy
Frontiers in Physiology, 2016, Frontiers in Physiology, 7 (MAYMAY), ⟨10.3389/fphys.2016.00185⟩
Article dans une revue hal-01685310v1

Ring opening polymerization of $\varepsilon$-caprolactone in the presence of wet $\beta$-cyclodextrin: Effect of the operative pressure and of water molecules in the $\beta$-cyclodextrin cavity

A. Galia , O. Scialdone , T. Spanò , M.G. Valenti , B. Grignard
RSC Advances, 2016, RSC Advances, 6, pp.90290-90299. ⟨10.1039/c6ra20211j⟩
Article dans une revue hal-01688082v1
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Cyclodextrins as Emerging Therapeutic Tools in the Treatment of Cholesterol-Associated Vascular and Neurodegenerative Diseases

Caroline Coisne , Sébastien Tilloy , Eric Monflier , Daniel Wils , Laurence Fenart
Molecules, 2016, 21 (12), pp.1748. ⟨10.3390/molecules21121748⟩
Article dans une revue hal-01681349v1

Cyclodextrins Modified by Metal-Coordinating Groups for Aqueous Organometallic Catalysis: What Remains to be Done?

Sebastien Tilloy , Herve Bricout , Stephane Menuel , Frederic Hapiot , Eric Monflier
Current Organocatalysis, 2016, 3 (1), pp.24-31. ⟨10.2174/2213337202666150618192947⟩
Article dans une revue hal-01685002v1

Rhodium catalyzed hydroformylation of 1-decene in low melting mixtures based on various cyclodextrins and N,N '-dimethylurea

Michel Ferreira , Jérôme François , Hervé Bricout , Stephane Menuel , David Landy
Catalysis Communications, 2015, 63, pp.62-65. ⟨10.1016/j.catcom.2014.11.001⟩
Article dans une revue hal-01337064v1

Tetrasulfonated 1,2-Bis(diphenylphosphanyl)ethane as a Building Block for the Synthesis of Disulfonated Alkyldiphenylphosphanes

Julien Denis , Michel Ferreira , Hervé Bricout , Cécile Machut , Sébastien Tilloy
European Journal of Organic Chemistry, 2015, 2015 (25), pp.5509-5512. ⟨10.1002/ejoc.201500772⟩
Article dans une revue hal-01681341v1

Ruthenium‐containing β‐cyclodextrin polymer globules for the catalytic hydrogenation of biomass‐derived furanic compounds

R. Herbois , S. Noël , B. Léger , S. Tilloy , S. Menuel
Green Chemistry, 2015, 17 (4), pp.2444-2454. ⟨10.1039/c5gc00005j⟩
Article dans une revue hal-01664683v1

Rhodium catalyzed hydroformylation assisted by cyclodextrins in biphasic medium: Can sulfonated naphthylphosphanes lead to active, selective and recyclable catalytic species?

Maxime Elard , Julien Denis , Michel Ferreira , Hervé Bricout , David Landy
Catalysis Today, 2015, 247, pp.47-54. ⟨10.1016/j.cattod.2014.06.002⟩
Article dans une revue hal-01681344v1

Recent developments in cyclodextrin-mediated aqueous biphasic hydroformylation and tsuji-trost reactions

F. Hapiot , S. Menuel , H. Bricout , S. Tilloy , Eric Monflier
Applied Organometallic Chemistry, 2015, Applied Organometallic Chemistry, 29 (99), pp.580-587. ⟨10.1002/aoc.3340⟩
Article dans une revue hal-01685316v1

Recent breakthroughs in aqueous cyclodextrin-assisted supramolecular catalysis

F. Hapiot , H. Bricout , S. Menuel , S. Tilloy , Eric Monflier
Catalysis science and Technology, 2014, Catalysis Science and Technology, 4 (77), pp.1899-1908. ⟨10.1039/c4cy00005f⟩
Article dans une revue hal-01685322v1

Low melting mixtures based on beta-cyclodextrin derivatives and N,N '-dimethylurea as solvents for sustainable catalytic processes

Jérôme François , Michel Ferreira , Herve Bricout , Stephane Menuel , Eric Monflier
Green Chemistry, 2014, 16 (8), pp.3876-3880. ⟨10.1039/c4gc00591k⟩
Article dans une revue hal-01186732v1
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Synthesis and characterization of a new photoinduced switchable β-cyclodextrin dimer

Florian Hamon , Claire Blaszkiewicz , Marie Buchotte , Estelle Banaszak-Léonard , Hervé Bricout
Beilstein Journal of Organic Chemistry, 2014, 10, pp.2874-2885. ⟨10.3762/bjoc.10.304⟩
Article dans une revue hal-01307688v1

Diametrically Opposed Carbenes on an α-Cyclodextrin: Synthesis, Characterization of Organometallic Complexes and Suzuki-Miyaura Coupling in Ethanol and in Water

Maxime Guitet , Filipa Marcelo , Ségolène Adam De Beaumais , Yongmin Zhang , Jesús Jiménez-Barbero
European Journal of Organic Chemistry, 2013, 2013 (18), pp.3691-3699. ⟨10.1002/ejoc.201300190⟩
Article dans une revue hal-01685012v1

A cyclodextrin dimer as a supramolecular reaction platform for aqueous organometallic catalysis

Claire Blaszkiewicz , Hervé Bricout , Estelle Léonard , Christophe Len , David Landy
Chemical Communications, 2013, 49 (62), pp.6989-6991. ⟨10.1039/c3cc43647k⟩
Article dans une revue hal-01685010v1

Hydroformylation in Aqueous Biphasic Media Assisted by Molecular Receptors

F. Hapiot , H. Bricout , S. Tilloy , E. Monflier
Topics in current chemistry, 2013, 342, pp.49-78. ⟨10.1007/128_2013_431⟩
Article dans une revue hal-01712405v1

Carboxylated polymers functionalized by cyclodextrins for the stabilization of highly efficient rhodium(0) nanoparticles in aqueous phase catalytic hydrogenation

S. Noël , B. Léger , R. Herbois , A. Ponchel , S. Tilloy
Dalton Transactions, 2012, 41 (43), pp.13359-13363. ⟨10.1039/c2dt31596c⟩
Article dans une revue hal-01664688v1

Interaction of water‐soluble triphenylphosphines with $\beta$‐cyclodextrin: A quantum chemistry study

Adlane Sayede , M. Ferreira , H. Bricout , S. Tilloy , E. Monflier
Journal of Physical Organic Chemistry, 2011, Journal of Physical Organic Chemistry, 24 (1212), pp.1129-1135. ⟨10.1002/poc.1833⟩
Article dans une revue hal-01668304v1

Properties and Catalytic Activities of New Easily-Made Amphiphilic Phosphanes for Aqueous Organometallic Catalysis

Michel Ferreira , Hervé Bricout , Nathalie Azaroual , Cedric Gaillard , David Landy
Advanced Synthesis and Catalysis, 2010, 352 (7), pp.1193-1203. ⟨10.1002/adsc.201000014⟩
Article dans une revue hal-02658358v1

Biphasic Aqueous Organometallic Catalysis Promoted by Cyclodextrins: How to Design the Water‐Soluble Phenylphosphane to Avoid Interaction with Cyclodextrin

Michel Ferreira , Hervé Bricout , Adlane Sayede , Anne Ponchel , Sophie Fourmentin
Advanced Synthesis and Catalysis, 2008, 350 (4), pp.609-618. ⟨10.1002/adsc.200700582⟩
Article dans une revue hal-01667852v1

A Property‐Matched Water‐Soluble Analogue of the Benchmark Ligand PPh3

Michel Ferreira , Hervé Bricout , Frédéric Hapiot , Adlane Sayede , Sébastien Tilloy
ChemSusChem, 2008, 1 (7), pp.631-636. ⟨10.1002/cssc.200800097⟩
Article dans une revue hal-01667851v1

Methylated β-cyclodextrin as P-gp modulators for deliverance of doxorubicin across an in vitro model of blood-brain barrier

Sébastien Tilloy , Véronique Monnaert , Laurence Fenart , Hervé Bricout , Roméo Cecchelli
Bioorganic and Medicinal Chemistry Letters, 2006, 16, p. 2154-2157
Article dans une revue hal-00543357v1

Water-Soluble Triphenylphosphane-3,3',3''-tricarboxylate (m-TPPTC) Ligand and Methylated Cyclodextrins: a New Combination for Biphasic Rhodium-Catalyzed Hydroformylation of Higher Olefins

S. Tilloy , E. Genin , F. Hapiot , David Landy , Sophie Fourmentin
Advanced Synthesis and Catalysis, 2006, 348 (12-13), pp.1547-1552
Article dans une revue hal-00091904v1

Complexation of Monosulfonated Triphenylphosphine with Chemically Modified β-Cyclodextrins: Effect of Substituents on the Stability of Inclusion Complexes

Michaël Canipelle , Sébastien Tilloy , Anne Ponchel , Hervé Bricout , Eric Monflier
Journal of Inclusion Phenomena and Macrocyclic Chemistry, 2005, 51 (1-2), pp.79-85. ⟨10.1007/s10847-004-2383-7⟩
Article dans une revue hal-01681347v1

Rhodium complexes non-covalently bound to cyclodextrins: Novel water-soluble supramolecular catalysts for the biphasic hydroformylation of higher olefins

Benoît Sueur , Loïc Leclercq , Mathieu Sauthier , Yves Castanet , André Mortreux
Chemistry - A European Journal, 2005, 11, pp.6228-6236. ⟨10.1002/chem.200500337⟩
Article dans une revue hal-00107067v1

Adamantoylated monosaccharides: new compounds for modification of the properties of cyclodextrin-containing materials

Céline Binkowski , Vincent Lequart , Frédéric Hapiot , Sébastien Tilloy , Roméo Cecchelli
Carbohydrate Research, 2005, 340, p. 1461-1468
Article dans une revue hal-00542130v1

Behavior of α-, β-, and γ-cyclodextrins and their derivatives on an in vitro model of blood-brain barrier

V. Monnaert , Sébastien Tilloy , Hervé Bricout , Laurence Fenart , Roméo Cecchelli
Journal of Pharmacology and Experimental Therapeutics, 2004, 310 (2), p. 745-751
Article dans une revue hal-00537883v1

Effects of γ-and Hydroxypropyl-γ-cyclodextrins on the transport of doxorubicin across an in vitro model of blood-brain barrier

V. Monnaert , Didier Betbeder , Laurence Fenart , Hervé Bricout , Anne-Marie Lenfant
Journal of Pharmacology and Experimental Therapeutics, 2004, 311 (3), p. 1115-1120
Article dans une revue hal-00540903v1

Cyclodextrins or calixarenes: What is the best mass transfer promoter for Suzuki cross-coupling reactions in water?

F. Hapiot , J. Lyskawa , H. Bricout , S. Tilloy , Eric Monflier
Advanced Synthesis and Catalysis, 2004, Advanced Synthesis and Catalysis, 346 (11), pp.83-89
Article dans une revue hal-01681331v1

Complexation of monosulfonated triphenylphosphine oxides with β-cyclodextrin: spectroscopic study and consequence on the behaviour of cyclodextrins in aqueous-phase organometallic catalysis

M. Canipelle , L. Caron , H. Bricout , S. Tilloy , E. Monflier
New J. Chem., 2003, 27 (11), pp.1603-1608. ⟨10.1039/b304183m⟩
Article dans une revue hal-01740570v1

Unexpected Effect of Cyclodextrins on Water-Soluble Rhodium Complexes

L. Caron , M. Canipelle , S. Tilloy , H. Bricout , E. Monflier
European Journal of Inorganic Chemistry, 2003, 4, pp.595-599. ⟨10.1002/ejic.200390081⟩
Article dans une revue hal-01740569v1

Unexpected effect of cyclodextrins on water-soluble rhodium complexes

L. Caron , M. Canipelle , S. Tilloy , H. Bricout , E. Monflier
European Journal of Inorganic Chemistry, 2003, 44, pp.595-599
Article dans une revue hal-01740571v1

Theoretical Investigations of Inclusion Processes of (4-tert.-butylphenyl)(3-sulfonatophenyl)(phenyl) Phosphine in the β-Cyclodextrin

N. Blidi Boukamel , A. Krallafa , D. Bormann , L. Caron , M. Canipelle
Journal of Inclusion Phenomena and Macrocyclic Chemistry, 2002, 42 (3/4), pp.269-274. ⟨10.1023/a:1016034323453⟩
Article dans une revue hal-01740574v1

One and Two-dimensional NMR Investigations of the Inclusion of the Monosulfonated Triphenylphosphine in the β-cyclodextrin

L. Caron , C. Christine , S. Tilloy , E. Monflier , David Landy
Supramolecular Chemistry, 2002, 14 (1), pp.11-20. ⟨10.1080/10610270290006547⟩
Article dans une revue hal-01740577v1

Thermodynamic insight into the origin of the inclusion of monosulfonated isomers of triphenylphosphine into the β-cyclodextrin cavity

M. Canipelle , L. Caron , C. Christine , S. Tilloy , E. Monflier
Carbohydrate Research, 2002, 337 (3), pp.281-287. ⟨10.1016/s0008-6215(01)00308-1⟩
Article dans une revue hal-01740576v1

Phosphocontaining Cyclodextrins as a New Class of Supramolecular Structures

Mikhail K. Gratchev , Galina I. Kurochkina , Eric Monflier , Sébastien Tilloy , Herve Bricout
Phosphorus, Sulfur, and Silicon and the Related Elements, 2002, 177 (6-7), pp.1489-1492. ⟨10.1080/10426500212232⟩
Article dans une revue hal-01740572v1

Cyclodextrins as inverse phase transfer catalysts for the biphasic catalytic hydrogenation of aldehydes: A green and easy alternative to conventional mass transfer promoters

S. Tilloy , H. Bricout , E. Monflier
Green Chemistry, 2002, Green Chemistry, 4 (33), pp.188-193. ⟨10.1039/b108405b⟩
Article dans une revue hal-01740586v1

Convenient synthesis of new amphiphilic triphenylphosphine analogues for aqueous biphasic catalysis

L. Caron , M. Canipelle , S. Tilloy , H. Bricout , E. Monflier
Tetrahedron Letters, 2001, 42 (50), pp.8837-8840. ⟨10.1016/s0040-4039(01)01918-9⟩
Article dans une revue hal-01740578v1

Rhodium catalyzed hydroformylation of water insoluble olefins in the presence of chemically modified β-cyclodextrins: evidence for ligand-cyclodextrin interactions and effect of various parameters on the activity and the aldehydes selectivity

T. Mathivet , C. Méliet , Y. Castanet , A. Mortreux , L. Caron
Journal of Molecular Catalysis A: Chemical, 2001, 176 (1-2), pp.105-116. ⟨10.1016/s1381-1169(01)00229-1⟩
Article dans une revue hal-01740580v1

Study of the inclusion complexes of β-cyclodextrin with the sodium salt of trisulfonated triphenylphosphine

L. Caron , S. Tilloy , E. Monflier , J-M. Wieruszeski , G. Lippens
Journal of Inclusion Phenomena and Macrocyclic Chemistry, 2000, 38 (1-4), pp.361-379
Article dans une revue hal-01740583v1

Determination of the Association Constant between a Cyclodextrin and a Guest using Machine Learning models

Adlane Sayede , Gökhan Tahil , Fabien Delorme , Daniel Le Berre , Eric Monflier
9th Symposium on Theoretical Biophysics (TheoBio2023), Jul 2023, Cetraro, Italy
Communication dans un congrès hal-04193143v1

Use of Machine Learning for Determination of Association Constant between a Cyclodextrin and a Guest

Gökhan Tahil , Fabien Delorme , Daniel Le Berre , Eric Monflier , Adlane Sayede
7th European Conference on Cyclodextrin (EuroCD 2023), Sep 2023, Budapest (Hungary)., Hungary
Communication dans un congrès hal-04214791v1

Machine learning challenges for determination of association constant between a cyclodextrin and a guest

Gökhan Tahil , Fabien Delorme , Daniel Le Berre , Eric Monflier , Adlane Sayede
20èmes Journées Cyclodextrines, Oct 2022, Lille, France
Communication dans un congrès hal-03954803v1

Aqueous Catalytic Hydrogenation and Hydroformylation Reactions Promoted by Highly Water-Soluble Amphiphilic Cyclodextrins Bearing Oleic Grafts

Sébastien Tilloy , Aurélien Cocq , Hervé Bricout , Cyril Rousseau , Sébastien Noël
20th International Cyclodextrin Symposium, Jun 2022, Giardini Naxos, Italy
Communication dans un congrès hal-03933414v1

Determination of the Association Constant between a Cyclodextrin and a Guest using Machine Learning for Catalyzed Functionalization of Bio-Sourced Substrates

Gökhan Tahil , Fabien Delorme , Daniel Le Berre , Eric Monflier , Adlane Sayede
First international symposium on High-Throughput Catalysts Design, Jun 2021, Lille, France
Communication dans un congrès hal-03957829v1

Synthèse de dérivés urées de cyclodextrines par mécanochimie sous pression de CO2

Maxime Lestoquoy , Sébastien Tilloy , Eric Monflier , Stéphane Menuel
Journée Master, Réseau des Jeunes Chimistes – Société Chimique de France (RJSCF), Jun 2021, Villeneuve d'Ascq [en ligne], France
Communication dans un congrès hal-03957853v1

Study of encapsulation properties of amphiphilic cyclodextrins in deep eutectic solvents

Véronique Bonnet , David Landy , Adlane Sayede , Sébastien Tilloy , Eric Monflier
6th European Conference on Cyclodextrins - EUROCD 2019, Oct 2019, Saint-Jacques de Compostelle, Spain
Communication dans un congrès hal-04448813v1

Various Applications of Cyclodextrins in Organometallic Catalytic Processes

Sébastien Tilloy
Global Summit on Catalysis Research and Applications (GSCRA-2019), Mar 2019, Rome, Italy
Communication dans un congrès hal-02165263v1

«Dimères de cyclodextrines comme plateforme supramoléculaire en catalyse biphasique aqueuse»

J. Leblond , S. Menuel , T.T. Nielsen , S. Tilloy , E. Monflier
Journées Nord-Ouest Européennes des Jeunes Chercheurs (JNOEJC), 2018, 2018, Villeneuve d Ascq, France
Communication dans un congrès hal-01816697v1

«Cyclodextrins as a Versatile Tool for Organometallic Catalytic Processes»

S. Tilloy
2nd Global Conference on Catalysis, Chemical Engineering and Technology, 2018, Rome, Italy
Communication dans un congrès hal-01890952v1

«Fatty acid modified cyclodextrins as mass transfert promoters for aqueous rhodium catalyzed hydroformylation»

A. Cocq , B. Hervé , S. Tilloy , B. Léger , E. Monflier
5ème Séminaire de recherche PIVERT, 2017, Bordeaux, France
Communication dans un congrès hal-01726463v1

«Nano-réacteurs à base de cyclodextrines amphiphiles pour la catalyse et la vectorisation»

E. Oliva , D. Mathiron , V. Bonnet , S. Pillard , A. Cocq
5ème Séminaire de recherche PIVERT, 2017, Bordeaux, France
Communication dans un congrès hal-01726466v1

«Water-soluble phosphane-Substituted cyclodextrin as effective bifunctional additive in hydroformylation of higher olefins»

J. Leblond , S. Menuel , H. Bricout , C. Machut-Binkowski , David Landy
JNOEJC 2017, 2017, Caen, France
Communication dans un congrès hal-01726465v1

Solvants eutectiques profonds : un nouveau milieu pour la formation de complexes d’inclusion à base de cyclodextrines

T. Moufawad , L. Moura , S. Tilloy , M. Ferreira , H. Bricout
18èmes Journées Cyclodextrines, Nov 2017, Lens, France
Communication dans un congrès hal-01726461v1

«Biphasic aqueous hydrogenation catalyzed by ruthenium nanoparticles pormoted by fatty acid-modified cyclodextrins (FA-CDs)»

B. Léger , A. Cocq , H. Bricout , Cyril Rousseau , S. Tilloy
9th International Symposium on Nano & Supramolecular Chemistry, 2017, Naples, Italy
Communication dans un congrès hal-01699574v1

«Greffage de phosphine hydrosoluble sur cyclodextrine : synthèse et applications en hydroformylation»

J. Leblond , S. Menuel , H. Bricout , S. Tilloy , E. Monflier
18èmes Journées Cyclodextrines, 2017, Lens, France
Communication dans un congrès hal-01726456v1

«Biphasic aqueous rhodium catalyzed hydroformylation promoted by fatty acid-modified

S. Tilloy , A. Cocq , H. Bricout , Cyril Rousseau , E. Monflier
cyclodextrins» 4th International Symposium on Green Chemistry (ISGC), 2017, La Rochelle, France
Communication dans un congrès hal-01699578v1

«Novel fatty acid-modified cyclodextrins: physicochemical properties and applications in aqueous catalysis»

A. Cocq , H. Bricout , Cyril Rousseau , S. Tilloy , E. Monflier
5th European Conference on Cyclodextrin (EuroCD 2017), 2017, Lisbon, Portugal
Communication dans un congrès hal-01699570v1

«Nouveaux promoteurs de transfert de matière pour l'hydroformylation biphasique aqueuse obtenus par modification chimique de cyclodextrines à l'aide de dérivés d'acides gras»

A. Cocq , H. Bricout , Chloé Rousseau , S. Tilloy , E. Monflier
JNOEJC 2017, 2017, Caen, France
Communication dans un congrès hal-01726469v1

New Method for Volatile Organic Compounds Abatement

Sophie Fourmentin , L. Moura , T. Moufawad , M. Ferreira , H. Bricout
4th International Symposium on Green Chemistry (ISGC), May 2017, La Rochelle, France
Communication dans un congrès hal-01699579v1

«Solvents based on cyclodextrin derivatives and N,N'-dimethylurea for sustainable organometallic catalytic processes»

S. Tilloy , M. Ferreira , F. Jérôme , H. Bricout , S. Menuel
CABiomass- 2016: Catalysis Applied to Biomass, 2016, Compiègne, France
Communication dans un congrès hal-01702701v1

«Nano-réacteurs à base de cyclodextrines amphiphiles pour la catalyse et la vectorisation»

E. Oliva , D. Mathiron , V. Bonnet , S. Pilard , A. Cocq
17èmes Journées Cyclodextrines, 2016, Nancy, France
Communication dans un congrès hal-01726583v1

«Homogeneous and heterogeneous catalysts for hydrothermal liquefaction of microalgae»

B. Schiavo , S. Sau , A. Galia , R. Bleta , A. Ponchel
10th European Congress of Chemical Engineering 3rd European Congress of Applied Biotechnology 5th European Process Intensification Conference ( ECCE10+ECAB3+EPIC5), 2015, Nice, France
Communication dans un congrès hal-01702917v1

«New bulky sulfonated phosphanes for cyclodextrin assisted rhodium catalyzed hydroformylation»

J. Denis , M. Elard , M. Ferreira , H. Bricout , David Landy
JNOEJC 2015, 2015, Rouen, France
Communication dans un congrès hal-01726721v1

«Low melting mixtures based on cyclodextrin derivatives and N,N’-dimethylurea as new solvents for biphasic organometallic catalysis»

M. Ferreira , F. Jérôme , H. Bricout , S. Menuel , David Landy
4th European Conference on Cyclodextrin (EuroCD 2015), 2015, Lille, France
Communication dans un congrès hal-01702916v1

«Rheological and mechanical behaviour of earth materials / starch mixes»

G. Alhaik , M. Ferreira , V. Dubois , E. Wirquin , S. Tilloy
First International Conference on Bio-based Building Materials (ICBBM 2015), 2015, Clermont-Ferrand, France
Communication dans un congrès hal-01702926v1

«Low-melting mixtures based on N,N’-Dimethylurea/b-cyclodextrins derivatives for homogeneous biphasic catalytic processes»

M. Ferreira , F. Jérôme , H. Bricout , S. Menuel , S. Tilloy
Congrès 2015 de la Société Chimique de France - Chimie et Transition Énergétique (SCF'15), 2015, Lille, France. ⟨10.1039/C4GC00591K⟩
Communication dans un congrès hal-01726716v1

«Synthèses de résines thermoplastiques par modifications chimiques de matières premières amylacées»

A. Gilet , V. Wiatz , C. Quettier , E. Monflier , S. Tilloy
2nd Séminaire de recherche de l’Institut Français des Matériaux Agro-Sourcés (IFMAS), 2015, Lille, France
Communication dans un congrès hal-01726719v1

«Effective liquid phase hydrogenation of furan derived compounds by metallic colloids stabilized by a hydrophilic polymer of cyclodextrin»

S. Noël , B. Léger , S. Menuel , A. Ponchel , S. Tilloy
Congrès 2015 de la Société Chimique de France - Chimie et Transition Énergétique (SCF'15), 2015, Lille, France
Communication dans un congrès hal-01726715v1

«Suistainable catalytic processes in low melting mixtures based on cyclodextrin derivatives and N,N’-dimethylurea»

M. Ferreira , F. Jerome , H. Bricout , S. Menuel , E. Monflier
3rd international Symposium on Green Chemistry, 2015, La Rochelle, France
Communication dans un congrès hal-01702925v1

«Sulfonated Naphtylphosphanes: New ligands for rhodium catalyzed hydroformylation assisted by randomly methylated β-cyclodextrins»

J. Denis , M. Elard , M. Ferreira , H. Bricout , David Landy
GECOM CONCOORD, 2015, Lyon, France
Communication dans un congrès hal-01726720v1

«Deep eutectic solvents based on β-cyclodextrins derivatives for homogeneous biphasic catalytic processes»

Michel Ferreira , H. Bricout , S. Menuel , S. Tilloy , E. Monflier
16èmes Journées Cyclodextrines, 2014, Amiens, France
Communication dans un congrès hal-01727030v1

«Synthèses de résines thermoplastiques par modifications chimiques de matières premières amylacées»

A. Gilet , V. Wiatz , C. Quettier , E. Monflier , S. Tilloy
1er Séminaire de recherche de l’Institut Français des Matériaux Agro-Sourcés (IFMAS), 2014, Douai, France
Communication dans un congrès hal-01727036v1

«Hydrogenation of biomass-derived compounds catalyzed by metallic nanoparticles stabilized by cyclodextrin polymers»

S. Noël , B. Léger , A. Ponchel , S. Tilloy , G. Wenz
17th International Cyclodextrin Symposium ICS 17, 2014, Saarbrücken, Germany
Communication dans un congrès hal-01703078v1

«Effective liquid phase hydrogenation of furan derived compounds by metallic colloids stabilized by hydrophilic polymer of cyclodextrin»

B. Léger , S. Noël , A. Ponchel , S. Tilloy , B. Martel
International Green Catalysis Symposium, 2014, Rennes, France
Communication dans un congrès hal-01703083v1

«Organometallic synthesis of water-soluble ruthenium nanoparticles»

B. Léger , S. Noël , A. Ponchel , S. Tilloy , B. Martel
2014 MRS Spring Meeting & Exhibit, 2014, San Francisco (USA), Unknown Region
Communication dans un congrès hal-01703079v1

«Synthèse de nouvelles phosphines hydrosolubles par réduction de sels de phosphonium»

J. Denis , Michel Ferreira , H. Bricout , S. Tilloy , E. Monflier
Journées Nord-Ouest Européennes des Jeunes Chercheurs, 2014, Villeneuve d’Ascq, France
Communication dans un congrès hal-01727037v1

«Supramolecular Reaction Platform based on Cyclodextrin Dimer for Aqueous Organometallic Catalysis»

C. Blaszkiewicz , F. Djedaïni-Pilard , C. Len , E. Monflier , S. Tilloy
3rd European Conference on Cyclodextrins (ECC-2013), 2013, Antalya, Turkey
Communication dans un congrès hal-01703216v1

Deep eutectic solvents incorporating cyclodextrins: promising candidates for the solubilisation of organic compounds

T. Moufawad , L. Moura , S. Tilloy , M. Ferreira , H. Bricout
19th International Cyclodextrin Symposium (ICS 19), Apr 2018, Tokyo, Japan. 2018
Poster de conférence hal-01810713v1

«Diamine derivatives of isohexide through direct Ru-catalyzed amination in presence of ammonia»

T. Vanbésien , S. Tilloy , E. Monflier , H. Bricout , T. Delaunay
CATBIOR, 2017, Lyon, France. 2017
Poster de conférence hal-01727399v1

«Fatty acid modified cyclodextrins as mass transfert promoters for aqueous rhodium catalyzed hydroformylation»

A. Cocq , Hervé Bricout , S. Tilloy , B. Léger , E. Monflier
5ème Séminaire de recherche PIVERT, 2017, Bordeaux, France. 2017
Poster de conférence hal-01738697v1

«Fatty acid-modified cyclodextrins as mass transfer promoters for aqueous rhodium catalyzed hydroformylation»

A. Cocq , H. Bricout , Chloé Rousseau , E. Monflier , S. Tilloy
9th Workshop on Fats and Oils Renewable Feedstock for the Chemical Industry, 2017, Karlsruhe, Germany. 2017
Poster de conférence hal-01727401v1

«Bio-based monomers synthesis via rhodium-catalyzed poly-allyl ether hydroformylation»

A. Lopes , C. Buffe , V. Wiatz , T. Delaunay , E. Monflier
BOSS XV, 15th Belgian Organic Synthesis Symposium, 2016, Antwerp, Belgium. 2016
Poster de conférence hal-01727511v1

«Synthesis of starch esters and ethers»

A. Gilet , S. Tilloy , H. Bricout , M. Ferreira , Chloé Rousseau
Biomass Conversion : Green chemistry & Innovative Processes, 2016, Paris, France. 2016
Poster de conférence hal-01727515v1

«Transformation de poly-éthers allyliques en poly-aldéhydes via la réaction d'hydroformylation catalysée au rhodium»

A. Lopes , C. Buffe , V. Wiatz , T. Delaunay , E. Monflier
JNOEJC-2016, Journées Nord-Ouest Européennes des Jeunes Chercheurs, 2016, Villeneuve d Ascq, France. 2016
Poster de conférence hal-01739581v1

«Synthesis of starch derivatives»

A. Gilet , S. Tilloy , H. Bricout , M. Ferreira , Chloé Rousseau
JNOEJC-2016, Journées Nord-Ouest Européennes des Jeunes Chercheurs, 2016, Villeneuve d Ascq, France. 2016
Poster de conférence hal-01739582v1

«Effective liquid phase hydrogenation of furan-derived compounds by ruthenium colloids stabilized by cyclodextrin-based hydrophilic polymer»

S. Noël , B. Léger , A. Ponchel , S. Tilloy , B. Martel
CABiomass-II Catalysis Applied to Biomass Toward sustainable processes and chemicals, 2014, Compiègne, France. 2014
Poster de conférence hal-01727681v1

«Tuning of the activity and the selectivity of rhodium complexes based on cyclodextrin-phosphanes during aqueous hydroformylation reaction»

S. Tilloy , E. Monflier , H. Bricout
IGCS, 2nd International Green Catalysis Symposium and Advanced School on Green Chemistry, 2014, Rennes, France. 2014
Poster de conférence hal-01727682v1

«Catalytic hydrogenation of furfural and its derivatives by Ru(0) nanoparticles dispersed in aqueous phase in presence of cyclodextrin-based polymer»

R. Herbois , S. Noël , B. Léger , S. Tilloy , B. Martel
Journée Scientifique de Catalyse Homogène 2013, Jun 2013, Villeneuve d Ascq, France. 2013
Poster de conférence hal-01739815v1

«New cyclodextrins dimer as a mass transfer promoter for aqueous organometallic catalysis»

C. Blaszkiewicz , E. Léonard , H. Bricout , David Landy , S. Tilloy
ISGC2, 2nd International Symposium on Green Chemistry Renewable carbon and Eco-Efficient Processes, 2013, La Rochelle, France. 2013
Poster de conférence hal-01727823v1

«Catalytic hydrogenation of furfural and its derivatives by Ru(0) nanoparticles dispersed in aqueous phase in presence of cyclodextrin-based polymer»

R. Herbois , S. Noël , B. Léger , S. Tilloy , B. Martel
ISGC2, 2nd International Symposium on Green Chemistry Renewable carbon and Eco-Efficient Processes, 2013, La Rochelle, France. 2013
Poster de conférence hal-01727824v1

«Polymer-stabilized metal nanoparticles with cyclodextrins for the aqueous phase catalytic hydrogenation of furfural and derivatives»

S. Noël , B. Léger , R. Herbois , B. Martel , G. Wenz
XIth European Congress on Catalysis, 2013, Lyon, France. 2013
Poster de conférence hal-01727828v1

Phosphines Modified by Cyclodextrins for Supramolecular Catalysis in Water

Sébastien Tilloy , Eric Monflier
Piet W.N.M. van Leeuwen, Matthieu Raynal. Supramolecular Catalysis - New Directions and Developments, 1, Wiley, pp.507-518, 2022, 9783527349029. ⟨10.1002/9783527832033.ch34⟩
Chapitre d'ouvrage hal-04532058v1

«Non-conventional reaction media: Hydroformylation, Carbonylation, and Carboxylation of Alkenes»

A. Mortreux , M. Sauthier , S. Tilloy , E. Monflier
van Leeuwen, P.W.N.M. «Science of Synthesis: C-1 Building Blocks in Organic Synthesis», Georg Thieme Verlag: Stuttgart, New York KG, pp.165-192, 2014, 978-3-13-170771-0
Chapitre d'ouvrage hal-01732355v1

Rhodium-Catalyzed Hydroformylation Promoted by Modified Cyclodextrins: Current Scope and Future Developments

Frédéric Hapiot , Loïc Leclercq , Nathalie Azaroual , Sophie Fourmentin , Sébastien Tilloy
Hapiot, Frédéric and Leclercq, Loïc and Azaroual, Nathalie and Fourmentin, Sophie and Tilloy, Sébastien and Monflier, EricEditors. Advances in Organic Synthesis, BENTHAM SCIENCE PUBLISHERS, pp.36-63, 2013, 978-1-60805-602-6. ⟨10.2174/9781608054756113040004⟩
Chapitre d'ouvrage hal-01685009v1