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Laurent Delbreilh

Dr. Laurent DELBREILH Associate Professor in the University of Rouen since September 2006 Section CNU : 28 Physics Researcher in Physics Researcher in GPM laboratory, UMR CNRS 6634, Co-Coordinator of « Physics Mention » Licence at the University of Rouen. Coordinator of Material Science specialty 3rd year Licence at University of Rouen Member of l’Association Française de Calorimétrie et d'Analyse Thermique (AFCAT) et de l’International Committee of Thermal Analysis and Calorimetry (ICTAC) depuis 2008. Education 2016 : “Habilitation à Diriger la Recherche” HDR 2004 : PhD. Of the University of Toulouse (F) in Polymer Physics Current Position Since 2016: Maître de Conférences HDR/ Associate Professor in the Physics research Department of the University of Rouen. Since 2014 : Visiting Adjunct Research Professor at the Mechanical and Materials Engineering department at University of Nebraska Lincoln (UNL) USA 2006/2016 : Maitre de conférences/Assistant Professor in the Physics research Department of the University of Rouen 2004/2006 : Assistant in the Physics research Department of the University of Rouen. Supervision Activities 50 Students in Master Degree 11 Students in PhD Thesis Scientific Activities: My research activities mainly concern the field of the physics of glasses, physics of disordered matter and more particularly the physics of polymers and nowadays of biopolymers. I work more specifically on the study of dynamics in amorphous phases, mainly in polymers but also for other glass formers. The various works that I have implemented, or in which I have participated, are at the intersection of two issues: - A more fundamental theme which aims to understand the physical mechanisms and the laws of behavior for glass-forming liquids below and above the glass transition temperature. - A theme with a more "materials" approach aimed at studying the impact of modifications of amorphous phases, in a physicochemical manner. This produces different relaxation environments. The principle of the environment is seen here in the broad sense since under this term we can group together: - microstructures in the case of semi-crystalline polymers - geometric confinement - fillers or nano-fillers in the case of composites - additives - nano-texturing ... These two approaches are most often interconnected in my work since the fundamental understanding of relaxation phenomena in amorphous "model" materials allows a more precise reading of the phenomena observed during an application on more complex materials.
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Documents

Présentation

Domaines de recherche

Matière Molle [cond-mat.soft] Science des matériaux [cond-mat.mtrl-sci] Physique [physics] Matériaux

Publications

eric-dargent

Effect of Chemical Composition on Molecular Mobility and Phase Coupling in Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) and Poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) with Different Comonomer Contents

Clément Fosse , Antonella Esposito , Pierre Lemechko , Yoga Sugama Salim , Valerio Causin
Journal of Polymers and the Environment, 2023, ⟨10.1007/s10924-023-02882-2⟩
Article dans une revue hal-04095807v1

Microstructural consequences of isothermal crystallization in homo- and co-polyesters based on 2,5- and 2,4-furandicarboxylic acid

Aurélie Bourdet , Clément Fosse , Marie-Rose Garda , Shanmugam Thiyagarajan , Laurent Delbreilh
Polymer, 2023, pp.125835. ⟨10.1016/j.polymer.2023.125835⟩
Article dans une revue hal-04020682v1

Cooperativity and fragility in furan-based polyesters with different glycolic subunits as compared to their terephthalic counterparts

Clément Fosse , Antonella Esposito , Shanmugam Thiyagarajan , Michelina Soccio , Nadia Lotti
Journal of Non-Crystalline Solids, 2022, 597, pp.121907. ⟨10.1016/j.jnoncrysol.2022.121907⟩
Article dans une revue hal-03779120v1

Segmental Relaxation Dynamics in Amorphous Polylactide Exposed to UV Light

Steven Araujo , Chloé Sainlaud , Nicolas Delpouve , Emmanuel Richaud , Laurent Delbreilh
Macromolecular Chemistry and Physics, 2022, 223 (16), pp.2200085. ⟨10.1002/macp.202200085⟩
Article dans une revue hal-03779180v1
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On the improvement of thermo-mechanical behavior of carbon/polyphenylene sulfide laminated composites upon annealing at high temperature

Benoît Vieille , E. Ernault , Nicolas Delpouve , J-D. Pujols Gonzalez , Antonella Esposito
Composites Part B: Engineering, 2021, 216, pp.108858. ⟨10.1016/j.compositesb.2021.108858⟩
Article dans une revue hal-03192259v1
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Molecular mobility in amorphous biobased copolyesters obtained with 2,5- and 2,4-furandicarboxylate acid

Aurélie Bourdet , Steven Araujo , Shanmugam Thiyagarajan , Laurent Delbreilh , Antonella Esposito
Polymer, 2021, 213, pp.123225. ⟨10.1016/j.polymer.2020.123225⟩
Article dans une revue hal-03331596v1
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Water-Induced Breaking of Interfacial Cohesiveness in a Poly(lactic acid)/Miscanthus Fibers Biocomposite

Nicolas Delpouve , Hajar Faraj , Clément Demarest , Eric Dontzoff , Marie-Rose Garda
Polymers, 2021, 13 (14), pp.2285. ⟨10.3390/polym13142285⟩
Article dans une revue hal-03331594v1
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Amorphous rigidification and cooperativity drop in semi−crystalline plasticized polylactide

Nagihan Varol , Nicolas Delpouve , Steven Araujo , Sandra Domenek , Alain Guinault
Polymer, 2020, 194, pp.1-9. ⟨10.1016/j.polymer.2020.122373⟩
Article dans une revue hal-02539613v1

Highlight of primary and secondary relaxations in amorphous stereocomplex polylactides

Nagihan Varol , X. Monnier , Laurent Delbreilh , Allisson Saiter , K. Fatyeyeva
Express Polymer Letters, 2020, 14 (1), pp.48-62. ⟨10.3144/expresspolymlett.2020.5⟩
Article dans une revue hal-02355911v1
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Dielectric and calorimetric signatures of chain orientation in strong and tough ultrafine electrospun polyacrylonitrile

Steven Araujo , Nicolas Delpouve , Laurent Delbreilh , Dimitry Papkov , Yuris Dzenis
Polymer, 2019, pp.121638. ⟨10.1016/j.polymer.2019.121638⟩
Article dans une revue hal-02178782v1
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Cooperativity Scaling and Free Volume in Plasticized Polylactide

Steven Araujo , Nicolas Delpouve , Sandra Domenek , Alain Guinault , Roman Golovchak
Macromolecules, 2019, 52 (16), pp.6107-6115. ⟨10.1021/acs.macromol.9b00464⟩
Article dans une revue hal-02277312v1

Quantifying Polymer Chain Orientation in Strong and Tough Nanofibers with Low Crystallinity: Toward Next Generation Nanostructured Superfibers

Dimitry Papkov , Nicolas Delpouve , Laurent Delbreilh , Steven Araujo , Taylor Stockdale
Article dans une revue hal-02129923v1
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Determination of the equilibrium enthalpy of melting of two-phase semi-crystalline polymers by fast scanning calorimetry

Clément Fosse , Aurélie Bourdet , Esteve Ernault , Antonella Esposito , Nicolas Delpouve
Thermochimica Acta, 2019, 677, pp.67-78. ⟨10.1016/j.tca.2019.03.035⟩
Article dans une revue hal-02154859v1

Investigation of Drug–Excipient Interactions in Biclotymol Amorphous Solid Dispersions

Benjamin Schammé , Nicolas Couvrat , Vincent Tognetti , Laurent Delbreilh , Valérie Dupray
Molecular Pharmaceutics, 2018, 15 (3), pp.1112-1125. ⟨10.1021/acs.molpharmaceut.7b00993⟩
Article dans une revue hal-01857154v1
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Reducing the Gap between the Activation Energy Measured in the Liquid and the Glassy States by Adding a Plasticizer to Polylactide

Steven Araujo , Nicolas Delpouve , Alexandre Dhotel , Sandra Domenek , Alain Guinault
ACS Omega, 2018, 3 (12), pp.17092-17099. ⟨10.1021/acsomega.8b02474⟩
Article dans une revue hal-02061741v1

Microstructural properties and dielectric relaxations of partially fluorinated copolymers

Jorge Arturo Soto Puente , Laurent Delbreilh , Jens Dittmer , Valérie Briand , Sébastien Vernay
Polymer, 2018, 157, pp.50-58. ⟨10.1016/j.polymer.2018.10.020⟩
Article dans une revue hal-02061723v1

Vitrification of two active pharmaceutical ingredients by fast scanning calorimetry: From structural relaxation to nucleation phenomena

Xavier Monnier , Quentin Viel , Benjamin Schammé , Samuel Petit , Laurent Delbreilh
International Journal of Pharmaceutics, 2018, 536 (1), pp.426 - 433. ⟨10.1016/j.ijpharm.2017.12.013⟩
Article dans une revue hal-01857176v1

Molecular Mobility in Amorphous Biobased Poly(ethylene 2,5-furandicarboxylate) and Poly(ethylene 2,4-furandicarboxylate)

Aurélie Bourdet , Antonella Esposito , Shanmugam Thiyagarajan , Laurent Delbreilh , Frederic Affouard
Macromolecules, 2018, 51 (5), pp.1937-1945. ⟨10.1021/acs.macromol.8b00108⟩
Article dans une revue hal-02061738v1

Compactness/density assessment of newly-paved highway containing recycled asphalt pavement by means of non-nuclear method

Steven Araujo , Bruno Beaucamp , Laurent Delbreilh , Eric Dargent , Cyrille Fauchard
Construction and Building Materials, 2017, 154, pp.1151 - 1163. ⟨10.1016/j.conbuildmat.2017.07.075⟩
Article dans une revue hal-01765957v1

Insights on the Physical State Reached by an Active Pharmaceutical Ingredient upon High-Energy Milling

Benjamin Schammé , Xavier Monnier , Nicolas Couvrat , Laurent Delbreilh , Valérie Dupray
Journal of Physical Chemistry B, 2017, 121 (19), pp.5142 - 5150. ⟨10.1021/acs.jpcb.7b02247⟩
Article dans une revue hal-01766057v1

Molecular Mobility of an Amorphous Chiral Pharmaceutical Compound: Impact of Chirality and Chemical Purity

Quentin Viel , Laurent Delbreilh , Gérard Coquerel , Samuel Petit , Eric Dargent
Journal of Physical Chemistry B, 2017, 121 (32), pp.7729 - 7740. ⟨10.1021/acs.jpcb.7b05667⟩
Article dans une revue hal-01927923v1
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Rock permittivity characterization and application of electromagnetic mixing models for density/compactness assessment of HMA by means of step‐frequency radar

Steven Araujo , Laurent Delbreilh , Laurent Laguerre , Hervé Dumont , Eric Dargent
Near Surface Geophysics, 2016, 14 (6), pp.551-562. ⟨10.3997/1873-0604.2016031⟩
Article dans une revue hal-02178143v1
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Correlated and cooperative motions in segmental relaxation: Influence of constitutive unit weight and intermolecular interactions

Bidur Rijal , Jorge Arturo Soto Puente , Bienvenu Atawa , Laurent Delbreilh , Kateryna Fatyeyeva
Physical Review E , 2016, 94 (6), pp.062502. ⟨10.1103/PhysRevE.94.062502⟩
Article dans une revue hal-02130947v1

Transformation of an active pharmaceutical ingredient upon high-energy milling: A process-induced disorder in Biclotymol

Benjamin Schammé , Nicolas Couvrat , Pascal Malpeli , Emeline Dudognon , Laurent Delbreilh
International Journal of Pharmaceutics, 2016, 499 (1-2), pp.67 - 73. ⟨10.1016/j.ijpharm.2015.12.032⟩
Article dans une revue hal-01928396v1

Molecular Relaxations in Supercooled Liquid and Glassy States of Amorphous Quinidine: Dielectric Spectroscopy and Density Functional Theory Approaches

Benjamin Schammé , Mélanie Mignot , Nicolas Couvrat , Vincent Tognetti , Laurent Joubert
Journal of Physical Chemistry B, 2016, 120 (30), pp.7579-7592. ⟨10.1021/acs.jpcb.6b04242⟩
Article dans une revue hal-01928417v1

Influence of Crystallinity on the Dielectric Relaxations of Poly(Butylene Succinate) and Poly[(Butylene Succinate)- Co -(Butylene Adipate)]

Sébastien Charlon , Laurent Delbreilh , Eric Dargent , Nadège Follain , Jérémie Soulestin
European Polymer Journal, 2016, 84, pp.366-376. ⟨10.1016/j.eurpolymj.2016.09.045⟩
Article dans une revue hal-01954223v1

From a Three-Phase Model to a Continuous Description of Molecular Mobility in Semicrystalline Poly(Hydroxybutyrate- \emphCo -Hydroxyvalerate)

Antonella Esposito , Nicolas Delpouve , Valerio Causin , Alexandre Dhotel , Laurent Delbreilh
Macromolecules, 2016, 49 (13), pp.4850-4861. ⟨10.1021/acs.macromol.6b00384⟩
Article dans une revue hal-01954226v1

Crystallization kinetics and molecular mobility of an amorphous active pharmaceutical ingredient: A case study with Biclotymol

Benjamin Schammé , Nicolas Couvrat , Pascal Malpeli , Laurent Delbreilh , Valérie Dupray
International Journal of Pharmaceutics, 2015, 490 (1-2), pp.248 - 257. ⟨10.1016/j.ijpharm.2015.05.036⟩
Article dans une revue hal-01928832v1

Combining Flash DSC, DSC and broadband dielectric spectroscopy to determine fragility

Alexandre Dhotel , Bidur Rijal , Laurent Delbreilh , Eric Dargent , Allisson Saiter
Journal of Thermal Analysis and Calorimetry, 2015, 121 (1), pp.453-461. ⟨10.1007/s10973-015-4650-9⟩
Article dans une revue hal-02129983v1

Molecular mobility and physical ageing of plasticized poly(lactide)

Larisa Dobircau , Nicolas Delpouve , Romuald Herbinet , Sandra Domenek , Loïc Le Pluart
Polymer Engineering and Science, 2015, 55 (4), pp.858-865. ⟨10.1002/pen.23952⟩
Article dans une revue hal-01173856v1
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Structural Dependence of the Molecular Mobility in the Amorphous Fractions of Polylactide

Nicolas Delpouve , Laurent Delbreilh , Grégory Stoclet , Allisson Saiter , Eric Dargent
Macromolecules, 2014, 47 (15), pp.5186-5197. ⟨10.1021/ma500839p⟩
Article dans une revue hal-01199661v1

Glass Transition Temperature and Value of the Relaxation Time at Tg in Vitreous Polymers

Jean Marc Saiter , Jean J. Grenet , Eric Dargent , Allisson Saiter , Laurent Delbreilh
Macromolecular Symposia, 2007, 258 (1), pp.152-161. ⟨10.1002/masy.200751217⟩
Article dans une revue hal-02156329v1
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Study of poly(bisphenol A carbonate) relaxation kinetics at the glass transition temperature

Laurent Delbreilh , Eric Dargent , Jean Grenet , Jean-Marc Saiter , Alain Bernès
European Polymer Journal, 2007, vol. 43 (1), pp. 249-254. ⟨10.1016/j.eurpolymj.2006.09.019⟩
Article dans une revue hal-00808431v1

Effect of Molecular Weights on the Physical Properties and Microstructure of Poly(lactic acid)

Yoga Sugama Salim , Esteve Ernault , Nicolas Delpouve , Benoît Vieille , Laurent Delbreilh
25eme congrès général de la société française de physique, Jul 2019, Nantes, France
Communication dans un congrès hal-02295880v1

Relaxation dynamics in plasticized polylactide

Nicolas Delpouve , Steven Araujo , Sandra Domenek , Alain Guinault , Laurent Delbreilh
9th International Conference on Times of Polymers and Composites. From Aerospace to Nanotechnology, Jun 2018, Ischia, Italy. pp.020055, ⟨10.1063/1.5045917⟩
Communication dans un congrès hal-02061764v1

Influence de la Fraction Amorphe Rigide sur les Propriétés Mécaniques d'un Composite Carbone/Polysulfure de Phenylène

Esteve Ernault , Nicolas Delpouve , Benoît Vieille , Yoga Sugama Salim , Antonella Esposito
DEPPOS 2018, Sep 2018, La Bresse, France
Communication dans un congrès hal-02294722v1

Parametric study of the compactness assessment of a new road containing recycled asphalt pavement through non-nuclear method

Steven Araujo , Bruno Beaucamp , Laurent Delbreilh , Eric Dargent , Cyrille Fauchard
2017 9th International Workshop on Advanced Ground Penetrating Radar (IWAGPR), Jun 2017, Edinburgh, France. ⟨10.1109/iwagpr.2017.7996089⟩
Communication dans un congrès hal-01766119v1

Transformation d’un principe actif sous broyage haute-énergie : cas du Biclotymol

Benjamin Schammé , Nicolas Couvrat , Pascal Malpeli , Emeline Dudognon , Laurent Delbreilh
CRISTAL 8 (Cristallisation et précipitation industrielles), May 2016, Rouen, France
Communication dans un congrès hal-02468844v1

Thermally stimulated depolarization currents and dielectric spectroscopy analysis of plasticized amorphous polylactide

Steven Araujo , Alexandre Dhotel , Nicolas Delpouve , Laurent Delbreilh , Sandra Domenek
45. French Conference on Calorimetry and Thermal Analysis (JCAT 45), Groupe Français d’Études et d’Applications des Polymères. FRA., May 2014, Rouen, France
Communication dans un congrès hal-01269157v1

Microstructure, amorphous phase dynamics and barrier properties in multilayer coextruded polylactide

Samira Fernandes Nassar , Nicolas Delpouve , Alain Guinault , Laurent Delbreilh , Cyrille Sollogoub
Polychar 22 World Forum on Advanced Materials, Stellenbosch University. ZAF., Apr 2014, Stellenbosch, South Africa
Communication dans un congrès hal-01269145v1

Role of plasticizing molecules on the amorphous phase dynamics of polylactide

Nicolas Delpouve , Laurent Delbreilh , Sandra Domenek , Eric Dargent
Polychar 22 World Forum on Advanced Materials, Stellenbosch University. ZAF., Apr 2014, Stellenbosch, South Africa
Communication dans un congrès hal-01269156v1

Amorphous phase molecular mobility of palsticized poly(lactic acid)

Nicolas Delpouve , L. Delbreilh , Alain Guinault , Sandra Domenek , Eric Dargent
4. International Conference on Biodegradable and Biobased Polymers (Biopol 2013), Aug 2012, Rome, Italy
Communication dans un congrès hal-01173852v1