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Laurent Delbreilh

Dr. Laurent DELBREILH Associate Professor in the University of Rouen since September 2006 Section CNU : 28 Physics Researcher in Physics Researcher in GPM laboratory, UMR CNRS 6634, Co-Coordinator of « Physics Mention » Licence at the University of Rouen. Coordinator of Material Science specialty 3rd year Licence at University of Rouen Member of l’Association Française de Calorimétrie et d'Analyse Thermique (AFCAT) et de l’International Committee of Thermal Analysis and Calorimetry (ICTAC) depuis 2008. Education 2016 : “Habilitation à Diriger la Recherche” HDR 2004 : PhD. Of the University of Toulouse (F) in Polymer Physics Current Position Since 2016: Maître de Conférences HDR/ Associate Professor in the Physics research Department of the University of Rouen. Since 2014 : Visiting Adjunct Research Professor at the Mechanical and Materials Engineering department at University of Nebraska Lincoln (UNL) USA 2006/2016 : Maitre de conférences/Assistant Professor in the Physics research Department of the University of Rouen 2004/2006 : Assistant in the Physics research Department of the University of Rouen. Supervision Activities 50 Students in Master Degree 11 Students in PhD Thesis Scientific Activities: My research activities mainly concern the field of the physics of glasses, physics of disordered matter and more particularly the physics of polymers and nowadays of biopolymers. I work more specifically on the study of dynamics in amorphous phases, mainly in polymers but also for other glass formers. The various works that I have implemented, or in which I have participated, are at the intersection of two issues: - A more fundamental theme which aims to understand the physical mechanisms and the laws of behavior for glass-forming liquids below and above the glass transition temperature. - A theme with a more "materials" approach aimed at studying the impact of modifications of amorphous phases, in a physicochemical manner. This produces different relaxation environments. The principle of the environment is seen here in the broad sense since under this term we can group together: - microstructures in the case of semi-crystalline polymers - geometric confinement - fillers or nano-fillers in the case of composites - additives - nano-texturing ... These two approaches are most often interconnected in my work since the fundamental understanding of relaxation phenomena in amorphous "model" materials allows a more precise reading of the phenomena observed during an application on more complex materials.
28
Documents

Présentation

Domaines de recherche

Matière Molle [cond-mat.soft] Science des matériaux [cond-mat.mtrl-sci] Physique [physics] Matériaux

Publications

nicolas-delpouve

Glass and sub-glass relaxation changes induced by thermal ageing of epoxy-amine polymer networks – A DMA study

Romain Delannoy , Blandine Quelennec , Vincent Tognetti , Laurent Delbreilh , Nicolas Delpouve
Polymer Degradation and Stability, 2023, 216, pp.110487. ⟨10.1016/j.polymdegradstab.2023.110487⟩
Article dans une revue hal-04271921v1

Enzymatic degradation and ageing of additively manufactured soy-based scaffolds for cell-cultured meat

A. Garrett , K.L.M. Avegnon , Laurent Delbreilh , Nicolas Delpouve , M.P. Sealy
CIRP Annals - Manufacturing Technology, 2023, ⟨10.1016/j.cirp.2023.04.020⟩
Article dans une revue hal-04111741v1
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Effect of physical and chemical ageing on barrier properties of epoxy coating

Blandine Quelennec , Zhibo Duan , Romain Delannoy , Nicolas Gay , Matthieu Briffaut
Construction and Building Materials, 2023, 409, pp.133908. ⟨10.1016/j.conbuildmat.2023.133908⟩
Article dans une revue hal-04272058v1

Post‐curing and structural relaxation of epoxy networks during early stages of aging for civil engineering applications

Sanaa Oumnas , Blandine Quelennec , Emmanuel Richaud , Alexis Duthoit , Nicolas Delpouve
Applied Research, 2023, ⟨10.1002/appl.202200090⟩
Article dans une revue hal-04042345v1

Segmental Relaxation Dynamics in Amorphous Polylactide Exposed to UV Light

Steven Araujo , Chloé Sainlaud , Nicolas Delpouve , Emmanuel Richaud , Laurent Delbreilh
Macromolecular Chemistry and Physics, 2022, 223 (16), pp.2200085. ⟨10.1002/macp.202200085⟩
Article dans une revue hal-03779180v1
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Physical Aging of an Epoxy Resin for Civil Engineering Applications from Fast Scanning Calorimetry Investigations

Blandine Quelennec , Nicolas Delpouve , Laurent Delbreilh , Romain Delannoy , Emmanuel Richaud
Macromolecular Symposia, 2022, Times of Polymers and Composites (TOP), 405 (1), pp.2100230. ⟨10.1002/masy.202100230⟩
Article dans une revue hal-04077208v1
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On the improvement of thermo-mechanical behavior of carbon/polyphenylene sulfide laminated composites upon annealing at high temperature

Benoît Vieille , E. Ernault , Nicolas Delpouve , J-D. Pujols Gonzalez , Antonella Esposito
Composites Part B: Engineering, 2021, 216, pp.108858. ⟨10.1016/j.compositesb.2021.108858⟩
Article dans une revue hal-03192259v1
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Fragility of short‐chain poly(lactic acid)s derivatives by combining dielectric spectroscopy and fast scanning calorimetry

Sareh Mahmoudian Moghaddam , Blandine Quelennec , Nicolas Delpouve , Bienvenu Atawa , Laurent Delbreilh
Journal of Polymer Science, 2021, 59 (14), pp.1571-1577. ⟨10.1002/pol.20210129⟩
Article dans une revue hal-03331591v1
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Water-Induced Breaking of Interfacial Cohesiveness in a Poly(lactic acid)/Miscanthus Fibers Biocomposite

Nicolas Delpouve , Hajar Faraj , Clément Demarest , Eric Dontzoff , Marie-Rose Garda
Polymers, 2021, 13 (14), pp.2285. ⟨10.3390/polym13142285⟩
Article dans une revue hal-03331594v1
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Amorphous rigidification and cooperativity drop in semi−crystalline plasticized polylactide

Nagihan Varol , Nicolas Delpouve , Steven Araujo , Sandra Domenek , Alain Guinault
Polymer, 2020, 194, pp.1-9. ⟨10.1016/j.polymer.2020.122373⟩
Article dans une revue hal-02539613v1
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Dielectric and calorimetric signatures of chain orientation in strong and tough ultrafine electrospun polyacrylonitrile

Steven Araujo , Nicolas Delpouve , Laurent Delbreilh , Dimitry Papkov , Yuris Dzenis
Polymer, 2019, pp.121638. ⟨10.1016/j.polymer.2019.121638⟩
Article dans une revue hal-02178782v1
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Cooperativity Scaling and Free Volume in Plasticized Polylactide

Steven Araujo , Nicolas Delpouve , Sandra Domenek , Alain Guinault , Roman Golovchak
Macromolecules, 2019, 52 (16), pp.6107-6115. ⟨10.1021/acs.macromol.9b00464⟩
Article dans une revue hal-02277312v1
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Determination of the equilibrium enthalpy of melting of two-phase semi-crystalline polymers by fast scanning calorimetry

Clément Fosse , Aurélie Bourdet , Esteve Ernault , Antonella Esposito , Nicolas Delpouve
Thermochimica Acta, 2019, 677, pp.67-78. ⟨10.1016/j.tca.2019.03.035⟩
Article dans une revue hal-02154859v1

Quantifying Polymer Chain Orientation in Strong and Tough Nanofibers with Low Crystallinity: Toward Next Generation Nanostructured Superfibers

Dimitry Papkov , Nicolas Delpouve , Laurent Delbreilh , Steven Araujo , Taylor Stockdale
Article dans une revue hal-02129923v1
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Reducing the Gap between the Activation Energy Measured in the Liquid and the Glassy States by Adding a Plasticizer to Polylactide

Steven Araujo , Nicolas Delpouve , Alexandre Dhotel , Sandra Domenek , Alain Guinault
ACS Omega, 2018, 3 (12), pp.17092-17099. ⟨10.1021/acsomega.8b02474⟩
Article dans une revue hal-02061741v1

From a Three-Phase Model to a Continuous Description of Molecular Mobility in Semicrystalline Poly(Hydroxybutyrate- \emphCo -Hydroxyvalerate)

Antonella Esposito , Nicolas Delpouve , Valerio Causin , Alexandre Dhotel , Laurent Delbreilh
Macromolecules, 2016, 49 (13), pp.4850-4861. ⟨10.1021/acs.macromol.6b00384⟩
Article dans une revue hal-01954226v1

Molecular mobility and physical ageing of plasticized poly(lactide)

Larisa Dobircau , Nicolas Delpouve , Romuald Herbinet , Sandra Domenek , Loïc Le Pluart
Polymer Engineering and Science, 2015, 55 (4), pp.858-865. ⟨10.1002/pen.23952⟩
Article dans une revue hal-01173856v1
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Structural Dependence of the Molecular Mobility in the Amorphous Fractions of Polylactide

Nicolas Delpouve , Laurent Delbreilh , Grégory Stoclet , Allisson Saiter , Eric Dargent
Macromolecules, 2014, 47 (15), pp.5186-5197. ⟨10.1021/ma500839p⟩
Article dans une revue hal-01199661v1

Rigid amorphous fraction in different molecular weight polylactic acid after cold crystallization from the glassy state

Yoga Sugama Salim , Antonella Esposito , Loïc Le Pluart , Esteve Ernault , Nicolas Delpouve
Journées GFP Grand Ouest, May 2019, Orléans, France
Communication dans un congrès hal-02295866v1
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Influence de la fraction amorphe rigide sur le comportement à rupture de composites Carbone/PPS

Estève Ernault , Benoît Vieille , Nicolas Delpouve , Juan Daniel Pujols Gonzalez , Laurent Delbreilh
21ème Journées Nationales sur les Composites, École Nationale Supérieure d'Arts et Métiers (ENSAM) - Bordeaux, Jul 2019, Bordeaux, Talence, France
Communication dans un congrès hal-02420710v1

Effect of Molecular Weights on the Physical Properties and Microstructure of Poly(lactic acid)

Yoga Sugama Salim , Esteve Ernault , Nicolas Delpouve , Benoît Vieille , Laurent Delbreilh
25eme congrès général de la société française de physique, Jul 2019, Nantes, France
Communication dans un congrès hal-02295880v1

Relaxation dynamics in plasticized polylactide

Nicolas Delpouve , Steven Araujo , Sandra Domenek , Alain Guinault , Laurent Delbreilh
9th International Conference on Times of Polymers and Composites. From Aerospace to Nanotechnology, Jun 2018, Ischia, Italy. pp.020055, ⟨10.1063/1.5045917⟩
Communication dans un congrès hal-02061764v1

Influence de la Fraction Amorphe Rigide sur les Propriétés Mécaniques d'un Composite Carbone/Polysulfure de Phenylène

Esteve Ernault , Nicolas Delpouve , Benoît Vieille , Yoga Sugama Salim , Antonella Esposito
DEPPOS 2018, Sep 2018, La Bresse, France
Communication dans un congrès hal-02294722v1

Microstructure, amorphous phase dynamics and barrier properties in multilayer coextruded polylactide

Samira Fernandes Nassar , Nicolas Delpouve , Alain Guinault , Laurent Delbreilh , Cyrille Sollogoub
Polychar 22 World Forum on Advanced Materials, Stellenbosch University. ZAF., Apr 2014, Stellenbosch, South Africa
Communication dans un congrès hal-01269145v1

Role of plasticizing molecules on the amorphous phase dynamics of polylactide

Nicolas Delpouve , Laurent Delbreilh , Sandra Domenek , Eric Dargent
Polychar 22 World Forum on Advanced Materials, Stellenbosch University. ZAF., Apr 2014, Stellenbosch, South Africa
Communication dans un congrès hal-01269156v1

Thermally stimulated depolarization currents and dielectric spectroscopy analysis of plasticized amorphous polylactide

Steven Araujo , Alexandre Dhotel , Nicolas Delpouve , Laurent Delbreilh , Sandra Domenek
45. French Conference on Calorimetry and Thermal Analysis (JCAT 45), Groupe Français d’Études et d’Applications des Polymères. FRA., May 2014, Rouen, France
Communication dans un congrès hal-01269157v1

Amorphous phase molecular mobility of palsticized poly(lactic acid)

Nicolas Delpouve , L. Delbreilh , Alain Guinault , Sandra Domenek , Eric Dargent
4. International Conference on Biodegradable and Biobased Polymers (Biopol 2013), Aug 2012, Rome, Italy
Communication dans un congrès hal-01173852v1

Effect of two plasticizers on the physical aging of polylactide

L Dobricau , Nicolas Delpouve , R Herbinet , Cecile Courgneau , L. Delbreilh
4. International Conference on Biodegradable and Biobased Polymers (Biopol 2013), Aug 2012, Rome, Italy
Communication dans un congrès hal-01173857v1