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Keywords

Photophysics Iron complexes Iron Deprotometalation Polarimetry Pair production Chirality Zinc Gamma ray Palladium Dyes Metalation Pigments Copper Bimetallic bases Lithium Carbene ligands DFT Heterocycle Azimuthal angle
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101

Dr Philippe C. GROS, CNRS Research Director

Head of the L2CM (Laboratoire Lorrain de Chimie Moléculaire) UMR7053 (CNRS/Université de Lorraine)  

 

Short biography

Philippe C. Gros studied chemistry at the Universite of Lyon (Lyon, France) and obtained his Ph.D. in 1992 with Dr Pierre Leperchec. He then worked for two years as a postdoctoral fellow with the Isochem Company on phosgene derivative chemistry. In 1994 he entered the CNRS as “Chargé de Recherches” in the Laboratory of Pr. Paul Caubère at Nancy-Université (Lorraine, France). He received his Habilitation (HDR) in 2000 and was appointed “Directeur de Recherches” in 2006. HIs is now Head of the L2CM Laboratory (joint CNRS-Univ Lorraine Laboratory, 65 persons). His current research interests include the design of new metalating agents (organolithiums, ate complexes) for the regio- and enantioselective functionalization of heterocycles, structural and reaction mechanism investigation, transition-metal-catalyzed cross-couplings for ligands synthesis, and the building of photo- and electroactive organometallic materials for various applications including solar energy. 

Journal articles91 documents

  • Cristina Cebrían, Mariachiara Pastore, Antonio Monari, Xavier Assfeld, Philippe Gros, et al.. Ultrafast Spectroscopy of Fe(II) Complexes Designed for Solar Energy Conversion: Current Status and Open Questions. ChemPhysChem, Wiley-VCH Verlag, 2022, ⟨10.1002/cphc.202100659⟩. ⟨hal-03552196⟩
  • Janske Nel, David Siniscalco, Cécilia Hognon, Mathilde Bouché, Nadège Touche, et al.. Structural and morphological changes of breast cancer cells induced by iron (II) complexes. Nanoscale, Royal Society of Chemistry, 2022, 14 (7), pp.2523-2860. ⟨10.1039/D1NR08301E⟩. ⟨hal-03563765⟩
  • Dhuaou Ibrahim, Pascal Boulet, Philippe Gros, Philippe Pierrat. Efficient Access to Arylated Aza‐ullazines by Regioselective Functionalization of their pyridine ring by H‐Li exchange and Electrophilic Substitution.. European Journal of Organic Chemistry, Wiley-VCH Verlag, 2021, 2021 (22), pp.3331-3339. ⟨10.1002/ejoc.202100333⟩. ⟨hal-03246746⟩
  • Gandrath Dayaker, William Erb, Madani Hedidi, Floris Chevallier, Marielle Blot, et al.. Enantioselective deprotometalation of alkyl ferrocenecarboxylates using bimetallic bases. New Journal of Chemistry, Royal Society of Chemistry, 2021, ⟨10.1039/d1nj04526a⟩. ⟨hal-03464801⟩
  • Anna Bonfiglio, Conor Mccartin, Ulises Carrillo, Cristina Cebrian, Philippe Gros, et al.. IrIII‐pyridoannelated N‐heterocyclic carbene complexes: potent theranostic agents via mitochondria targeting. European Journal of Inorganic Chemistry, Wiley-VCH Verlag, 2021, 2021 (16), pp.1551-1564. ⟨10.1002/ejic.202100132⟩. ⟨hal-03158231⟩
  • Sabrina Touchet, Callum Yeardley, Charles O’hara, Philippe Gros. Critical ligand and salt effects in organomagnesiate‐promoted 3,3‐disubstituted phthalides synthesis from 2‐iodobenzoate derivatives. European Journal of Organic Chemistry, Wiley-VCH Verlag, 2021, 2021 (34), pp.4835-4845. ⟨10.1002/ejoc.202100899⟩. ⟨hal-03325715v2⟩
  • B Brett Finlay, Katherine R Amato, Meghan Azad, Martin J Blaser, Thomas C G Bosch, et al.. The hygiene hypothesis, the COVID pandemic, and consequences for the human microbiome. Proceedings of the National Academy of Sciences of the United States of America, National Academy of Sciences, 2021, 118 (6), pp.e2010217118. ⟨10.1073/pnas.2010217118⟩. ⟨pasteur-03263665⟩
  • Anil Reddy Marri, Edoardo Marchini, Valentin Diez-Cabanes, Roberto Argazzi, Mariachiara Pastore, et al.. Record power conversion efficiencies for Iron (II)-NHC-sensitized DSSCs from rational molecular engineering and electrolyte optimization. Journal of Materials Chemistry A, Royal Society of Chemistry, 2021, 9 (6), pp.3540-3554. ⟨10.1039/D0TA10841C⟩. ⟨hal-03093810⟩
  • Anil Reddy Marri, Edoardo Marchini, Valentin Diez Cabanes, Roberto Argazzi, Mariachiara Pastore, et al.. A series of Iron(II)‐NHC Sensitizers with remarkable power conversion efficiency in photoelectrochemical cells. Chemistry - A European Journal, Wiley-VCH Verlag, 2021, 27 (65), ⟨10.1002/chem.202103178⟩. ⟨hal-03347445v2⟩
  • Elodie Rousset, Olivier Mongin, Juliette Moreau, Latevi Max Lawson Daku, Marc Beley, et al.. Molecular engineering for optical properties of 5-substituted-1,10-phenanthroline-based Ru(II) complexes. Dalton Transactions, Royal Society of Chemistry, 2021, 50 (29), pp.10119-10132. ⟨10.1039/D1DT00886B⟩. ⟨hal-03251344⟩
  • Kévin Magra, Antonio Francés-Monerris, Cristina Cebrian, Antonio Monari, Stefan Haacke, et al.. Bidentate pyridyl‐NHC ligands: synthesis, ground and excited state properties of their iron(II) complexes and role of the fac/mer isomerism. European Journal of Inorganic Chemistry, Wiley-VCH Verlag, 2021, ⟨10.1002/ejic.202100818⟩. ⟨hal-03464828⟩
  • F. Hainer, N. Alagna, A. Reddy Marri, T. Penfold, Philippe Gros, et al.. Vibrational Coherence Spectroscopy Identifies Ultrafast Branching in an Iron(II) Sensitizer. Journal of Physical Chemistry Letters, American Chemical Society, 2021, 12 (35), pp.8560-8565. ⟨10.1021/acs.jpclett.1c01580⟩. ⟨hal-03335923⟩
  • Dalel El-Marrouki, Sabrina Touchet, Abderrahmen Abdelli, Hédi M’rabet, Mohamed Lotfi Efrit, et al.. Tuneable access to indole, indolone, and cinnoline derivatives from a common 1,4-diketone Michael acceptor. Beilstein Journal of Organic Chemistry, Beilstein-Institut, 2020, 16, pp.1722-1731. ⟨10.3762/bjoc.16.144⟩. ⟨hal-02901438⟩
  • Anna Bonfiglio, Kevin Magra, Cristina Cebrian, Federico Polo, Philippe Gros, et al.. Red-emitting neutral rhenium( i ) complexes bearing a pyridyl pyridoannelated N-heterocyclic carbene. Dalton Transactions, Royal Society of Chemistry, 2020, 49, pp.3102-3111. ⟨10.1039/c9dt04890a⟩. ⟨hal-02490224⟩
  • Rui Yang, Federico Mele, Lisa Worley, David Langlais, Jérémie Rosain, et al.. Human T-bet Governs Innate and Innate-like Adaptive IFN-γ Immunity against Mycobacteria. Cell, Elsevier, 2020, 183 (7), pp.1826-1847.e31. ⟨10.1016/j.cell.2020.10.046⟩. ⟨pasteur-03260339⟩
  • Kevin Magra, Mohamed Darari, Edoardo Domenichini, Antonio Francés-Monerris, Cristina Cebrian, et al.. Photophysical Investigation of Iron(II) Complexes Bearing Bidentate Annulated Isomeric Pyridine-NHC Ligands. Journal of Physical Chemistry C, American Chemical Society, 2020, 124 (34), pp.18379-18389. ⟨10.1021/acs.jpcc.0c03638⟩. ⟨hal-02918450⟩
  • Mohamed Darari, Antonio Francés-Monerris, Bogdan Marekha, Abdelatif Doudouh, Emmanuel Wenger, et al.. Towards Iron(II) Complexes with Octahedral Geometry: Synthesis, Structure and Photophysical Properties. Molecules, MDPI, 2020, 25 (24), pp.5991. ⟨10.3390/molecules25245991⟩. ⟨hal-03081500⟩
  • Ilona Gurgul, Olga Mazuryk, Michał Łomzik, Philippe Gros, Dorota Rutkowska-Zbik, et al.. Unexplored features of Ru(II) polypyridyl complexes - towards combined cytotoxic and antimetastatic activity. Metallomics, Royal Society of Chemistry, 2020, 12 (5), pp.784-793. ⟨10.1039/D0MT00019A⟩. ⟨hal-02514957⟩
  • Mathilde Bouché, Cécilia Hognon, Stéphanie Grandemange, Antonio Monari, Philippe Gros. Recent advances in iron-complexes as drug candidates for cancer therapy: reactivity, mechanism of action and metabolites. Dalton Transactions, Royal Society of Chemistry, 2020, 49 (33), pp.11451-11466. ⟨10.1039/D0DT02135K⟩. ⟨hal-02915892⟩
  • Callum Yeardley, Alan Kennedy, Philippe Gros, Sabrina Touchet, Michael Fairley, et al.. Structural and metal–halogen exchange reactivity studies of sodium magnesiate biphenolate complexes. Dalton Transactions, Royal Society of Chemistry, 2020, pp.5257-5263. ⟨10.1039/d0dt00904k⟩. ⟨hal-02530892⟩
  • Edoardo Marchini, Mohamed Darari, Luca Lazzarin, Rita Boaretto, Roberto Argazzi, et al.. Recombination and regeneration dynamics in FeNHC( ii )-sensitized solar cells. Chemical Communications, Royal Society of Chemistry, 2020, 56, pp.543-546. ⟨10.1039/C9CC07794D⟩. ⟨hal-02410187⟩
  • Antonio Francés-Monerris, Philippe Gros, Mariachiara Pastore, Xavier Assfeld, Antonio Monari. Photophysical properties of bichromophoric Fe(II) complexes bearing an aromatic electron acceptor. Theoretical Chemistry Accounts: Theory, Computation, and Modeling, Springer Verlag, 2019, 138 (86), pp.138:86. ⟨10.1007/s00214-019-2471-9⟩. ⟨hal-03445134⟩
  • Antonio Francés‐monerris, Philippe Gros, Xavier Assfeld, Antonio Monari, Mariachiara Pastore. Toward Luminescent Iron Complexes: Unravelling the Photophysics by Computing Potential Energy Surfaces. ChemPhotoChem, Wiley, 2019, 3 (9), pp.666-683. ⟨10.1002/cptc.201900100⟩. ⟨hal-03445128⟩
  • Mohamed Darari, Edoardo Domenichini, Antonio Francés-Monerris, Cristina Cebrian, Kevin Magra, et al.. Iron(II) complexes with diazinyl-NHC ligands: impact of π-deficiency of the azine core on photophysical properties. Dalton Transactions, Royal Society of Chemistry, 2019, 48 (29), pp.10915-10926. ⟨10.1039/c9dt01731c⟩. ⟨hal-02145893⟩
  • Li Liu, Damianos Agathangelou, Thomas Roland, Olivier Crégut, Thibaud Duchanois, et al.. High sensitivity fluorescence up-conversion spectroscopy of 3 MLCT emission of metal-organic complexes. EPJ Web of Conferences, EDP Sciences, 2019, 205, pp.09009. ⟨10.1051/epjconf/201920509009⟩. ⟨hal-02394782⟩
  • Kevin Magra, Edoardo Domenichini, Antonio Francés-Monerris, Cristina Cebrian, Marc Beley, et al.. Impact of the fac / mer Isomerism on the Excited-State Dynamics of Pyridyl-carbene Fe(II) Complexes. Inorganic Chemistry, American Chemical Society, 2019, 58 (8), pp.5069-5081. ⟨10.1021/acs.inorgchem.9b00138⟩. ⟨hal-02099506⟩
  • Madani Hedidi, Dayaker Gandrath, Yu Kitazawa, Yoshii Tatsuya, Mutsumi Kimura, et al.. Enantioselective deprotometalation of N,N-dialkyl ferrocenecarboxamides using metal amides. New Journal of Chemistry, Royal Society of Chemistry, 2019, 43 (37), pp.14898-14907. ⟨10.1039/c9nj03780b⟩. ⟨hal-02277472⟩
  • Philippe Pierrat, Cristina Cebrian, Marc Beley, Philippe Gros, Ivan Torres-Moya, et al.. Synthesis and properties of new multiple TCNE-adducts from dialkynyl-N-(het)arylpyrroles.. European Journal of Organic Chemistry, Wiley-VCH Verlag, 2019, 2019 (27), pp.4341-4348. ⟨10.1002/ejoc.201900447⟩. ⟨hal-02152157⟩
  • Antonio Francés-Monerris, Kevin Magra, Mohamed Darari, Cristina Cebrian, Marc Beley, et al.. Synthesis and Computational Study of a Pyridylcarbene Fe(II) Complex: Unexpected Effects of fac / mer Isomerism in Metal-to-Ligand Triplet Potential Energy Surfaces. Inorganic Chemistry, American Chemical Society, 2018, 57 (16), pp.10431 - 10441. ⟨10.1021/acs.inorgchem.8b01695⟩. ⟨hal-01858716⟩
  • Sabrina Touchet, Sai Shradha Reddy Kommidi, Philippe Gros. Organomagnesiate-Promoted Enantioselective Cascade Process: Straightforward Access to Chiral 3-Substituted Isobenzofuranones. ChemistrySelect, Wiley, 2018, 3 (14), pp.3939-3942. ⟨10.1002/slct.201800178⟩. ⟨hal-01813276⟩
  • Thibaut Duchanois, Li Liu, Mariachiara Pastore, Antonio Monari, Cristina Cebrian, et al.. NHC-Based Iron Sensitizers for DSSCs. Inorganics, MDPI AG, 2018, 6 (2), pp.63. ⟨10.3390/inorganics6020063⟩. ⟨hal-01825557⟩
  • David Attié, Ties Behnke, Alain Bellerive, Oleg Bezshyyko, Deb Sankar Bhattacharya, et al.. A time projection chamber with GEM-based readout. Nucl.Instrum.Meth.A, 2017, 856, pp.109-118. ⟨10.1016/j.nima.2016.11.002⟩. ⟨hal-01554956⟩
  • Philippe Gros, Denis Bernard. $\gamma$-ray polarimetry with conversions to $e^+e^-$ pairs: polarization asymmetry and the way to measure it. Astropart.Phys., 2017, 88, pp.30-37. ⟨10.1016/j.astropartphys.2016.12.006⟩. ⟨hal-01554513⟩
  • Philippe Pierrat, Stéphanie Hesse, Cristina Cebrian, Philippe Gros. Controlling charge-transfer properties through a microwave-assisted mono- or bis-annulation of dialkynyl-N-(het)arylpyrroles. Organic and Biomolecular Chemistry, Royal Society of Chemistry, 2017, 15 (40), pp.8568 - 8575. ⟨10.1039/C7OB02149F⟩. ⟨hal-01812856⟩
  • Michał Łomzik, Olga Mazuryk, Dorota Rutkowska-Zbik, Grażyna Stochel, Philippe Gros, et al.. New ruthenium compounds bearing semicarbazone 2-formylopyridine moiety: Playing with auxiliary ligands for tuning the mechanism of biological activity. Journal of Inorganic Biochemistry, Elsevier, 2017, 175, pp.80-91. ⟨10.1016/j.jinorgbio.2017.07.006⟩. ⟨hal-01813271⟩
  • Philippe Gros, Denis Bernard. $\gamma$-ray telescopes using conversions to $e^+e^−$ pairs: event generators, angular resolution and polarimetry. Astropart.Phys., 2017, 88, pp.60-67. ⟨10.1016/j.astropartphys.2017.01.002⟩. ⟨hal-03191225⟩
  • Ozlem Sengul, Esma Birsen Boydas, Mariachiara Pastore, Walid Sharmouk, Philippe Gros, et al.. Probing optical properties of thiophene derivatives for two-photon absorption. Theoretical Chemistry Accounts: Theory, Computation, and Modeling, Springer Verlag, 2017, 136 (6), ⟨10.1007/s00214-017-2094-y⟩. ⟨hal-01812854⟩
  • Walid Walid Sharmoukh, Walid Hassan, Philippe Gros, Nageh Allam. Design and synthesis of new Ru-complexes as potential photo-sensitizers: experimental and TD-DFT insights. RSC Advances, Royal Society of Chemistry, 2016, 6 (73), pp.69647 - 69657. ⟨10.1039/C6RA16458G⟩. ⟨hal-01812852⟩
  • Li Liu, Thibaut Duchanois, Thibaud Etienne, Antonio Monari, Marc Beley, et al.. A new record excited state 3 MLCT lifetime for metalorganic iron( ii ) complexes. Physical Chemistry Chemical Physics, Royal Society of Chemistry, 2016, 18 (18), pp.12550-12556. ⟨10.1039/C6CP01418F⟩. ⟨hal-01812755⟩
  • Robin Cisneros, Marc Beley, François Lapicque, Philippe C. Gros. Hydrophilic Ethylene-Glycol-Based Ruthenium Sensitizers for Aqueous Dye-Sensitized Solar Cells. European Journal of Inorganic Chemistry, Wiley-VCH Verlag, 2016, pp.33-39. ⟨10.1002/ejic.201501026⟩. ⟨hal-01496640⟩
  • Olga Mazuryk, Michal Lomzik, David Martineau, Marc Beley, Malgorzata Brindell, et al.. Anticancer activity of ruthenium(II) polypyridine complexes bearing pyrrolidine substituents. Inorganica Chimica Acta, Elsevier, 2016, 443, pp.86-90. ⟨10.1016/j.ica.2015.12.021⟩. ⟨hal-01496645⟩
  • Robin Cisneros, Marc Beley, François Lapicque, Philippe Gros. Hydrophilic Ethylene-Glycol-Based Ruthenium Sensitizers for Aqueous Dye-Sensitized Solar Cells. European Journal of Inorganic Chemistry, Wiley-VCH Verlag, 2016, 2016 (1), pp.2-2. ⟨10.1002/ejic.201501448⟩. ⟨hal-02929959⟩
  • Mariachiara Pastore, Thibaut Duchanois, Li Liu, Antonio Monari, Xavier Assfeld, et al.. Interfacial charge separation and photovoltaic efficiency in Fe(ii)–carbene sensitized solar cells. Physical Chemistry Chemical Physics, Royal Society of Chemistry, 2016, 18 (40), pp.28069-28081. ⟨10.1039/C6CP05535D⟩. ⟨hal-01812853⟩
  • Andressa V. Müller, Poliana S. Mendonça, Stéphane Parant, Thibaut Duchanois, Philippe C. Gros, et al.. Effects of Methyl-Substituted Phenanthrolines on the Performance of Ruthenium(II) Dye-Sensitizers. Journal of the Brazilian Chemical Society, Sociedade Brasileira de Química, SBQ, 2015, 26 (11), ⟨10.5935/0103-5053.20150208⟩. ⟨hal-01496019⟩
  • Joelle Char, Emilie Brulé, Philippe C. Gros, Marie-Noelle Rager, Vincent Guérineau, et al.. Synthesis of heterotactic PLA from rac-lactide using hetero-bimetallic Mg/Zn-Li systems. Journal of Organometallic Chemistry, Elsevier, 2015, 796, pp.47-52. ⟨10.1016/j.jorganchem.2015.02.038⟩. ⟨hal-01495967⟩
  • Rebekah van Bruggen, Christian Gualtieri, Alexandra Iliescu, Chalisa Louicharoen Cheepsunthorn, Punchalee Mungkalasut, et al.. Modulation of Malaria Phenotypes by Pyruvate Kinase (PKLR) Variants in a Thai Population. PLoS ONE, Public Library of Science, 2015, 10 (12), pp.e0144555. ⟨10.1371/journal.pone.0144555⟩. ⟨pasteur-02082234⟩
  • Walid Sharmoukh, Antonio Attanzio, Eva Busatto, Thibaud Etienne, Stefano Carli, et al.. 2,5-Dithienylpyrrole (DTP) as a donor component in DTP-pi-A organic sensitizers: photophysical and photovoltaic properties. RSC Advances, Royal Society of Chemistry, 2015, 5 (6), pp.4041-4050. ⟨10.1039/c4ra10342d⟩. ⟨hal-01495200⟩
  • Javier Francos, Philippe C. Gros, Alan R. Kennedy, Charles T. O'Hara. Structural Studies of (rac)-BIPHEN Organomagnesiates and Intermediates in the Halogen-Metal Exchange of 2-Bromopyridine. Organometallics, American Chemical Society, 2015, 34 (11), pp.2550-2557. ⟨10.1021/om501225g⟩. ⟨hal-01495973⟩
  • Thibaut Duchanois, Thibaud Etienne, Cristina Cebrian, Li Liu, Antonio Monari, et al.. An Iron-Based Photosensitizer with Extended Excited-State Lifetime: Photophysical and Photovoltaic Properties. European Journal of Inorganic Chemistry, Wiley-VCH Verlag, 2015, pp.2469-2477. ⟨10.1002/ejic.201500142⟩. ⟨hal-01495210⟩
  • Xianqin Zhang, Bo Bogunovic, Béatrice Payelle-Brogard, Véronique François-Newton, Scott Speer, et al.. Human intracellular ISG15 prevents interferon-α/β over-amplification and auto-inflammation. Nature, Nature Publishing Group, 2015, 517 (7532), pp.89-93. ⟨10.1038/nature13801⟩. ⟨pasteur-02070691⟩
  • Hugo Gattuso, Thibaut Duchanois, Vanessa Besancenot, Claire Barbieux, Xavier Assfeld, et al.. Interaction of iron II complexes with B-DNA. Insights from molecular modeling, spectroscopy and cellular biology. Frontiers in Chemistry, Frontiers Media, 2015, 3 (67), ⟨10.3389/fchem.2015.00067⟩. ⟨hal-01242500⟩
  • Walid Sharmoukh, Antonio Attanzio, Eva Busatto, Thibaud Etienne, Stefano Carli, et al.. 2,5-Dithienylpyrrole (DTP) as a donor component in DTP–π–A organic sensitizers: photophysical and photovoltaic properties. RSC Advances, Royal Society of Chemistry, 2015, 5 (6), pp.4041 - 4050. ⟨10.1039/C4RA10342D⟩. ⟨hal-01913513⟩
  • David Tilly, Floris Chevallier, Florence Mongin, Philippe C. Gros. Bimetallic Combinations for Dehalogenative Metalation Involving Organic Compounds. Chemical Reviews, American Chemical Society, 2014, 114 (2), pp.1207--1257. ⟨10.1021/cr400367p⟩. ⟨hal-01153814⟩
  • Nada Marquise, Guillaume Bretel, Frédéric Lassagne, Floris Chevallier, Thierry Roisnel, et al.. Deproto-metallation using mixed lithium-zinc and lithium-copper bases and computed CH acidity of 2-substituted quinolines. RSC Advances, Royal Society of Chemistry, 2014, 4 (38), pp.19602. ⟨10.1039/c4ra02583k⟩. ⟨hal-01002410⟩
  • Sajida Noureen, Roberto Argazzi, Antonio Monari, Marc Beley, Xavier Assfeld, et al.. Novel Ru-based sunlight harvesters bearing dithienylpyrrolo (DTP)-bipyridine ligands: Synthesis, characterization and photovoltaic properties. Dyes and Pigments, Elsevier, 2014, 101, pp.318-328. ⟨10.1016/j.dyepig.2013.10.013⟩. ⟨hal-01494554⟩
  • Grégory Caignard, Megan Eva, Rebekah van Bruggen, Robert Eveleigh, Guillaume Bourque, et al.. Mouse ENU Mutagenesis to Understand Immunity to Infection: Methods, Selected Examples, and Perspectives. Genes, MDPI, 2014, 5 (4), pp.887-925. ⟨10.3390/genes5040887⟩. ⟨hal-03352903⟩
  • Marc Beley, Philippe C. Gros. Ruthenium Polypyridine Complexes Bearing Pyrroles and pi-Extended Analogues. Synthesis, Spectroelectronic, Electrochemical, and Photovoltaic Properties. Organometallics, American Chemical Society, 2014, 33 (18), pp.4590-4606. ⟨10.1021/om5002183⟩. ⟨hal-01494565⟩
  • Thibaut Duchanois, Thibaud Etienne, Marc Beley, Xavier Assfeld, Eric A. Perpete, et al.. Heteroleptic Pyridyl-Carbene Iron Complexes with Tuneable Electronic Properties. European Journal of Inorganic Chemistry, Wiley-VCH Verlag, 2014, pp.3747-3753. ⟨10.1002/ejic.201402356⟩. ⟨hal-01494414⟩
  • Nada Marquise, Philip J. Harford, Floris Chevallier, Thierry Roisnel, Vincent Dorcet, et al.. Synthesis of azafluorenones and related compounds using deprotocupration-aroylation followed by intramolecular direct arylation. Tetrahedron, Elsevier, 2013, 69 (47), pp.10123-10133. ⟨10.1016/j.tet.2013.09.030⟩. ⟨hal-00869376⟩
  • Minji Byun, Cindy S. Ma, Arzu Akçay, Vincent Pedergnana, Umaimainthan Palendira, et al.. Inherited human OX40 deficiency underlying classic Kaposi sarcoma of childhood. Journal of Experimental Medicine, Rockefeller University Press, 2013, 210 (9), pp.1743 - 1759. ⟨10.1084/jem.20130592⟩. ⟨pasteur-01370948⟩
  • Raghu Ram Kadiyala, David Tilly, Elisabeth Nagaradja, Thierry Roisnel, Vadim E. Matulis, et al.. Computed CH acidity of biaryl compounds and their deprotonative metalation by using a mixed lithium/zinc-TMP base.. Chemistry - A European Journal, Wiley-VCH Verlag, 2013, 19, pp.7944--7960. ⟨10.1002/chem.201300552⟩. ⟨hal-01069722⟩
  • Mebarek Bahnous, Abdelmalek Bouraiou, Meryem Chelghoum, Sofiane Bouacida, Thierry Roisnel, et al.. Synthesis, crystal structure and antibacterial activity of new highly functionalized ionic compounds based on the imidazole nucleus. Bioorganic and Medicinal Chemistry Letters, Elsevier, 2013, 23 (5), pp.1274-1278. ⟨10.1016/j.bmcl.2013.01.004⟩. ⟨hal-01494086⟩
  • Nada Marquise, Philip J. Harford, Floris Chevallier, Thierry Roisnel, Andrew E. H. Wheatley, et al.. Efficient two-step access to azafluorenones and related compounds. Tetrahedron Letters, Elsevier, 2013, 54 (24), pp.3154-3157. ⟨10.1016/j.tetlet.2013.04.020⟩. ⟨hal-00871003⟩
  • Gandrath Dayaker, David Tilly, Floris Chevallier, Göran Hilmersson, Philippe C. Gros, et al.. Enantioselective Metalation of N,N-Diisopropylferrocenecarboxamide and Methyl Ferrocenecarboxylate Using Lithium-Metal Chiral Bases. European Journal of Organic Chemistry, Wiley-VCH Verlag, 2012, pp.6051-6057. ⟨10.1002/ejoc.201200965⟩. ⟨hal-01053773⟩
  • David Tilly, Katia Snegaroff, Gandrath Dayaker, Floris Chevallier, Philippe C. Gros, et al.. (Chiral) lithium-(magnesium-)zinc and lithium-cobalt combinations as dual reagents for aromatic deproto-metalation and aryl transfer to aldehydes.. Tetrahedron, Elsevier, 2012, 68, pp.8761--8766. ⟨10.1016/j.tet.2012.08.008⟩. ⟨hal-01070070⟩
  • Fabien Lachaud, Christophe Jeandon, Marc Beley, Romain Ruppert, Philippe Gros, et al.. Ground and Excited State Properties of New Porphyrin Based Dyads: A Combined Theoretical and Experimental Study.. Journal of Physical Chemistry A, American Chemical Society, 2012, 116 (44), pp.10736-10744. ⟨10.1021/jp307452d⟩. ⟨hal-02309979⟩
  • Fabien Lachaud, Christophe Jeandon, Marc Beley, Romain Ruppert, Philippe Gros, et al.. Ground and Excited State Properties of New Porphyrin Based Dyads: A Combined Theoretical and Experimental Study.. Journal of Physical Chemistry A, American Chemical Society, 2012, 116 (44), pp.10736-10744. ⟨10.1021/jp307452d⟩. ⟨hal-02189241⟩
  • Olivier Payen, Floris Chevallier, Florence Mongin, Philippe C. Gros. Straightforward access to enantioenriched pyrazyl alcohols using chiral organomagnesiates. Tetrahedron: Asymmetry, Elsevier, 2012, 23 (34), pp.1678-1682. ⟨10.1016/j.tetasy.2012.11.003⟩. ⟨hal-00813094⟩
  • Sajida Noureen, Stefano Caramori, Antonio Monari, Xavier Assfeld, Roberto Argazzi, et al.. Strong π-delocalization and substitution effect on electronic properties of dithienylpyrrole-containing bipyridine ligands and corresponding ruthenium complexes. Dalton Transactions, Royal Society of Chemistry, 2012, 41 (16), pp.4833. ⟨10.1039/C2DT12367C⟩. ⟨hal-02189257⟩
  • Fabien Lachaud, Christophe Jeandon, Antonio Monari, Xavier Assfeld, Marc Beley, et al.. New dyads using (metallo)porphyrins as ancillary ligands in polypyridine ruthenium complexes. Synthesis and electronic properties. Dalton Transactions, Royal Society of Chemistry, 2012, 41 (41), pp.12865. ⟨10.1039/C2DT31656K⟩. ⟨hal-02189256⟩
  • Fabien Lachaud, Christophe Jeandon, Antonio Monari, Xavier Assfeld, Marc Beley, et al.. New dyads using (metallo)porphyrins as ancillary ligands in polypyridine ruthenium complexes. Synthesis and electronic properties. Dalton Transactions, Royal Society of Chemistry, 2012, 41 (41), pp.12865. ⟨10.1039/C2DT31656K⟩. ⟨hal-02309982⟩
  • J. Berghout, S. Higgins, C. Loucoubar, Anavaj Sakuntabhai, Kevin C. Kain, et al.. Genetic diversity in human erythrocyte pyruvate kinase. Genes and Immunity, Nature Publishing Group: Open Access Hybrid Model Option B, 2012, 13 (1), pp.98-102. ⟨10.1038/gene.2011.54⟩. ⟨pasteur-02069000⟩
  • Delphine Catel, Floris Chevallier, Florence Mongin, Philippe C. Gros. Chiral organomagnesiates as dual reagents for bromine-magnesium exchange of 2-bromopyridine and access to chiral α-substituted 2-pyridylcarbinols. European Journal of Organic Chemistry, Wiley-VCH Verlag, 2012, pp.53-57. ⟨10.1002/ejoc.201101490⟩. ⟨hal-01053767⟩
  • Maqsood Ahmed, Sajida Noureen, Philippe C. Gros, Benoît Guillot, Christian Jelsch. 2,2′-(Ethane-1,2-diyl)bis[2-(5-bromothiophen-2-yl)-1,3-dioxolane] at 100 K refined using a multipolar atom model. Acta Crystallographica Section C : Crystal Structure Communications [1968-2013], International Union of Crystallography, 2011, 67 (8), pp.o329 - o333. ⟨10.1107/S0108270111027247⟩. ⟨hal-01713014⟩
  • Katia Snégaroff, Tan Tai Nguyen, Nada Marquise, Yury S. Halauko, Philip J. Harford, et al.. Deprotonative metalation of chloro- and bromopyridines using amido-based bimetallic species and regioselectivity-computed CH acidity relationships.. Chemistry - A European Journal, Wiley-VCH Verlag, 2011, 17 (47), pp.13284. ⟨10.1002/chem.201101993⟩. ⟨hal-00735265⟩
  • Antonio Monari, Xavier Assfeld, Marc Beley, Philippe Gros. Theoretical Study of New Ruthenium-Based Dyes for Dye-Sensitized Solar Cells. Journal of Physical Chemistry A, American Chemical Society, 2011, 115 (15), pp.3596-3603. ⟨10.1021/jp201058v⟩. ⟨hal-02189805⟩
  • Gandrath Dayaker, Floris Chevallier, Philippe C. Gros, Florence Mongin. Deprotonative metalation of substituted aromatics using mixed lithium-cobalt combinations. Tetrahedron, Elsevier, 2010, 66, pp.8904-8910. ⟨10.1016/j.tet.2010.09.053⟩. ⟨hal-01010453⟩
  • Katia Snégaroff, Shinsuke Komagawa, M. Yonehara, Floris Chevallier, Philippe C. Gros, et al.. Lithium cadmate-mediated deprotonative metalation of anisole: experimental and computational study. Journal of Organic Chemistry, American Chemical Society, 2010, 75 (9), pp.3117-3120. ⟨10.1021/jo100150S⟩. ⟨hal-00785078⟩
  • Katia Snégaroff, Shinsuke Komagawa, Floris Chevallier, Philippe C. Gros, Stéphane Golhen, et al.. Deprotonative metalation of substituted benzenes and heteroaromatics using amino/alkyl mixed lithium-zinc combinations.. Chemistry - A European Journal, Wiley-VCH Verlag, 2010, 16 (27), pp.8191-8201. ⟨10.1002/chem.201000543⟩. ⟨hal-00737564⟩
  • Nguyet Trang Thanh Chau, Maxime Meyer, Shinsuke Komagawa, Floris Chevallier, Yves Fort, et al.. Homoleptic zincate-promoted room-temperature halogen-metal exchange of bromopyridines. Chemistry - A European Journal, Wiley-VCH Verlag, 2010, 16, pp.12425-12433. ⟨10.1002/chem.201001664⟩. ⟨hal-01010436⟩
  • Maciej Czachorowski, Steven Lam-Yuk-Tseung, Mathieu Cellier, Philippe Gros. Transmembrane topology of the mammalian Slc11a2 iron transporter.. Biochemistry, American Chemical Society, 2009, 48 (35), pp.8422-34. ⟨10.1021/bi900606y⟩. ⟨pasteur-00819949⟩
  • An-Sheng Zhang, Francois Canonne-Hergaux, Samantha Gruenheid, Philippe Gros, Prem Ponka. Use of Nramp2-transfected Chinese hamster ovary cells and reticulocytes from mk/mk mice to study iron transport mechanisms.. Experimental Hematology, Elsevier, 2008, 36 (10), pp.1227-35. ⟨10.1016/j.exphem.2008.04.014⟩. ⟨hal-00337328⟩
  • Anne Fortier, Chantal de Chastellier, Stéphanie Balor, Philippe Gros. Birc1e/Naip5 rapidly antagonizes modulation of phagosome maturation by Legionella pneumophila.. Cellular Microbiology, Wiley, 2007, 9 (4), pp.910-23. ⟨10.1111/j.1462-5822.2006.00839.x⟩. ⟨hal-00165498⟩
  • Philippe Pierrat, Yves Fort, Philippe C. Gros. First Immobilization of Chiral Menthol-Derived Picoline on Solid Support and Evaluation for Asymmetric Catalysis.. ChemInform, Wiley-VCH Verlag, 2007, 38 (43). ⟨hal-01998685⟩
  • Vinciane Kelsen, Philippe Pierrat, Philippe Gros. Enantioselective ethylation of aldehydes using a regenerable polymer-supported N-picolylvalinol tridentate ligand. Tetrahedron, Elsevier, 2007, 63 (43), pp.10693-10697. ⟨10.1016/j.tet.2007.07.077⟩. ⟨hal-02000362⟩
  • Adam Belley, Mario Callejo, Francis Arhin, Mohammed Dehbi, Ibtihal Fadhil, et al.. Competition of bacteriophage polypeptides with native replicase proteins for binding to the DNA sliding clamp reveals a novel mechanism for DNA replication arrest in Staphylococcus aureus.. Molecular Microbiology, Wiley, 2006, 62 (4), pp.1132-43. ⟨10.1111/j.1365-2958.2006.05427.x⟩. ⟨hal-00194898⟩
  • Philippe Pierrat, Philippe C. Gros, Yves Fort. Unusual tBuLi Induced Ortholithiation versus Halogen?Lithium Exchange in Bromopyridines: Two Alternative Strategies for Functionalization.. SYNLETT, Georg Thieme Verlag, 2005, pp.2319-2322. ⟨10.1055/s-2004-831337⟩. ⟨hal-01998669⟩
  • Philippe Pierrat, Philippe C. Gros, Yves Fort. Hiyama Cross-Coupling of Chloro-, Fluoro-, and Methoxypyridyltrimethylsilanes: Room-Temperature Novel Access to Functional Bi(het)aryl. Organic Letters, American Chemical Society, 2005, 7 (4), pp.697-700. ⟨hal-01998677⟩
  • Philippe Pierrat, Philippe Gros, Yves Fort. Hiyama Cross-Coupling of Chloro-, Fluoro-, and Methoxypyridyltrimethylsilanes: Room-Temperature Novel Access to Functional Bi(het)aryl. Organic Letters, American Chemical Society, 2005, 7 (4), pp.697-700. ⟨10.1021/ol047482u⟩. ⟨hal-02184010⟩
  • Philippe Pierrat, Philippe C. Gros, Yves Fort. Solid Phase Synthesis of Pyridine-Based Derivatives from a 2-Chloro-5-Bromopyridine Scaffold. Journal of Combinatorial Chemistry, American Chemical Society, 2005, 7 (6), pp.879-886. ⟨hal-01998682⟩
  • Jean-Marc Guarini, Philippe Gros, G.F. Blanchard, Patrick Richard, Alain Fillon. Benthic contribution to pelagic microalgal communities in two semi-enclosed, European-type littoral ecosystems (Marennes-Oléron Bay and Aiguillon Bay, France). Journal of Sea Research (JSR), Elsevier, 2004, 52, pp.241-258. ⟨hal-00094891⟩

Conference papers6 documents

  • Philippe Gros. Design of New Iron-based Sensitizers for Light harvesting and Electron-transfer. Euchems, Nitrogen Ligands, Sep 2018, LISBONNE, Portugal. ⟨hal-01898293⟩
  • Stefan Haacke, Li Liu, Edoardo Domenichini, Xavier Assfeld, Philippe Gros, et al.. Ultrafast excited state dynamics of NHC-Fe(II) complexes designed for light harvesting. Advances in Ultrafast Condensed Phase Physics, Apr 2018, Strasbourg, France. pp.28. ⟨hal-01898263⟩
  • Philippe Gros. From Ruthenium to Iron Sensitizers: The Challenging Chemical Tuning of Photophysical Properties. HOPV17, May 2017, Lausanne, Switzerland. ⟨hal-01898299⟩
  • Philippe Gros. From Ruthenium to Iron Sensitizers: A Challenge towards more Ecofriendly Hybrid Solar Cells. 4th USM-UL congress, Jan 2017, PENANG, Malaysia. ⟨hal-01898301⟩
  • Yannick Geerebaert, Denis Bernard, Philippe Bruel, Mickaël Frotin, Berrie Giebels, et al.. Electronics for HARPO: Design, development and validation of electronics for a high performance polarised-Gamma-ray detector. 20th IEEE-NPSS Real Time Conference, Jun 2016, Padua, Italy. ⟨10.1109/RTC.2016.7543098⟩. ⟨hal-03617690⟩
  • Gérard Thouzeau, Philippe Gros. Flux verticaux pelagos-benthos : problématique, méthodologie et instrumentation nouvelle. Instrumentation nouvelle en Océanographie côtière, Nov 1992, Paris, France. pp.91-117. ⟨hal-00524813⟩

Books1 document

  • Philippe Goulletquer, Philippe Gros, Gilles Boeuf, Jacques Weber, Christophe Béné, et al.. Biodiversité en environnement marin.. P. Goulletquer, P. Gros, G. Boeuf & J. Weber. Editions Quae, pp.208, 2012, 978-2-7592-1762-5. ⟨hal-01132629⟩

Book sections2 documents

  • Philippe Cury, Arnaud Bertrand, Sophie Bertrand, Marta Coll, Philippe Gros, et al.. The Ecosystem Approach to Fisheries: Reconciling Conservation and Exploitation. André Monaco; Patrick Prouzet. Tools for Oceanography and Ecosystemic Modeling, John Wiley & Sons, Ltd, pp.221-311, 2016, 978-1-119-33022-6. ⟨10.1002/9781119330226.ch7⟩. ⟨hal-02569970⟩
  • Sophie Girard, Philippe Gros. Raréfaction des ressources halieutiques: l'alternative aquacole ?. Jacquet P., Pachauri R.K. et Tubiana L. (dir). Regards sur la Terre 2011. Océans : la nouvelle frontière, Armand Colin, pp.219-222, 2011. ⟨hal-00838281⟩

Patents1 document

  • Stéphanie Grandemange, Antonio Monari, Philippe Gros, Pierre-François Cartron. Utilisation d'un composé organométallique en tant que qu'agent de déméthylation de l'ADN. France, N° de brevet: FR3088200. BioSiS. 2020. ⟨hal-02987504⟩