Number of documents

43

CV Rémi Marsac


My research focuses on the fate of contaminants in the environment (heavy metals/radionuclides/emerging organic contaminants), especially their interaction with natural mineral and organic colloids under various physico-chemical conditions, taking into account the heterogeneity of adsorbing phases, contaminant competition/cooperation and redox processes. My approach combines experimentation, spectroscopy and speciation modeling.


Journal articles41 documents

  • Aleksandr Vassiliev, Nidhu Banik, Rémi Marsac, Stepan Kalmykov, Christian Marquardt. Determination of complex formation constants of neptunium(V) with propionate and lactate in 0.5–2.6 m NaCl solutions at 22–60°C using a solvent extraction technique. Radiochimica Acta, R Oldenbourg Verlag GMBH, 2019, 107 (7), pp.623-634. ⟨10.1515/ract-2019-3107⟩. ⟨insu-02270560⟩
  • Delphine Vantelon, Mélanie Davranche, Rémi Marsac, Camille La Fontaine, Hélène Guénet, et al.. Iron speciation in iron–organic matter nanoaggregates: a kinetic approach coupling Quick-EXAFS and MCR-ALS chemometrics. Environmental science‎.Nano, Royal Society of Chemistry, 2019, 6 (8), pp.2641-2651. ⟨10.1039/c9en00210c⟩. ⟨insu-02178213⟩
  • Wei Cheng, Elaheh Lotfi Kalahroodi, Remi Marsac, Khalil Hanna. Adsorption of Quinolone Antibiotics to Goethite under Seawater Conditions: Application of a Surface Complexation Model. Environmental Science & Technology, American Chemical Society, 2019, 53 (3), pp.1130-1138. ⟨10.1021/acs.est.8b04853⟩. ⟨hal-01964933⟩
  • Wei Cheng, Rémi Marsac, Khalil Hanna. Influence of magnetite stoichiometry on the binding of emerging organic contaminants. Environmental Science & Technology, American Chemical Society, 2018, 52 (2), pp.467-473. ⟨10.1021/acs.est.7b04849⟩. ⟨insu-01662350⟩
  • Nidhu Lal Banik, Rémi Marsac, Johannes Lützenkirchen, Christian Maquardt, Kathy Dardenne, et al.. Neptunium sorption and redox speciation at the illite surface under highly saline conditions. Geochimica et Cosmochimica Acta, Elsevier, 2017, 215, pp.421-431. ⟨10.1016/j.gca.2017.08.008⟩. ⟨insu-01588250⟩
  • Remi Marsac, Nidhu Lal Banika, Johannes Luetzenkirchen, Alexandre Diascorn, Kerstin Bender, et al.. Sorption and redox speciation of plutonium at the illite surface under highly saline conditions. Journal of Colloid and Interface Science, Elsevier, 2017, 485, pp.59-64. ⟨10.1016/j.jcis.2016.09.013⟩. ⟨hal-01438105⟩
  • Rémi Marsac, Florent Réal, Nidhul Lal Banik, Mathieu Pédrot, Olivier Pourret, et al.. Aqueous chemistry of Ce(IV): estimations using actinide analogues. Dalton Transactions, Royal Society of Chemistry, 2017, 46, pp.13553-13561. ⟨10.1039/C7DT02251D⟩. ⟨insu-01588240⟩
  • Rémi Marsac, Nidhu Banik, Johannes Lützenkirchen, Charlotte Catrouillet, Christian Marquardt, et al.. Modeling metal ion-humic substances complexation in highly saline conditions. Applied Geochemistry, Elsevier, 2017, 79, pp.52-64. ⟨10.1016/j.apgeochem.2017.02.004⟩. ⟨insu-01467504⟩
  • Florian Mathias Huber, Yury Totskiy, Remi Marsac, Dieter Schild, Ivan Pidchenko, et al.. Tc interaction with crystalline rock from Äspö (Sweden): Effect of in-situ rock redox capacity. Applied Geochemistry, Elsevier, 2017, 80, pp.90-101. ⟨10.1016/j.apgeochem.2017.01.026⟩. ⟨insu-01715154⟩
  • Rémi Marsac, Mathieu Pasturel, Khalil Hanna. Reduction Kinetics of Nitroaromatic Compounds by Titanium Substituted Magnetite. Journal of Physical Chemistry C, American Chemical Society, 2017, 121 (21), pp.11399-11406. ⟨10.1021/acs.jpcc.7b01920⟩. ⟨hal-01559202⟩
  • Jing Xu, Rémi Marsac, Dominique Costa, Wei Cheng, Feng Wu, et al.. Co-binding of pharmaceutical compounds at mineral surfaces: Molecular investigations of dimer formation at goethite/water interfaces. Environmental Science & Technology, American Chemical Society, 2017, 51 (15), pp.8343-8349. ⟨10.1021/acs.est.7b02835⟩. ⟨insu-01557413⟩
  • Jing Xu, Rémi Marsac, Cheng Wei, Feng Wu, Jean-François Boily, et al.. Co-binding of pharmaceutical compounds at mineral surfaces: mechanistic modeling of binding and co-binding of nalidixic acid and niflumic acid at goethite surfaces. Environmental Science & Technology, American Chemical Society, 2017, 51 (20), pp.11617-11624. ⟨10.1021/acs.est.7b02900⟩. ⟨insu-01588238⟩
  • Knapp Karin Norrfors, Remi Marsac, Muriel Bouby, Stephanie Heck, Susanna Wold, et al.. Montmorillonite colloids: II. Colloidal size dependency on radionuclide adsorption. Applied Clay Science, Elsevier, 2016, 123, pp.292-303. ⟨10.1016/j.clay.2016.01.017⟩. ⟨hal-01904318⟩
  • Nidhu L Banik, Valérie Vallet, Florent Réal, Réda Belmecheri, Bernd Schimmelpfennig, et al.. First structural characterization of Pa(IV) in aqueous solution and quantum chemical investigations of the tetravalent actinides up to Bk(IV): the evidence of a curium break. Dalton Transactions, Royal Society of Chemistry, 2016, 45, pp.453. ⟨10.1039/c5dt03560k⟩. ⟨hal-01213903⟩
  • Remi Marsac, Sébastien Martin, Jean-François Boily, Khalil Hanna. Oxolinic Acid Binding at Goethite and Akaganeite Surfaces: Experimental Study and Modeling. Environmental Science & Technology, American Chemical Society, 2016, 50 (2), pp.660-668. ⟨10.1021/acs.est.5b04940⟩. ⟨hal-01904132⟩
  • Nidhu Lal Banik, Remi Marsac, Johannes Lützenkirchen, Alexandre Diascorn, Kerstin Bender, et al.. Sorption and Redox Speciation of Plutonium at the Illite Surface. Environmental Science & Technology, American Chemical Society, 2016, 50 (4), pp.2092 - 2098. ⟨10.1021/acs.est.5b05129⟩. ⟨hal-01904367⟩
  • Knapp Karin Norrfors, Muriel Bouby, Stephanie Heck, Nicolas Finck, Remi Marsac, et al.. Montmorillonite colloids: I. Characterization and stability of dispersions with different size fractions. Applied Clay Science, Elsevier, 2015, 114, pp.179 - 189. ⟨10.1016/j.clay.2015.05.028⟩. ⟨hal-01904321⟩
  • Remi Marsac, Nidhu Banik, Johannes Lützenkirchen, Christian Marquardt, Kathy Dardenne, et al.. Neptunium redox speciation at the illite surface. Geochimica et Cosmochimica Acta, Elsevier, 2015, 152, pp.39 - 51. ⟨10.1016/j.gca.2014.12.021⟩. ⟨hal-01904147⟩
  • Andreas Schnurr, Remi Marsac, Thomas Rabung, Johannes Lützenkirchen, Horst Geckeis. Sorption of Cm(III) and Eu(III) onto clay minerals under saline conditions: Batch adsorption, laser-fluorescence spectroscopy and modeling. Geochimica et Cosmochimica Acta, Elsevier, 2015, 151, pp.192 - 202. ⟨10.1016/j.gca.2014.11.011⟩. ⟨hal-01904333⟩
  • Carl-Heinrich Graser, Nidhu Lal Banik, Kerstin Anne Bender, Markus Lagos, Christian Michael Marquardt, et al.. Sensitive Redox Speciation of Iron, Neptunium, and Plutonium by Capillary Electrophoresis Hyphenated to Inductively Coupled Plasma Sector Field Mass Spectrometry. Analytical Chemistry, American Chemical Society, 2015, 87 (19), pp.9786 - 9794. ⟨10.1021/acs.analchem.5b02051⟩. ⟨hal-01904326⟩
  • Remi Marsac, Nidhu Banik, Johannes Lützenkirchen, Razvan Buda, Jens Kratz, et al.. Modeling plutonium sorption to kaolinite: Accounting for redox equilibria and the stability of surface species. Chemical Geology, Elsevier, 2015, 400, pp.1 - 10. ⟨10.1016/j.chemgeo.2015.02.006⟩. ⟨hal-01904144⟩
  • Remi Marsac, Mélanie Davranche, Nicolas Briant, Guillaume Morin, Yoshio Takahashi, et al.. Effect of loading on the nature of the REE–humate complexes as determined by Yb3+ and Sm3+ LIII-edge EXAFS analysis. Chemical Geology, Elsevier, 2015, 396, pp.218-227. ⟨10.1016/j.chemgeo.2014.12.024⟩. ⟨insu-01111992⟩
  • Aline Dia, Béatrice Lauga, Mélanie Davranche, Anne Fahy, Robert Duran, et al.. Bacteria-mediated reduction of As(V)-doped lepidocrocite in a flooded soil sample. Chemical Geology, Elsevier, 2015, 406, pp.34-44. ⟨10.1016/j.chemgeo.2015.04.008⟩. ⟨insu-01145497⟩
  • Charlotte Catrouillet, Mélanie Davranche, Aline Dia, Martine Bouhnik-Le Coz, Mathieu Pédrot, et al.. Thiol groups controls on arsenite binding by organic matter: New experimental and modeling evidence. Journal of Colloid and Interface Science, Elsevier, 2015, 460, pp.310-320. ⟨10.1016/j.jcis.2015.08.045⟩. ⟨insu-01187067⟩
  • Aleksandr Vasiliev, Nidhu Banik, Remi Marsac, Daniel Froehlich, Jörg Rothe, et al.. Np(V) complexation with propionate in 0.5–4 M NaCl solutions at 20–85 °C. Dalton Transactions, Royal Society of Chemistry, 2015, 44 (8), pp.3837 - 3844. ⟨10.1039/C4DT03688C⟩. ⟨hal-01904329⟩
  • Mélanie Davranche, Gérard Gruau, Aline Dia, Remi Marsac, Mathieu Pédrot, et al.. Biogeochemical factors affecting rare earth element distribution in shallow wetland groundwater. Aquatic Geochemistry, Springer Verlag, 2015, 21 (2-4), pp.197-215. ⟨10.1007/s10498-014-9247-6⟩. ⟨insu-01117200⟩
  • Johannes Lützenkirchen, Remi Marsac, Dmitrii Kulik, Timothy Payne, Zhengrong Xue, et al.. Treatment of multi-dentate surface complexes and diffuse layer implementation in various speciation codes. Applied Geochemistry, Elsevier, 2015, 55, pp.128 - 137. ⟨10.1016/j.apgeochem.2014.07.006⟩. ⟨hal-01904344⟩
  • Mélanie Davranche, Gérard Gruau, Aline Dia, Rémi Marsac, Mathieu Pédrot, et al.. Biogeochemical factors affecting rare earth element distribution in shallow wetland groundwater. Aquatic Geochemistry, Springer Verlag, 2015, 21 (2-4), pp.197-215. ⟨10.1007/s10498-014-9247-6⟩. ⟨hal-02265582⟩
  • Johannes Lützenkirchen, Remi Marsac, William Casey, Gerhard Furrer, Tom Kupcik, et al.. The Effect of Monovalent Electrolytes on the Deprotonation of MAl12 Keggin Ions. Aquatic Geochemistry, Springer Verlag, 2015, 21 (2-4), pp.81 - 97. ⟨10.1007/s10498-014-9250-y⟩. ⟨hal-01904336⟩
  • Remi Marsac, Nidhu Lal Banik, Christian Marquardt, Jens Volker Kratz. Stabilization of polynuclear plutonium(IV) species by humic acid. Geochimica et Cosmochimica Acta, Elsevier, 2014, 131, pp.290 - 300. ⟨10.1016/j.gca.2014.01.039⟩. ⟨hal-01904152⟩
  • Johannes Lützenkirchen, Ahmed Abdelmonem, Rohan Weerasooriya, Frank Heberling, Volker Metz, et al.. Adsorption of dissolved aluminum on sapphire-c and kaolinite: implications for points of zero charge of clay minerals. Geochemical Transactions, Chemistry Central, 2014, 15 (1), ⟨10.1186/1467-4866-15-9⟩. ⟨hal-01904356⟩
  • Charlotte Catrouillet, Mélanie Davranche, Aline Dia, Martine Bouhnik-Le Coz, Remi Marsac, et al.. Geochemical modeling of Fe(II) binding to humic and fulvic acids. Chemical Geology, Elsevier, 2014, 372, pp.109-118. ⟨10.1016/j.chemgeo.2014.02.019⟩. ⟨insu-00965127⟩
  • Remi Marsac, Mélanie Davranche, Gérard Gruau, Aline Dia, Mathieu Pédrot, et al.. Effects of Fe competition on REE binding to humic acid: Origin of REE pattern variability in organic waters. Chemical Geology, Elsevier, 2013, 342, pp.119-127. ⟨10.1016/j.chemgeo.2013.01.020⟩. ⟨insu-00811470⟩
  • M Denecke, T Petersmann, Remi Marsac, K Dardenne, T. Vitova, et al.. XANES characterization of UO 2 /Mo(Pd) thin films as models for ϵ-particles in spent nuclear fuel. Journal of Physics: Conference Series, IOP Publishing, 2013, 430, ⟨10.1088/1742-6596/430/1/012113⟩. ⟨hal-01904360⟩
  • Patric Lindqvist-Reis, Christos Apostolidis, Olaf Walter, Remi Marsac, Nidhu Lal Banik, et al.. Structure and spectroscopy of hydrated neptunyl(VI) nitrate complexes. Dalton Transactions, Royal Society of Chemistry, 2013, 42 (43), pp.15275. ⟨hal-01964937⟩
  • Remi Marsac, Mélanie Davranche, Gérard Gruau, Aline Dia, Martine Bouhnik-Le Coz. Aluminium competitive effect on rare earth elements binding to humic acid. Geochimica et Cosmochimica Acta, Elsevier, 2012, 89, pp.1-9. ⟨10.1016/j.gca.2012.04.028⟩. ⟨hal-01904157⟩
  • Remi Marsac, Mélanie Davranche, Gérard Gruau, Martine Bouhnik-Le Coz, Aline Dia. An improved description of the interactions between rare earth elements and humic acids by modeling: PHREEQC-Model VI coupling. Geochimica et Cosmochimica Acta, Elsevier, 2011, 75 (19), pp.5625 - 5637. ⟨10.1016/j.gca.2011.07.009⟩. ⟨hal-01904313⟩
  • Mélanie Davranche, Malagorzata Grybos, Gérard Gruau, Mathieu Pédrot, Aline Dia, et al.. Rare earth element patterns: A tool for identifying trace metal sources during wetland soil reduction. Chemical Geology, Elsevier, 2011, 284 (1-2), pp.127-137. ⟨10.1016/j.chemgeo.2011.02.014⟩. ⟨insu-00611782⟩
  • Remi Marsac, Mélanie Davranche, Gérard Gruau, Aline Dia. Metal loading effect on rare earth element binding to humic acid: Experimental and modelling evidence. Geochimica et Cosmochimica Acta, Elsevier, 2010, 74 (6), pp.1749 - 1761. ⟨10.1016/j.gca.2009.12.006⟩. ⟨hal-01904314⟩
  • Jean-Marc Noël, Béatrice Sjöberg, Remi Marsac, Dodzi Zigah, Jean-François Bergamini, et al.. Flexible Strategy for Immobilizing Redox-Active Compounds Using in Situ Generation of Diazonium Salts. Investigations of the Blocking and Catalytic Properties of the Layers. Langmuir, American Chemical Society, 2009, 25 (21), pp.12742 - 12749. ⟨10.1021/la901765e⟩. ⟨hal-01904363⟩
  • Jean-Marc Noël, Béatrice Sjöberg, Remi Marsac, Dodzi Zigah, Jean-François Bergamini, et al.. Flexible strategy for immobilizing redox-active compounds using in situ generation of diazonium salts. Investigations of the blocking and catalytic properties of the layers. Langmuir, American Chemical Society, 2009, 25 (21), pp.12742-12749. ⟨American Chemical Society⟩. ⟨10.1021/1a901765e⟩. ⟨hal-00428950⟩

Theses1 document

  • Remi Marsac. Contrôle de la spéciation des terres rares par les acides humiques : rôle de l'hétérogénéité des sites de complexation et de la compétition entre cations. Géochimie. Université Rennes 1, 2011. Français. ⟨tel-00674929⟩

Habilitation à diriger des recherches1 document

  • Remi Marsac. Impact des colloïdes organiques et minéraux sur la dynamique des contaminants dans l'environnement. Géochimie. Université de Rennes 1, 2017. ⟨tel-01863419⟩