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Effect of the Metal on metal-based Disulfide/Thiolate Interconversion: Manganese versus Cobalt

Marcello Gennari , Deborah Brazzolotto , Shengying Yu , Jacques Pécaut , Christian Philouze , et al.
Chemistry - A European Journal, 2015, 21 (51), pp.18770-18778. ⟨10.1002/chem.201502996⟩
Article dans une revue hal-01441956v1

A Bio-Inspired Switch Based on Cobalt(II) Disulfide/Cobalt(III) Thiolate Interconversion

Marcello Gennari , Bertrand Gerey , Nikita Hall , Jacques Pécaut , Marie-Nöelle Collomb , et al.
Angewandte Chemie International Edition, 2014, 53 (21), pp.5318-5321. ⟨10.1002/anie.201402125⟩
Article dans une revue istex hal-01979862v1
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O2 Activation by Non-Heme Thiolate-Based Dinuclear Fe Complexes

Lianke Wang , Marcello Gennari , Fabián Cantú Reinhard , Sandeep Padamati , Christian Philouze , et al.
Inorganic Chemistry, 2020, 59 (5), pp.3249-3259. ⟨10.1021/acs.inorgchem.9b03633⟩
Article dans une revue hal-03012269v1
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Bio-inspired, Multifunctional Metal–Thiolate Motif: From Electron Transfer to Sulfur Reactivity and Small-Molecule Activation

Marcello Gennari , Carole Duboc
Accounts of Chemical Research, 2020, 53 (11), pp.2753-2761. ⟨10.1021/acs.accounts.0c00555⟩
Article dans une revue hal-03012179v1

Experimental and Computational Investigation of Thiolate Alkylation in Ni II and Zn II Complexes: Role of the Metal on the Sulfur Nucleophilicity

Marcello Gennari , Marius Retegan , Serena Debeer , Jacques Pécaut , Frank Neese , et al.
Inorganic Chemistry, 2011, 50 (20), pp.10047 - 10055. ⟨10.1021/ic200899w⟩
Article dans une revue hal-01655259v1

Long-Lived Charge Separated State in NiO-Based p-Type Dye-Sensitized Solar Cells with Simple Cyclometalated Iridium Complexes

Marcello Gennari , Florent Légalité , Lei Zhang , Yann Pellegrin , Errol Blart , et al.
Journal of Physical Chemistry Letters, 2014, 5 (13), pp.2254 - 2258. ⟨10.1021/jz5009714⟩
Article dans une revue hal-01652237v1
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Characterization of model soil colloids by cryo-scanning electron microscopy.

M. Nègre , P . Leone , Jean Trichet , Christian Défarge , V. Boero , et al.
Geoderma, 2004, 121, pp.1-2, 1-16. ⟨10.1016/j.geoderma.2003.09.011⟩
Article dans une revue hal-00069152v1

Molecular Catalysts for N 2 Reduction: State of the Art, Mechanism, and Challenges

Yoann Roux , Carole Duboc , Marcello Gennari
ChemPhysChem, 2017, 18 (19), pp.2606 - 2617. ⟨10.1002/cphc.201700665⟩
Article dans une revue hal-01639818v1
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Dioxygen Activation and Catalytic Reduction to Hydrogen Peroxide by a Thiolate-Bridged Dimanganese(II) Complex with a Pendant Thiol

Marcello Gennari , Deborah Brazzolotto , Jacques Pécaut , Mickael V Cherrier , Christopher J. Pollock , et al.
Journal of the American Chemical Society, 2015, 137 (26), pp.8644-8653. ⟨10.1021/jacs.5b04917⟩
Article dans une revue hal-01174446v1

Tuning Reactivity of Bioinspired [NiFe]-Hydrogenase Models by Ligand Design and Modeling the CO Inhibition Process

Deborah Brazzolotto , Lianke Wang , Hao Tang , Marcello Gennari , Nicolas Queyriaux , et al.
ACS Catalysis, 2018, 8 (11), pp.10658-10667. ⟨10.1021/acscatal.8b02830⟩
Article dans une revue hal-01938358v1

Visible Light-Driven Electron Transfer from a Dye-Sensitized p-Type NiO Photocathode to a Molecular Catalyst in Solution: Toward NiO-Based Photoelectrochemical Devices for Solar Hydrogen Production

Carmen E. Castillo , M. Gennari , T. Stoll , J. Fortage , A. Deronzier , et al.
Journal of Physical Chemistry C, 2015, 119 (11), pp.5806-5818. ⟨10.1021/jp511469f⟩
Article dans une revue hal-01588166v1
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Nickel-centred proton reduction catalysis in a model of [NiFe] hydrogenase.

Deborah Brazzolotto , Marcello Gennari , Nicolas Queyriaux , Trevor R. Simmons , Jacques Pécault , et al.
Nature Chemistry, 2016, 8 (11), pp.1054-1060. ⟨10.1038/nchem.2575⟩
Article dans une revue hal-01386604v1

Multifrequency cw-EPR and DFT Studies of an Apparent Compressed Octahedral Cu(II) Complex

Nikita Hall , Maylis Orio , Marcello Gennari , Christopher C. Wills , Florian Molton , et al.
Inorganic Chemistry, 2016, 55 (4), pp.1497 - 1504. ⟨10.1021/acs.inorgchem.5b02287⟩
Article dans une revue hal-01644694v1

Electronic structure investigation of mononuclear CoII thiolate complexes: an experimental and theoretical study

M. Gennari , B. Gerey , N. Hall , H. Vezin , M.N. Collomb , et al.
Réunion de l'Association française de Résonance Paramagnétique Electronique, Mar 2013, Autrans, France
Communication dans un congrès hal-00830602v1

Reversible Apical Coordination of Imidazole between the Ni(III) and Ni(II) Oxidation States of a Dithiolate Complex: A Process Related to the Ni Superoxide Dismutase

Marcello Gennari , Maylis Orio , Jacques Pécaut , Frank Neese , Marie-Noëlle Collomb , et al.
Inorganic Chemistry, 2010, 49 (14), pp.6399 - 6401. ⟨10.1021/ic100945n⟩
Article dans une revue hal-01658568v1

On the Road to MM′X Polymers: Redox Properties of Heterometallic Ni···Pt Paddlewheel Complexes

Marcello Gennari , Gonzalo Givaja , Oscar Castillo , Laura Hermosilla , Carlos J. Gomez-Garcia , et al.
Inorganic Chemistry, 2014, 53 (19), pp.10553 - 10562. ⟨10.1021/ic501659x⟩
Article dans une revue hal-01652325v1

Structural, spectroscopic and redox properties of a mononuclear CoII thiolate complex - the reactivity toward S-alkylation: an experimental and theoretical study

M. Gennari , B. Gerey , Nikita Hall , J. Pécaut , H. Vezin , et al.
Dalton Transactions, 2012, 41, pp.12586 - 12594. ⟨10.1039/C2DT31222K⟩
Article dans une revue hal-00744947v1

Experimental Techniques for Determining Spin States

Carole Duboc , Marcello Gennari
Experimental techniques for determining spin states, John Wiley & Sons, Ltd, pp.59-83, 2015
Chapitre d'ouvrage hal-02022137v1

Confinement of molecular complexes for catalytic N2 reduction

Ashta C. Ghosh , Matthieu Koepf , Marcello Gennari
International Winter School (ICS2019) on Innovative Catalysis and Sustainability, Jan 2019, Bardonecchia (présentiel), Italy
Poster de conférence hal-04176843v1

Confinement of molecular complexes for catalytic N2 reduction

Ashta C. Ghosh , Matthieu Koepf , Marcello Gennari
Journée scientifique ARCANE, Jun 2019, Grenoble (Présentiel), France
Communication dans un congrès hal-04178891v1

Insulin sensor based on nanoparticle-decorated multiwalled carbon nanotubes modified electrodes

Emiliano Martínez-Periñán , Mónica Revenga-Parra , Marcello Gennari , Félix Pariente , Rubén Mas-Ballesté , et al.
Sensors and Actuators B: Chemical, 2016, 222, pp.331-338
Article dans une revue hal-02022135v1
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An experimental and theoretical investigation on pentacoordinated cobalt(III) complexes with an intermediate S=1 spin state: How halide ligands affect their magnetic anisotropy

Deborah Brazzolotto , Marcello Gennari , Shengying Yu , Jacques Pecaut , Mathieu Rouzieres , et al.
Chemistry - A European Journal, 2015, 22 (3), pp.925-933. ⟨10.1002/chem.201502997⟩
Article dans une revue hal-01366392v1

Heterogenization of a [NiFe] Hydrogenase Mimic through Simple and Efficient Encapsulation into a Mesoporous MOF

Davide Balestri , Yoann Roux , Monica Mattarozzi , Claudio Mucchino , Heux Laurent , et al.
Inorganic Chemistry, 2017, 56 (24), pp.14801-14808. ⟨10.1021/acs.inorgchem.7b01824⟩
Article dans une revue hal-02154087v1

A Fully Delocalized Mixed-Valence Bis-μ(Thiolato) Dicopper Complex: A Structural and Functional Model of the Biological CuA Center

Marcello Gennari , Jacques Pécaut , Serena Debeer , Frank Neese , Marie-Noëlle Collomb , et al.
Angewandte Chemie International Edition, 2011, 50 (25), pp.5662 - 5666. ⟨10.1002/anie.201100605⟩
Article dans une revue istex hal-01655181v1

Highly dense nickel hydroxide nanoparticles catalyst electrodeposited from a novel Ni(II) paddle–wheel complex

Emiliano Martínez-Periñán , Marcello Gennari , Mónica Revenga-Parra , José M. Abad , Eva Mateo-Marti , et al.
Chinese Journal of Catalysis, 2015, 329, pp.22 - 31. ⟨10.1016/j.jcat.2015.04.010⟩
Article dans une revue hal-01651066v1

Experimental and Theoretical Identification of the Origin of Magnetic Anisotropy in Intermediate Spin Iron(III) Complexes

Franc Wang , Matija Zlatar , Filip Vlahović , Serhiy Demeshko , Christian Philouze , et al.
Chemistry - A European Journal, 2018, 24 (20), pp.5091 - 5094. ⟨10.1002/chem.201705989⟩
Article dans une revue hal-01847096v1

An efficient RuII-RhIII-RuII polypyridyl photocatalyst for visible-light-driven hydrogen production in aqueous solution

T. Stoll , M. Gennari , J. Fortage , C.E. Castillo , M. Rebarz , et al.
Angewandte Chemie International Edition, 2014, 53 (6), pp.1654-1658. ⟨10.1002/anie.201308132⟩
Article dans une revue hal-00950597v1

A High‐Valent Non‐Heme μ‐Oxo Manganese(IV) Dimer Generated from a Thiolate‐Bound Manganese(II) Complex and Dioxygen

Déborah Brazzolotto , Fabián G. Cantú reinhard , Julian Smith-Jones , Marius Retegan , Lucia Amidani , et al.
Angewandte Chemie International Edition, 2017, 56 (28), pp.8211-8215. ⟨10.1002/anie.201703215⟩
Article dans une revue hal-02154187v1
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A non-heme diiron complex for (electro)catalytic reduction of dioxygen: tuning the selectivity through electron-delivery

Lianke Wang , Marcello Gennari , Fabián G. Cantú reinhard , Javier Gutiérrez , Adina Morozan , et al.
Journal of the American Chemical Society, 2019, 141 (20), pp.8244-8253. ⟨10.1021/jacs.9b02011⟩
Article dans une revue hal-02119043v1
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Synergy between metals for small molecule activation: Enzymes and bio-inspired complexes

Ashta Ghosh , Carole Duboc , Marcello Gennari
Coordination Chemistry Reviews, 2021, 428, pp.213606. ⟨10.1016/j.ccr.2020.213606⟩
Article dans une revue hal-03012204v1