Mots-clés

Ruthenium Pigments Photophysics Iron complexes Copper Sensitizers Metalation Heterocycle Acidity Bimetallic bases Anisole aryl aldehyde deprotonation metalation addn ALDEHYDES Solar cells Palladium Zinc Chirality Lithium ABSOLUTE-CONFIGURATION Iron Dyes
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41

Dr Philippe C. GROS, CNRS Research Director

Head of the L2CM (Laboratoire Lorrain de Chimie Moléculaire) UMR7053 (CNRS/Université de Lorraine)  

 

Short biography

Philippe C. Gros studied chemistry at the Universite of Lyon (Lyon, France) and obtained his Ph.D. in 1992 with Dr Pierre Leperchec. He then worked for two years as a postdoctoral fellow with the Isochem Company on phosgenederivative chemistry. In 1994 he entered the CNRS as “Chargé de Recherches” in the Laboratory of Pr. Paul Caubère at Nancy-Université(Lorraine, France). He received his Habilitation (HDR) in 2000 and was appointed “Directeur de Recherches” in 2006. His current research interests include the design of new metalating agents (organolithiums, ate complexes) for the regio- and enantioselective functionalization of heterocycles, structural and reaction mechanism investigation, transition-metal-catalyzed cross-couplings for ligands ynthesis, and the building of photo- and electroactive organometallic materials for various applications including solar energy. He has published more than 110 international peer reviewed papers.

Article dans une revue37 documents

  • Sabrina Touchet, Sai Shradha Reddy Kommidi, Philippe Gros. Organomagnesiate-Promoted Enantioselective Cascade Process: Straightforward Access to Chiral 3-Substituted Isobenzofuranones. ChemistrySelect, Wiley, 2018, 3 (14), pp.3939-3942. 〈10.1002/slct.201800178〉. 〈hal-01813276〉
  • Thibaut Duchanois, Li Liu, Mariachiara Pastore, Antonio Monari, Cristina Cebrian, et al.. NHC-Based Iron Sensitizers for DSSCs. Inorganics, 2018, 6 (2), 〈10.3390/inorganics6020063〉. 〈hal-01825557〉
  • Philippe Gros, Antonio Francés-Monerris, Kevin Magra, Mohamed Darari, Cristina Cebrian, et al.. Synthesis and Computational Study of a Pyridylcarbene Fe(II) Complex: Unexpected Effects of fac / mer Isomerism in Metal-to-Ligand Triplet Potential Energy Surfaces. Inorganic Chemistry, American Chemical Society, 2018, 57 (16), pp.10431 - 10441. 〈10.1021/acs.inorgchem.8b01695〉. 〈hal-01858716〉
  • Ozlem Sengul, Esma Birsen Boydas, Mariachiara Pastore, Walid Sharmouk, Philippe Gros, et al.. Probing optical properties of thiophene derivatives for two-photon absorption. Theoretical Chemistry Accounts: Theory, Computation, and Modeling, Springer Verlag, 2017, 136 (6), 〈10.1007/s00214-017-2094-y〉. 〈hal-01812854〉
  • Michał Łomzik, Olga Mazuryk, Dorota Rutkowska-Zbik, Grażyna Stochel, Philippe Gros, et al.. New ruthenium compounds bearing semicarbazone 2-formylopyridine moiety: Playing with auxiliary ligands for tuning the mechanism of biological activity. Journal of Inorganic Biochemistry, Elsevier, 2017, 175, pp.80-91. 〈10.1016/j.jinorgbio.2017.07.006〉. 〈hal-01813271〉
  • Philippe Pierrat, Stéphanie Hesse, Cristina Cebrian, Philippe Gros. Controlling charge-transfer properties through a microwave-assisted mono- or bis-annulation of dialkynyl-N-(het)arylpyrroles. Organic and Biomolecular Chemistry, Royal Society of Chemistry, 2017, 15 (40), pp.8568 - 8575. 〈10.1039/C7OB02149F〉. 〈hal-01812856〉
  • Robin Cisneros, Marc Beley, François Lapicque, Philippe C. Gros. Hydrophilic Ethylene-Glycol-Based Ruthenium Sensitizers for Aqueous Dye-Sensitized Solar Cells. European Journal of Inorganic Chemistry, Wiley-VCH Verlag, 2016, pp.33-39. 〈10.1002/ejic.201501026〉. 〈hal-01496640〉
  • Olga Mazuryk, Michal Lomzik, David Martineau, Marc Beley, Malgorzata Brindell, et al.. Anticancer activity of ruthenium(II) polypyridine complexes bearing pyrrolidine substituents. Inorganica Chimica Acta, Elsevier, 2016, 443, pp.86-90. 〈10.1016/j.ica.2015.12.021〉. 〈hal-01496645〉
  • Li Liu, Thibaut Duchanois, Thibaud Etienne, Antonio Monari, Marc Beley, et al.. A new record excited state 3 MLCT lifetime for metalorganic iron( ii ) complexes. Physical Chemistry Chemical Physics, Royal Society of Chemistry, 2016, 18 (18), pp.12550-12556. 〈10.1039/C6CP01418F〉. 〈hal-01812755〉
  • Mariachiara Pastore, Thibaut Duchanois, Li Liu, Antonio Monari, Xavier Assfeld, et al.. Interfacial charge separation and photovoltaic efficiency in Fe(ii)–carbene sensitized solar cells. Physical Chemistry Chemical Physics, Royal Society of Chemistry, 2016, 18 (40), pp.28069-28081. 〈10.1039/C6CP05535D〉. 〈hal-01812853〉
  • Walid Walid Sharmoukh, Walid Hassan, Philippe Gros, Nageh Allam. Design and synthesis of new Ru-complexes as potential photo-sensitizers: experimental and TD-DFT insights. RSC Advances, Royal Society of Chemistry, 2016, 6 (73), pp.69647 - 69657. 〈10.1039/C6RA16458G〉. 〈hal-01812852〉
  • Thibaut Duchanois, Thibaud Etienne, Cristina Cebrian, Li Liu, Antonio Monari, et al.. An Iron-Based Photosensitizer with Extended Excited-State Lifetime: Photophysical and Photovoltaic Properties. European Journal of Inorganic Chemistry, Wiley-VCH Verlag, 2015, pp.2469-2477. 〈10.1002/ejic.201500142〉. 〈hal-01495210〉
  • Joelle Char, Emilie Brulé, Philippe C. Gros, Marie-Noelle Rager, Vincent Guérineau, et al.. Synthesis of heterotactic PLA from rac-lactide using hetero-bimetallic Mg/Zn-Li systems. Journal of Organometallic Chemistry, Elsevier, 2015, 796, pp.47-52. 〈10.1016/j.jorganchem.2015.02.038〉. 〈hal-01495967〉
  • Andressa V. Müller, Poliana S. Mendonça, Stéphane Parant, Thibaut Duchanois, Philippe C. Gros, et al.. Effects of Methyl-Substituted Phenanthrolines on the Performance of Ruthenium(II) Dye-Sensitizers. Journal of the Brazilian Chemical Society, Sociedade Brasileira de Química, SBQ, 2015, 26 (11), 〈10.5935/0103-5053.20150208 〉. 〈hal-01496019〉
  • Hugo Gattuso, Thibaut Duchanois, Vanessa Besancenot, Claire Barbieux, Xavier Assfeld, et al.. Interaction of iron II complexes with B-DNA. Insights from molecular modeling, spectroscopy and cellular biology. Frontiers in Chemistry, Frontiers, 2015, 3 (67), 〈10.3389/fchem.2015.00067〉. 〈hal-01242500〉
  • Javier Francos, Philippe C. Gros, Alan R. Kennedy, Charles T. O'Hara. Structural Studies of (rac)-BIPHEN Organomagnesiates and Intermediates in the Halogen-Metal Exchange of 2-Bromopyridine. Organometallics, American Chemical Society, 2015, 34 (11), pp.2550-2557. 〈10.1021/om501225g〉. 〈hal-01495973〉
  • Walid Sharmoukh, Antonio Attanzio, Eva Busatto, Thibaud Etienne, Stefano Carli, et al.. 2,5-Dithienylpyrrole (DTP) as a donor component in DTP-pi-A organic sensitizers: photophysical and photovoltaic properties. RSC Advances, Royal Society of Chemistry, 2015, 5 (6), pp.4041-4050. 〈10.1039/c4ra10342d〉. 〈hal-01495200〉
  • Walid Sharmoukh, Antonio Attanzio, Eva Busatto, Thibaud Etienne, Stefano Carli, et al.. 2,5-Dithienylpyrrole (DTP) as a donor component in DTP–π–A organic sensitizers: photophysical and photovoltaic properties. RSC Advances, Royal Society of Chemistry, 2015, 5 (6), pp.4041 - 4050. 〈10.1039/C4RA10342D〉. 〈hal-01913513〉
  • Sajida Noureen, Roberto Argazzi, Antonio Monari, Marc Beley, Xavier Assfeld, et al.. Novel Ru-based sunlight harvesters bearing dithienylpyrrolo (DTP)-bipyridine ligands: Synthesis, characterization and photovoltaic properties. Dyes and Pigments, Elsevier, 2014, 101, pp.318-328. 〈10.1016/j.dyepig.2013.10.013〉. 〈hal-01494554〉
  • Thibaut Duchanois, Thibaud Etienne, Marc Beley, Xavier Assfeld, Eric A. Perpete, et al.. Heteroleptic Pyridyl-Carbene Iron Complexes with Tuneable Electronic Properties. European Journal of Inorganic Chemistry, Wiley-VCH Verlag, 2014, pp.3747-3753. 〈10.1002/ejic.201402356〉. 〈hal-01494414〉
  • David Tilly, Floris Chevallier, Florence Mongin, Philippe C. Gros. Bimetallic Combinations for Dehalogenative Metalation Involving Organic Compounds. Chemical Reviews, American Chemical Society, 2014, 114 (2), pp.1207--1257. 〈10.1021/cr400367p〉. 〈hal-01153814〉
  • Marc Beley, Philippe C. Gros. Ruthenium Polypyridine Complexes Bearing Pyrroles and pi-Extended Analogues. Synthesis, Spectroelectronic, Electrochemical, and Photovoltaic Properties. Organometallics, American Chemical Society, 2014, 33 (18), pp.4590-4606. 〈10.1021/om5002183〉. 〈hal-01494565〉
  • Nada Marquise, Guillaume Bretel, Frédéric Lassagne, Floris Chevallier, Thierry Roisnel, et al.. Deproto-metallation using mixed lithium-zinc and lithium-copper bases and computed CH acidity of 2-substituted quinolines. RSC Advances, Royal Society of Chemistry, 2014, 4, pp.19602. 〈10.1039/c4ra02583k〉. 〈hal-01002410〉
  • Raghu Ram Kadiyala, David Tilly, Elisabeth Nagaradja, Thierry Roisnel, Vadim E. Matulis, et al.. Computed CH acidity of biaryl compounds and their deprotonative metalation by using a mixed lithium/zinc-TMP base.. Chemistry - A European Journal, Wiley-VCH Verlag, 2013, 19, pp.7944--7960. 〈10.1002/chem.201300552〉. 〈hal-01069722〉
  • Nada Marquise, Philip Harford, Floris Chevallier, Thierry Roisnel, Vincent Dorcet, et al.. Synthesis of azafluorenones and related compounds using deprotocupration-aroylation followed by intramolecular direct arylation. Tetrahedron, Elsevier, 2013, 69 (47), pp.10123-10133. 〈10.1016/j.tet.2013.09.030〉. 〈hal-00869376〉
  • Nada Marquise, Philip J. Harford, Floris Chevallier, Thierry Roisnel, Andrew E. H. Wheatley, et al.. Efficient two-step access to azafluorenones and related compounds. Tetrahedron Letters, Elsevier, 2013, 54 (24), pp.3154-3157. 〈10.1016/j.tetlet.2013.04.020〉. 〈hal-00871003〉
  • Mebarek Bahnous, Abdelmalek Bouraiou, Meryem Chelghoum, Sofiane Bouacida, Thierry Roisnel, et al.. Synthesis, crystal structure and antibacterial activity of new highly functionalized ionic compounds based on the imidazole nucleus. Bioorganic and Medicinal Chemistry Letters, Elsevier, 2013, 23 (5), pp.1274-1278. 〈10.1016/j.bmcl.2013.01.004〉. 〈hal-01494086〉
  • Gandrath Dayaker, David Tilly, Floris Chevallier, Göran Hilmersson, Philippe C. Gros, et al.. Enantioselective Metalation of N,N-Diisopropylferrocenecarboxamide and Methyl Ferrocenecarboxylate Using Lithium-Metal Chiral Bases. European Journal of Organic Chemistry, Wiley-VCH Verlag, 2012, pp.6051-6057. 〈10.1002/ejoc.201200965〉. 〈hal-01053773〉
  • Delphine Catel, Floris Chevallier, Florence Mongin, Philippe C. Gros. Chiral organomagnesiates as dual reagents for bromine-magnesium exchange of 2-bromopyridine and access to chiral α-substituted 2-pyridylcarbinols. European Journal of Organic Chemistry, Wiley-VCH Verlag, 2012, pp.53-57. 〈10.1002/ejoc.201101490〉. 〈hal-01053767〉
  • David Tilly, Katia Snegaroff, Gandrath Dayaker, Floris Chevallier, Philippe C. Gros, et al.. (Chiral) lithium-(magnesium-)zinc and lithium-cobalt combinations as dual reagents for aromatic deproto-metalation and aryl transfer to aldehydes.. Tetrahedron, Elsevier, 2012, 68, pp.8761--8766. 〈10.1016/j.tet.2012.08.008〉. 〈hal-01070070〉
  • Olivier Payen, Floris Chevallier, Florence Mongin, Philippe Gros. Straightforward access to enantioenriched pyrazyl alcohols using chiral organomagnesiates. Tetrahedron: Asymmetry, Elsevier, 2012, 23 (34), pp.1678-1682. 〈10.1016/j.tetasy.2012.11.003〉. 〈hal-00813094〉
  • Katia Snégaroff, Tan Tai Nguyen, Nada Marquise, Yury S. Halauko, Philip J. Harford, et al.. Deprotonative metalation of chloro- and bromopyridines using amido-based bimetallic species and regioselectivity-computed CH acidity relationships.. Chemistry - A European Journal, Wiley-VCH Verlag, 2011, 17 (47), pp.13284. 〈10.1002/chem.201101993〉. 〈hal-00735265〉
  • Maqsood Ahmed, Sajida Noureen, Philippe Gros, Benoît Guillot, Christian Jelsch. 2,2′-(Ethane-1,2-diyl)bis[2-(5-bromothiophen-2-yl)-1,3-dioxolane] at 100 K refined using a multipolar atom model. Acta Crystallographica Section C: Crystal Structure Communications, International Union of Crystallography, 2011, 67 (8), pp.o329 - o333. 〈10.1107/S0108270111027247〉. 〈hal-01713014〉
  • Katia Snégaroff, Shinsuke Komagawa, Floris Chevallier, Philippe Gros, Stéphane Golhen, et al.. Deprotonative metalation of substituted benzenes and heteroaromatics using amino/alkyl mixed lithium-zinc combinations.. Chemistry - A European Journal, Wiley-VCH Verlag, 2010, 16 (27), pp.8191-8201. 〈10.1002/chem.201000543〉. 〈hal-00737564〉
  • Nguyet Trang Thanh Chau, Maxime Meyer, Shinsuke Komagawa, Floris Chevallier, Yves Fort, et al.. Homoleptic zincate-promoted room-temperature halogen-metal exchange of bromopyridines. Chemistry - A European Journal, Wiley-VCH Verlag, 2010, 16, pp.12425-12433. 〈10.1002/chem.201001664〉. 〈hal-01010436〉
  • Gandrath Dayaker, Floris Chevallier, Philippe C. Gros, Florence Mongin. Deprotonative metalation of substituted aromatics using mixed lithium-cobalt combinations. Tetrahedron, Elsevier, 2010, 66, pp.8904-8910. 〈10.1016/j.tet.2010.09.053〉. 〈hal-01010453〉
  • Katia Snégaroff, Shinsuke Komagawa, M. Yonehara, Floris Chevallier, Philippe Gros, et al.. Lithium cadmate-mediated deprotonative metalation of anisole: experimental and computational study. Journal of Organic Chemistry, American Chemical Society, 2010, 75 (9), pp.3117-3120. 〈10.1021/jo100150S〉. 〈hal-00785078〉

Communication dans un congrès4 documents

  • Philippe Gros. Design of New Iron-based Sensitizers for Light harvesting and Electron-transfer. Euchems, Nitrogen Ligands, Sep 2018, LISBONNE, Portugal. 〈hal-01898293〉
  • Stefan Haacke, Li Liu, Edoardo Domenichini, Xavier Assfeld, Philippe Gros, et al.. Ultrafast excited state dynamics of NHC-Fe(II) complexes designed for light harvesting. Advances in Ultrafast Condensed Phase Physics, Apr 2018, Strasbourg, France. 〈hal-01898263〉
  • Philippe Gros. From Ruthenium to Iron Sensitizers: A Challenge towards more Ecofriendly Hybrid Solar Cells. 4th USM-UL congress, Jan 2017, PENANG, Malaysia. 〈hal-01898301〉
  • Philippe Gros. From Ruthenium to Iron Sensitizers: The Challenging Chemical Tuning of Photophysical Properties. HOPV17, May 2017, Lausanne, Switzerland. 〈hal-01898299〉