Keywords

Zinc Lithium Heterocycle Deprotometalation Sensitizers Solar cells Pigments Palladium Ruthenium Chirality Dyes Iron Iron complexes DFT ALDEHYDES ABSOLUTE-CONFIGURATION Metalation Bimetallic bases Photophysics Copper
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Number of documents

53

Dr Philippe C. GROS, CNRS Research Director

Head of the L2CM (Laboratoire Lorrain de Chimie Moléculaire) UMR7053 (CNRS/Université de Lorraine)  

 

Short biography

Philippe C. Gros studied chemistry at the Universite of Lyon (Lyon, France) and obtained his Ph.D. in 1992 with Dr Pierre Leperchec. He then worked for two years as a postdoctoral fellow with the Isochem Company on phosgenederivative chemistry. In 1994 he entered the CNRS as “Chargé de Recherches” in the Laboratory of Pr. Paul Caubère at Nancy-Université(Lorraine, France). He received his Habilitation (HDR) in 2000 and was appointed “Directeur de Recherches” in 2006. His current research interests include the design of new metalating agents (organolithiums, ate complexes) for the regio- and enantioselective functionalization of heterocycles, structural and reaction mechanism investigation, transition-metal-catalyzed cross-couplings for ligands ynthesis, and the building of photo- and electroactive organometallic materials for various applications including solar energy. He has published more than 110 international peer reviewed papers.

Journal articles49 documents

  • Antonio Francés-Monerris, Philippe Gros, Xavier Assfeld, Antonio Monari, Mariachiara Pastore. Toward luminescent iron complexes: unraveling the photophysics by computing potential energy surfaces. ChemPhotoChem, ChemPubSoc Europe, 2019, ⟨10.1002/cptc.201900100⟩. ⟨hal-02152159⟩
  • Madani Hedidi, Dayaker Gandrath, Yu Kitazawa, Yoshii Tatsuya, Mutsumi Kimura, et al.. Enantioselective deprotometalation of N,N-dialkyl ferrocenecarboxamides using metal amides. New Journal of Chemistry, Royal Society of Chemistry, 2019, ⟨10.1039/c9nj03780b⟩. ⟨hal-02277472⟩
  • Antonio Francés-Monerris, Philippe Gros, Mariachiara Pastore, Xavier Assfeld, Antonio Monari. Photophysical properties of bichromophoric Fe(II) complexes bearing an aromatic electron acceptor. Theoretical Chemistry Accounts: Theory, Computation, and Modeling, Springer Verlag, 2019, 138 (7), ⟨10.1007/s00214-019-2471-9⟩. ⟨hal-02152160⟩
  • Kevin Magra, Edoardo Domenichini, Antonio Francés-Monerris, Cristina Cebrian, Marc Beley, et al.. Impact of the fac / mer Isomerism on the Excited-State Dynamics of Pyridyl-carbene Fe(II) Complexes. Inorganic Chemistry, American Chemical Society, 2019, ⟨10.1021/acs.inorgchem.9b00138⟩. ⟨hal-02099506⟩
  • Philippe Pierrat, Cristina Cebrian, Marc Beley, Philippe Gros, Ivan Torres-Moya, et al.. Synthesis and properties of new multiple TCNE-adducts from dialkynyl-N-(het)arylpyrroles.. European Journal of Organic Chemistry, Wiley-VCH Verlag, 2019, ⟨10.1002/ejoc.201900447⟩. ⟨hal-02152157⟩
  • Mohamed Darari, Edoardo Domenichini, Antonio Francés-Monerris, Cristina Cebrian, Kevin Magra, et al.. Iron( ii ) complexes with diazinyl-NHC ligands: impact of π-deficiency of the azine core on photophysical properties. Dalton Transactions, Royal Society of Chemistry, 2019, ⟨10.1039/c9dt01731c⟩. ⟨hal-02145893⟩
  • Antonio Francés-Monerris, Kevin Magra, Mohamed Darari, Cristina Cebrian, Marc Beley, et al.. Synthesis and Computational Study of a Pyridylcarbene Fe(II) Complex: Unexpected Effects of fac / mer Isomerism in Metal-to-Ligand Triplet Potential Energy Surfaces. Inorganic Chemistry, American Chemical Society, 2018, 57 (16), pp.10431 - 10441. ⟨10.1021/acs.inorgchem.8b01695⟩. ⟨hal-01858716⟩
  • Thibaut Duchanois, Li Liu, Mariachiara Pastore, Antonio Monari, Cristina Cebrian, et al.. NHC-Based Iron Sensitizers for DSSCs. Inorganics, MDPI AG, 2018, 6 (2), pp.63. ⟨10.3390/inorganics6020063⟩. ⟨hal-01825557⟩
  • Sabrina Touchet, Sai Shradha Reddy Kommidi, Philippe Gros. Organomagnesiate-Promoted Enantioselective Cascade Process: Straightforward Access to Chiral 3-Substituted Isobenzofuranones. ChemistrySelect, Wiley, 2018, 3 (14), pp.3939-3942. ⟨10.1002/slct.201800178⟩. ⟨hal-01813276⟩
  • Ozlem Sengul, Esma Birsen Boydas, Mariachiara Pastore, Walid Sharmouk, Philippe Gros, et al.. Probing optical properties of thiophene derivatives for two-photon absorption. Theoretical Chemistry Accounts: Theory, Computation, and Modeling, Springer Verlag, 2017, 136 (6), ⟨10.1007/s00214-017-2094-y⟩. ⟨hal-01812854⟩
  • Michał Łomzik, Olga Mazuryk, Dorota Rutkowska-Zbik, Grażyna Stochel, Philippe Gros, et al.. New ruthenium compounds bearing semicarbazone 2-formylopyridine moiety: Playing with auxiliary ligands for tuning the mechanism of biological activity. Journal of Inorganic Biochemistry, Elsevier, 2017, 175, pp.80-91. ⟨10.1016/j.jinorgbio.2017.07.006⟩. ⟨hal-01813271⟩
  • Philippe Pierrat, Stéphanie Hesse, Cristina Cebrian, Philippe Gros. Controlling charge-transfer properties through a microwave-assisted mono- or bis-annulation of dialkynyl-N-(het)arylpyrroles. Organic and Biomolecular Chemistry, Royal Society of Chemistry, 2017, 15 (40), pp.8568-8575. ⟨10.1039/c7ob02149f⟩. ⟨hal-01998658⟩
  • Philippe Pierrat, Stéphanie Hesse, Cristina Cebrian, Philippe Gros. Controlling charge-transfer properties through a microwave-assisted mono- or bis-annulation of dialkynyl-N-(het)arylpyrroles. Organic and Biomolecular Chemistry, Royal Society of Chemistry, 2017, 15 (40), pp.8568 - 8575. ⟨10.1039/C7OB02149F⟩. ⟨hal-01812856⟩
  • Li Liu, Thibaut Duchanois, Thibaud Etienne, Antonio Monari, Marc Beley, et al.. A new record excited state 3 MLCT lifetime for metalorganic iron( ii ) complexes. Physical Chemistry Chemical Physics, Royal Society of Chemistry, 2016, 18 (18), pp.12550-12556. ⟨10.1039/C6CP01418F⟩. ⟨hal-01812755⟩
  • Mariachiara Pastore, Thibaut Duchanois, Li Liu, Antonio Monari, Xavier Assfeld, et al.. Interfacial charge separation and photovoltaic efficiency in Fe(ii)–carbene sensitized solar cells. Physical Chemistry Chemical Physics, Royal Society of Chemistry, 2016, 18 (40), pp.28069-28081. ⟨10.1039/C6CP05535D⟩. ⟨hal-01812853⟩
  • Robin Cisneros, Marc Beley, François Lapicque, Philippe C. Gros. Hydrophilic Ethylene-Glycol-Based Ruthenium Sensitizers for Aqueous Dye-Sensitized Solar Cells. European Journal of Inorganic Chemistry, Wiley-VCH Verlag, 2016, pp.33-39. ⟨10.1002/ejic.201501026⟩. ⟨hal-01496640⟩
  • Olga Mazuryk, Michal Lomzik, David Martineau, Marc Beley, Malgorzata Brindell, et al.. Anticancer activity of ruthenium(II) polypyridine complexes bearing pyrrolidine substituents. Inorganica Chimica Acta, Elsevier, 2016, 443, pp.86-90. ⟨10.1016/j.ica.2015.12.021⟩. ⟨hal-01496645⟩
  • Walid Walid Sharmoukh, Walid Hassan, Philippe Gros, Nageh Allam. Design and synthesis of new Ru-complexes as potential photo-sensitizers: experimental and TD-DFT insights. RSC Advances, Royal Society of Chemistry, 2016, 6 (73), pp.69647 - 69657. ⟨10.1039/C6RA16458G⟩. ⟨hal-01812852⟩
  • Andressa V. Müller, Poliana S. Mendonça, Stéphane Parant, Thibaut Duchanois, Philippe C. Gros, et al.. Effects of Methyl-Substituted Phenanthrolines on the Performance of Ruthenium(II) Dye-Sensitizers. Journal of the Brazilian Chemical Society, Sociedade Brasileira de Química, SBQ, 2015, 26 (11), ⟨10.5935/0103-5053.20150208 ⟩. ⟨hal-01496019⟩
  • Joelle Char, Emilie Brulé, Philippe C. Gros, Marie-Noelle Rager, Vincent Guérineau, et al.. Synthesis of heterotactic PLA from rac-lactide using hetero-bimetallic Mg/Zn-Li systems. Journal of Organometallic Chemistry, Elsevier, 2015, 796, pp.47-52. ⟨10.1016/j.jorganchem.2015.02.038⟩. ⟨hal-01495967⟩
  • Hugo Gattuso, Thibaut Duchanois, Vanessa Besancenot, Claire Barbieux, Xavier Assfeld, et al.. Interaction of iron II complexes with B-DNA. Insights from molecular modeling, spectroscopy and cellular biology. Frontiers in Chemistry, Frontiers, 2015, 3 (67), ⟨10.3389/fchem.2015.00067⟩. ⟨hal-01242500⟩
  • Thibaut Duchanois, Thibaud Etienne, Cristina Cebrian, Li Liu, Antonio Monari, et al.. An Iron-Based Photosensitizer with Extended Excited-State Lifetime: Photophysical and Photovoltaic Properties. European Journal of Inorganic Chemistry, Wiley-VCH Verlag, 2015, pp.2469-2477. ⟨10.1002/ejic.201500142⟩. ⟨hal-01495210⟩
  • Javier Francos, Philippe C. Gros, Alan R. Kennedy, Charles T. O'Hara. Structural Studies of (rac)-BIPHEN Organomagnesiates and Intermediates in the Halogen-Metal Exchange of 2-Bromopyridine. Organometallics, American Chemical Society, 2015, 34 (11), pp.2550-2557. ⟨10.1021/om501225g⟩. ⟨hal-01495973⟩
  • Walid Sharmoukh, Antonio Attanzio, Eva Busatto, Thibaud Etienne, Stefano Carli, et al.. 2,5-Dithienylpyrrole (DTP) as a donor component in DTP-pi-A organic sensitizers: photophysical and photovoltaic properties. RSC Advances, Royal Society of Chemistry, 2015, 5 (6), pp.4041-4050. ⟨10.1039/c4ra10342d⟩. ⟨hal-01495200⟩
  • Walid Sharmoukh, Antonio Attanzio, Eva Busatto, Thibaud Etienne, Stefano Carli, et al.. 2,5-Dithienylpyrrole (DTP) as a donor component in DTP–π–A organic sensitizers: photophysical and photovoltaic properties. RSC Advances, Royal Society of Chemistry, 2015, 5 (6), pp.4041 - 4050. ⟨10.1039/C4RA10342D⟩. ⟨hal-01913513⟩
  • David Tilly, Floris Chevallier, Florence Mongin, Philippe C. Gros. Bimetallic Combinations for Dehalogenative Metalation Involving Organic Compounds. Chemical Reviews, American Chemical Society, 2014, 114 (2), pp.1207--1257. ⟨10.1021/cr400367p⟩. ⟨hal-01153814⟩
  • Sajida Noureen, Roberto Argazzi, Antonio Monari, Marc Beley, Xavier Assfeld, et al.. Novel Ru-based sunlight harvesters bearing dithienylpyrrolo (DTP)-bipyridine ligands: Synthesis, characterization and photovoltaic properties. Dyes and Pigments, Elsevier, 2014, 101, pp.318-328. ⟨10.1016/j.dyepig.2013.10.013⟩. ⟨hal-01494554⟩
  • Thibaut Duchanois, Thibaud Etienne, Marc Beley, Xavier Assfeld, Eric A. Perpete, et al.. Heteroleptic Pyridyl-Carbene Iron Complexes with Tuneable Electronic Properties. European Journal of Inorganic Chemistry, Wiley-VCH Verlag, 2014, pp.3747-3753. ⟨10.1002/ejic.201402356⟩. ⟨hal-01494414⟩
  • Marc Beley, Philippe C. Gros. Ruthenium Polypyridine Complexes Bearing Pyrroles and pi-Extended Analogues. Synthesis, Spectroelectronic, Electrochemical, and Photovoltaic Properties. Organometallics, American Chemical Society, 2014, 33 (18), pp.4590-4606. ⟨10.1021/om5002183⟩. ⟨hal-01494565⟩
  • Nada Marquise, Guillaume Bretel, Frédéric Lassagne, Floris Chevallier, Thierry Roisnel, et al.. Deproto-metallation using mixed lithium-zinc and lithium-copper bases and computed CH acidity of 2-substituted quinolines. RSC Advances, Royal Society of Chemistry, 2014, 4, pp.19602. ⟨10.1039/c4ra02583k⟩. ⟨hal-01002410⟩
  • Mebarek Bahnous, Abdelmalek Bouraiou, Meryem Chelghoum, Sofiane Bouacida, Thierry Roisnel, et al.. Synthesis, crystal structure and antibacterial activity of new highly functionalized ionic compounds based on the imidazole nucleus. Bioorganic and Medicinal Chemistry Letters, Elsevier, 2013, 23 (5), pp.1274-1278. ⟨10.1016/j.bmcl.2013.01.004⟩. ⟨hal-01494086⟩
  • Raghu Ram Kadiyala, David Tilly, Elisabeth Nagaradja, Thierry Roisnel, Vadim E. Matulis, et al.. Computed CH acidity of biaryl compounds and their deprotonative metalation by using a mixed lithium/zinc-TMP base.. Chemistry - A European Journal, Wiley-VCH Verlag, 2013, 19, pp.7944--7960. ⟨10.1002/chem.201300552⟩. ⟨hal-01069722⟩
  • Nada Marquise, Philip Harford, Floris Chevallier, Thierry Roisnel, Vincent Dorcet, et al.. Synthesis of azafluorenones and related compounds using deprotocupration-aroylation followed by intramolecular direct arylation. Tetrahedron, Elsevier, 2013, 69 (47), pp.10123-10133. ⟨10.1016/j.tet.2013.09.030⟩. ⟨hal-00869376⟩
  • Nada Marquise, Philip J. Harford, Floris Chevallier, Thierry Roisnel, Andrew E. H. Wheatley, et al.. Efficient two-step access to azafluorenones and related compounds. Tetrahedron Letters, Elsevier, 2013, 54 (24), pp.3154-3157. ⟨10.1016/j.tetlet.2013.04.020⟩. ⟨hal-00871003⟩
  • Delphine Catel, Floris Chevallier, Florence Mongin, Philippe C. Gros. Chiral organomagnesiates as dual reagents for bromine-magnesium exchange of 2-bromopyridine and access to chiral α-substituted 2-pyridylcarbinols. European Journal of Organic Chemistry, Wiley-VCH Verlag, 2012, pp.53-57. ⟨10.1002/ejoc.201101490⟩. ⟨hal-01053767⟩
  • Gandrath Dayaker, David Tilly, Floris Chevallier, Göran Hilmersson, Philippe C. Gros, et al.. Enantioselective Metalation of N,N-Diisopropylferrocenecarboxamide and Methyl Ferrocenecarboxylate Using Lithium-Metal Chiral Bases. European Journal of Organic Chemistry, Wiley-VCH Verlag, 2012, pp.6051-6057. ⟨10.1002/ejoc.201200965⟩. ⟨hal-01053773⟩
  • David Tilly, Katia Snegaroff, Gandrath Dayaker, Floris Chevallier, Philippe C. Gros, et al.. (Chiral) lithium-(magnesium-)zinc and lithium-cobalt combinations as dual reagents for aromatic deproto-metalation and aryl transfer to aldehydes.. Tetrahedron, Elsevier, 2012, 68, pp.8761--8766. ⟨10.1016/j.tet.2012.08.008⟩. ⟨hal-01070070⟩
  • Olivier Payen, Floris Chevallier, Florence Mongin, Philippe Gros. Straightforward access to enantioenriched pyrazyl alcohols using chiral organomagnesiates. Tetrahedron: Asymmetry, Elsevier, 2012, 23 (34), pp.1678-1682. ⟨10.1016/j.tetasy.2012.11.003⟩. ⟨hal-00813094⟩
  • Antonio Monari, Xavier Assfeld, Marc Beley, Philippe Gros. Theoretical Study of New Ruthenium-Based Dyes for Dye-Sensitized Solar Cells. Journal of Physical Chemistry A, American Chemical Society, 2011, 115 (15), pp.3596-3603. ⟨10.1021/jp201058v⟩. ⟨hal-02189805⟩
  • Katia Snégaroff, Tan Tai Nguyen, Nada Marquise, Yury S. Halauko, Philip J. Harford, et al.. Deprotonative metalation of chloro- and bromopyridines using amido-based bimetallic species and regioselectivity-computed CH acidity relationships.. Chemistry - A European Journal, Wiley-VCH Verlag, 2011, 17 (47), pp.13284. ⟨10.1002/chem.201101993⟩. ⟨hal-00735265⟩
  • Maqsood Ahmed, Sajida Noureen, Philippe Gros, Benoît Guillot, Christian Jelsch. 2,2′-(Ethane-1,2-diyl)bis[2-(5-bromothiophen-2-yl)-1,3-dioxolane] at 100 K refined using a multipolar atom model. Acta Crystallographica Section C: Crystal Structure Communications, International Union of Crystallography, 2011, 67 (8), pp.o329 - o333. ⟨10.1107/S0108270111027247⟩. ⟨hal-01713014⟩
  • Katia Snégaroff, Shinsuke Komagawa, M. Yonehara, Floris Chevallier, Philippe Gros, et al.. Lithium cadmate-mediated deprotonative metalation of anisole: experimental and computational study. Journal of Organic Chemistry, American Chemical Society, 2010, 75 (9), pp.3117-3120. ⟨10.1021/jo100150S⟩. ⟨hal-00785078⟩
  • Nguyet Trang Thanh Chau, Maxime Meyer, Shinsuke Komagawa, Floris Chevallier, Yves Fort, et al.. Homoleptic zincate-promoted room-temperature halogen-metal exchange of bromopyridines. Chemistry - A European Journal, Wiley-VCH Verlag, 2010, 16, pp.12425-12433. ⟨10.1002/chem.201001664⟩. ⟨hal-01010436⟩
  • Katia Snégaroff, Shinsuke Komagawa, Floris Chevallier, Philippe Gros, Stéphane Golhen, et al.. Deprotonative metalation of substituted benzenes and heteroaromatics using amino/alkyl mixed lithium-zinc combinations.. Chemistry - A European Journal, Wiley-VCH Verlag, 2010, 16 (27), pp.8191-8201. ⟨10.1002/chem.201000543⟩. ⟨hal-00737564⟩
  • Gandrath Dayaker, Floris Chevallier, Philippe C. Gros, Florence Mongin. Deprotonative metalation of substituted aromatics using mixed lithium-cobalt combinations. Tetrahedron, Elsevier, 2010, 66, pp.8904-8910. ⟨10.1016/j.tet.2010.09.053⟩. ⟨hal-01010453⟩
  • Philippe Pierrat, Yves Fort, Philippe Gros. First Immobilization of Chiral Menthol-Derived Picoline on Solid Support and Evaluation for Asymmetric Catalysis.. ChemInform, Wiley-VCH Verlag, 2007, 38 (43). ⟨hal-01998685⟩
  • Philippe Pierrat, Philippe Gros, Yves Fort. Unusual tBuLi Induced Ortholithiation versus Halogen?Lithium Exchange in Bromopyridines: Two Alternative Strategies for Functionalization.. SYNLETT, Georg Thieme Verlag, 2005, pp.2319-2322. ⟨10.1055/s-2004-831337⟩. ⟨hal-01998669⟩
  • Philippe Pierrat, Philippe Gros, Yves Fort. Solid Phase Synthesis of Pyridine-Based Derivatives from a 2-Chloro-5-Bromopyridine Scaffold. Journal of Combinatorial Chemistry, American Chemical Society, 2005, 7 (6), pp.879-886. ⟨hal-01998682⟩
  • Philippe Pierrat, Philippe Gros, Yves Fort. Hiyama Cross-Coupling of Chloro-, Fluoro-, and Methoxypyridyltrimethylsilanes: Room-Temperature Novel Access to Functional Bi(het)aryl. Organic Letters, American Chemical Society, 2005, 7 (4), pp.697-700. ⟨hal-01998677⟩

Conference papers4 documents

  • Philippe Gros. Design of New Iron-based Sensitizers for Light harvesting and Electron-transfer. Euchems, Nitrogen Ligands, Sep 2018, LISBONNE, Portugal. ⟨hal-01898293⟩
  • Stefan Haacke, Li Liu, Edoardo Domenichini, Xavier Assfeld, Philippe Gros, et al.. Ultrafast excited state dynamics of NHC-Fe(II) complexes designed for light harvesting. Advances in Ultrafast Condensed Phase Physics, Apr 2018, Strasbourg, France. pp.28. ⟨hal-01898263⟩
  • Philippe Gros. From Ruthenium to Iron Sensitizers: A Challenge towards more Ecofriendly Hybrid Solar Cells. 4th USM-UL congress, Jan 2017, PENANG, Malaysia. ⟨hal-01898301⟩
  • Philippe Gros. From Ruthenium to Iron Sensitizers: The Challenging Chemical Tuning of Photophysical Properties. HOPV17, May 2017, Lausanne, Switzerland. ⟨hal-01898299⟩