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31

Water - rock interactions at the pore scale

Topics: Fluid-rocks interactions at the pore scale, interfacial processes, porosity-permeability-reactivity loop

Targets: aquifers, caprocks and natural/anthropized unsaturated media

Tools: thermodynamics, vibrational spectroscopy, micro/nano-fluidic experiments

Responsabilities:

2011-present: member of the steering committee of the doctoral school (ED) 552 Energy, Materials, Earth and Universe Sciences (EMSTU), joint structure of the Universities of Orléans and Tours.

2015-present : elected member, Conseil National des Universités, section 35 (‘Structure and evolution of Earth and other planets’).

01/08/2017-present : Director of ISTO.

Teaching: Thermodynamics of natural systems, thermochemistry, environmental geochemistry, hydrogeology

Journal articles22 documents

  • Claudie Hulin, Lionel Mercury. Regeneration of capillary water in unsaturated zones. Geochimica et Cosmochimica Acta, Elsevier, 2019, 265, pp.279-291. ⟨10.1016/j.gca.2019.07.058⟩. ⟨insu-02267563⟩
  • Claudie Hulin, Lionel Mercury. Capillarity-driven supersolubility in dual-porosity systems. Geochimica et Cosmochimica Acta, Elsevier, 2019, 252, pp.144-158. ⟨10.1016/j.gca.2019.02.026⟩. ⟨insu-02043546⟩
  • O. Crabeck, R. Galley, Lionel Mercury, B. Delille, L. Tison, et al.. Evidence of freezing pressure in sea ice discrete brine inclusions and its impact on aqueous-gaseous equilibrium. Journal of Geophysical Research. Oceans, Wiley-Blackwell, 2019, 124, pp.1660-1678. ⟨10.1029/2018JC014597⟩. ⟨insu-02005429⟩
  • Yves Krüger, Lionel Mercury, Aurélien Canizares, Dominik Marti, Patrick Simon. Metastable phase equilibria in the ice II stability field. A Raman study of synthetic high-density water inclusions in quartz. Physical Chemistry Chemical Physics, Royal Society of Chemistry, 2019, pp.19554-19566. ⟨10.1039/c9cp03647d⟩. ⟨insu-02274539⟩
  • Dhirendra Tiwari, Lionel Mercury, Marcel Dijkstra, Himanshu Chaudhary, José-Federico Hernandez-Sanchez. Post-pinch-off relaxation of two-dimensional droplets in a Hele-Shaw cell. Physical Review Fluids, American Physical Society, 2018, 3 (12), Article : 124202 (12 p.). ⟨10.1103/physrevfluids.3.124202⟩. ⟨insu-01950861⟩
  • Khalifa Nsir, Gerhard Schäfer, Raphaël Di Chiararoupert, Lionel Mercury. Pore scale modelling of DNAPL migration in a water–saturated porous medium. Journal of Contaminant Hydrology, Elsevier, 2018, 215, pp.39-50. ⟨10.1016/j.jconhyd.2018.07.001⟩. ⟨insu-01856217⟩
  • F Baum, Diane Rébiscoul, S Tardif, N Tas, Lionel Mercury, et al.. X-Ray Reflectivity Analysis of SiO2 Nanochannels Filled with Water and Ions: A New Method for the Determination of the Spatial Distribution of Ions Inside Confined Media. Procedia Earth and Planetary Science, Elsevier, 2017, 15th Water-Rock Interaction International Symposium, WRI-15, 17, pp.682 - 685. ⟨10.1016/j.proeps.2016.12.146⟩. ⟨insu-01440178⟩
  • Isabelle Bergonzi, Lionel Mercury, Patrick Simon, Frederic Jamme, Kirill Shmulovich. Oversolubility in the microvicinity of solid-solution interfaces. Physical Chemistry Chemical Physics, Royal Society of Chemistry, 2016, 18, pp.14874-14885. ⟨10.1039/C5CP08012F⟩. ⟨insu-01308355⟩
  • Lionel Mercury, Kirill Shmulovich, Isabelle Bergonzi, Aurélien Canizarès, Patrick Simon. Growing Negative Pressure in Dissolved Solutes: Raman Monitoring of Solvent-Pulling Effect. Journal of Physical Chemistry C, American Chemical Society, 2016, 120, pp.7697-7704. ⟨10.1021/acs.jpcc.6b01700⟩. ⟨insu-01293221⟩
  • Kirill Shmulovich, Lionel Mercury. Size Effect in Metastable Water. Petrology, MAIK Nauka/Interperiodica, 2014, 22 (4), pp.418-428. ⟨10.1134/S0869591114030060⟩. ⟨insu-01018693⟩
  • Isabelle Bergonzi, Lionel Mercury, Jean-Blaise Brubach, Pascale Roy. Gibbs free energy of liquid water derived from infrared measurements. Physical Chemistry Chemical Physics, Royal Society of Chemistry, 2014, 16, pp.24830 - 24830. ⟨10.1039/c4cp03466j⟩. ⟨insu-01090133⟩
  • Izzeddine Sameut-Bouhaik, Philippe Leroy, Patrick Ollivier, Mohamed Azaroual, Lionel Mercury. Influence of surface conductivity on the apparent zeta potential of TiO2 nanoparticles: application to the modeling of their aggregation kinetics. Journal of Colloid and Interface Science, Elsevier, 2013, 406, pp.75-85. ⟨10.1016/j.jcis.2013.05.034⟩. ⟨insu-00832278⟩
  • Lionel Mercury. Macroscopic Thermodynamics of Interfaces at Water Pore Scales: Effects on Water-Rock Interactions and Mass Transfer. Procedia Earth and Planetary Science, Elsevier, 2013, 7, pp.586-589. ⟨10.1016/j.proeps.2013.03.145⟩. ⟨insu-00819848⟩
  • Lionel Mercury, Frédéric Jamme, Paul Dumas. Infra-red imaging of bulk water and water-solid interfaces under stable and metastable conditions.. Physical Chemistry Chemical Physics, Royal Society of Chemistry, 2012, 14, pp.2864-2874. ⟨10.1039/C2CP23221A⟩. ⟨insu-00655736⟩
  • Tadashi Yokoyamaama, Satoru Nakashima, Takashi Murakami, Lionel Mercury, Yusuke Kirino. Solute distribution in porous rhyolite as evaluated by sequential centrifugation. Applied Geochemistry, Elsevier, 2011, 26 (8), pp.1524-1534. ⟨10.1016/j.apgeochem.2011.06.017⟩. ⟨insu-00602697⟩
  • Majda Bouzid, Lionel Mercury, Arnault Lassin, Jean-Michel Matray, Mohamed Azaroual. In-Pore stress by drying-induced capillary bridges inside porous materials.. Journal of Colloid and Interface Science, Elsevier, 2011, 355, pp.494-502. ⟨10.1016/j.jcis.2010.12.058⟩. ⟨insu-00551322⟩
  • Majda Bouzid, Lionel Mercury, Arnault Lassin, Jean-Michel Matray. Salt precipitation and trapped liquid cavitation in micrometric capillary tubes.. Journal of Colloid and Interface Science, Elsevier, 2011, 360 (2), pp.768-776. ⟨10.1016/j.jcis.2011.04.095⟩. ⟨insu-00589810⟩
  • Régis Thiery, Lionel Mercury. Explosive properties of water in volcanic and hydrothermal systems. Journal of Geophysical Research : Solid Earth, American Geophysical Union, 2009, 114 (B05205), pp.1-19. ⟨10.1029/2008JB005742⟩. ⟨insu-00403839⟩
  • Régis Thiery, Lionel Mercury. Explosivity Conditions of Aqueous Solutions. Journal of Solution Chemistry, Springer Verlag (Germany), 2009, 38 (7), pp.893-905. ⟨10.1007/s10953-009-9417-0⟩. ⟨insu-00403838⟩
  • Kirill Shmulovich, Lionel Mercury, Régis Thiery, Claire Ramboz, Mouna El Mekki. Experimental superheating of water and aqueous solutions. Geochimica et Cosmochimica Acta, Elsevier, 2009, 73, pp.2457-2470. ⟨10.1016/j.gca.2009.02.006⟩. ⟨insu-00371852⟩
  • Marie Pettenati, Lionel Mercury, Mohamed Azaroual. Capillary geochemistry in non-saturated zone of soils. Water content and geochemical signatures.. Applied Geochemistry, Elsevier, 2008, 23, pp.3799-3818. ⟨10.1016/j.apgeochem.2008.10.002⟩. ⟨insu-00356838⟩
  • M. Bouzid, Lionel Mercury, J.M. Matray. interactions solides-solution dans les milieux confinés. institut de radioprotection et de sûreté nucléaire, 2007, DEI/SARG (2006-044), 48 pp. ⟨hal-00386230⟩

Book sections8 documents

  • Lionel Mercury, Kirill Shmulovich. Experimental superheating and cavitation of water and solutions at spinodal-like negative pressures. Transport and Reactivity of Solutions in Confined Hydrosystems, Springer, pp.159-171, 2014, Series: NATO Science for Peace and Security Series C: Environmental Security, 978-94-007-7533-6. ⟨10.1007/978-94-007-7534-3_14⟩. ⟨insu-00906681⟩
  • Lionel Mercury, Niel Tas, Michael Zilberbrand. Confined water in complex networks: unifying our understanding of pore water and solutes at all scales. Mercury, Lionel; Tas, Niels; Zilberbrand, Michael (Eds.). Transport and Reactivity of Solutions in Confined Hydrosystems, Springer, 3 p., 2014, Series: NATO Science for Peace and Security Series C: Environmental Security, 978-94-007-7533-6. ⟨insu-00908738⟩
  • Isabelle Bergonzi, Lionel Mercury. Infrared-Thermodynamics Conversion as a Function of Temperature: Towards Confined Water. Mercury, Lionel; Tas, Niels; Zilberbrand, Michael (Eds.). Transport and Reactivity of Solutions in Confined Hydrosystems, Springer, pp.43-53, 2013, Series: NATO Science for Peace and Security Series C: Environmental Security, ⟨10.1007/978-94-007-7534-3_4⟩. ⟨insu-00906892⟩
  • Arnault Lassin, Lionel Mercury, Mohamed Azaroual. Geochemistry of Capillary Hydrogeochemical Systems in Arid Environments. Mercury, Lionel; Tas, Niels; Zilberbrand, Michael (Eds.). Transport and Reactivity of Solutions in Confined Hydrosystems, Springer, pp.213-221, 2013, Series: NATO Science for Peace and Security Series C: Environmental Security, ⟨10.1007/978-94-007-7534-3_18⟩. ⟨insu-00906685⟩
  • Lionel Mercury, Michael Zilberbrand. Thermodynamics of gas and mineral solubility in the unsaturated-zone water. Michael Zilberbrand. Geochemical Modeling of Groundwater, Vadose and Geothermal Systems, CRC Press, pp.27-43, 2011, 978-0-415-66810-1. ⟨10.1201/b11394-4⟩. ⟨insu-00752634⟩
  • Mouna El Mekki, Claire Ramboz, Laurent Perdereau, Kirill Shmulovich, Lionel Mercury. Lifetime of superheated water in a micrometric synthetic fluid inclusion. Metastable Systems under Pressure, Springer Verlag, pp.279-292, 2010. ⟨insu-00460565⟩
  • Kirill Shmulovich, Lionel Mercury. Vapour nucleation in metastable water and solutions by synthetic fluid inclusion method.. Metastable System Under Pressure, Springer, pp.311-322, 2010. ⟨insu-00462273⟩
  • Régis Thiery, Sébastien Loock, Lionel Mercury. Explosive properties of superheated aqueous solutions in volcanic and hydrothermal systems. Metastable Systems under Pressure, Springer, pp.293-310, 2010. ⟨insu-00460799⟩

Habilitation à diriger des recherches1 document

  • Lionel Mercury. SUR CERTAINS ETATS EXOTIQUES DE L’EAU LIQUIDE EN MILIEU NATUREL. Sciences of the Universe [physics]. Université Paris-Sud, 2006. ⟨tel-02081078⟩