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Electrochemical deprotection of a substrate binding site in [Mo2(cp)2-(μ-SMe)3(μ-Cl)] (cp = η5-C5H5) via chloride-bridge opening. Kinetics of MeCN and ButNC binding at this site

Frédéric Barrière , Yves Le Mest , François Y. Pétillon , Sylvie Poder-Guillou , Philippe P. Schollhammer , et al.
Journal of the Chemical Society - Dalton Transactions, 1996, 20, pp.3967-3976. ⟨10.1039/DT9960003967⟩
Article dans une revue istex hal-02296678v1

Incorporation of alkyne and vinylidene ligands into tetrazolate groups at a sulfur-rich dimolybdenum site using sodium azide

Philippe P. Schollhammer , Nolwenn Cabon , A.-C. Kervella , François Pétillon , R. Rumin , et al.
Inorganica Chimica Acta, 2003, 350, pp.495-502. ⟨10.1016/S0020-1693(02)01556-6⟩
Article dans une revue istex hal-01763906v1

Controlled nucleophilic activation of different sites in [Mo 2Cp2L2(μ-SMe)2(μ-L′)] + cations (L = ButNC, xylNC, CO; L′ = SMe or PPh2)

Nolwenn Cabon , François Pétillon , Pierre Yves Orain , Philippe P. Schollhammer , Jean Talarmin , et al.
Journal of Organometallic Chemistry, 2005, 690 (21-22), pp.4583-4601. ⟨10.1016/j.jorganchem.2005.07.034⟩
Article dans une revue istex hal-01763754v1

Triiron clusters derived from dinuclear complexes related to the active site of [Fe-Fe] hydrogenases: Steric effect of the dithiolate bridge on redox properties, a DFT analysis.

Ahmad Hobballah , Federica Arrigoni , Catherine Elleouet , Claudio Greco , Maxime Laurans , et al.
Inorganic Chemistry Frontiers, 2021, ⟨10.1039/D1QI00006C⟩
Article dans une revue hal-03138212v1

The effect of replacing carbonyl with acetonitrile on the reactivity of the bimetallic system [Mo2Cp2(μ-SMe)3(L)2]+ (L=CO, CH3CN). Crystal structure of [Mo2Cp2(μ-SMe)2(CH3CN) 4](BF4)2

Philippe P. Schollhammer , François Pétillon , J. Talarmin , K.W. Muir
Inorganica Chimica Acta, 1999, 284, pp.107--111. ⟨10.1016/S0020-1693(98)00266-7⟩
Article dans une revue istex hal-01771400v1

Halogenation and alkylation at a MoIII2(μ-S) site. Crystal structure of the metal - sulfenyl halide complex [Mo2(η5-C5 Me5)2(μ-SMe)2(μ-SI) (CO)2]I5

P. Schollhammer , François Pétillon , J. Talarmin , K.W. Muir , H.K. Fun , et al.
Inorganic Chemistry, 2000, 39, pp.5879--5882. ⟨10.1021/ic000591u⟩
Article dans une revue istex hal-01771368v1
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Insights into Triazolylidene Ligands Behaviour at a Di-Iron Site Related to [FeFe]-Hydrogenases

Andrea Mele , Federica Arrigoni , Catherine Elleouet , François Pétillon , Philippe Schollhammer , et al.
Molecules, 2022, 27 (15), pp.4700. ⟨10.3390/molecules27154700⟩
Article dans une revue hal-03917886v1

First insights into the protonation of dissymetrically disubstituted di-iron azadithiolate models of the [FeFe]H2ases active site

Salah Ezzaher , Pierre-Yves Orain , Jean-François Capon , Frederic Gloaguen , François Y. Pétillon , et al.
Chemical Communications, 2008, 22, ⟨10.1039/B801373J⟩
Article dans une revue istex hal-01580431v1

Novel μ-η2:η2 coordination of a thiophenium cation

J.-F. Capon , Philippe P. Schollhammer , François Pétillon , J. Talarmin , K.W. Muir
Organometallics, 1999, 18, pp.2055--2057
Article dans une revue hal-01771397v1

A Bridging Side-on Allenylidene Dimolybdenum Complex without Carbonyl Stabilization

Wilfried-Solo Ojo , François Y. Pétillon , Philippe P. Schollhammer , Jean Talarmin , Kenneth W. Muir
Organometallics, 2006, 25 (22), pp.5503 - 5505. ⟨10.1021/om060663a⟩
Article dans une revue istex hal-01582977v1

Influence of the Dithiolate Bridge on the Oxidative Processes of Diiron Models Related to the Active Site of [FeFe] Hydrogenases

Federica Arrigoni , Salma Mohamed bouh , Luca De gioia , Catherine Elleouet , François Y. Pétillon , et al.
Chemistry - A European Journal, 2017, 23 (18), pp.4364 - 4372. ⟨10.1002/chem.201605060⟩
Article dans une revue hal-01520734v1

Electrochemical Insights into the Mechanisms of Proton Reduction by [Fe2(CO)6{μ-SCH2N(R)CH2S}] Complexes Related to the [2Fe]H Subsite of [FeFe]Hydrogenase

Jean-François Capon , Salah Ezzaher , Frederic Gloaguen , François Y. Pétillon , Philippe P. Schollhammer , et al.
Chemistry - A European Journal, 2008, 14 (6), pp.1954 - 1964. ⟨10.1002/chem.200701454⟩
Article dans une revue istex hal-01580430v1

Reactions of di- and poly-nuclear complexes 13. Synthesis, structure and fluxional behaviour of hydrido- and thiolato- or selenato-bridged complexes [Mo2Cp2(μ-H)(μ-ER)(CO)4] (E S, R Me, tBu, Bz, or Ph; E Se, R Ph)

Philippe P. Schollhammer , F.Y. Pétillon , R. Pichon , S. Poder-Guillou , J. Talarmin , et al.
Journal of Organometallic Chemistry, 1995, 486 (1-2), pp.183-191. ⟨10.1016/0022-328X(94)05062-G⟩
Article dans une revue istex hal-02296666v1

Electrochemical reduction of a bridging imide: Generation of ammonia at a dimolybdenum tris(μ-thiolate) site

Jean Yves Cabon , Christine Leroy , K.W. Muir , François Pétillon , F. Quentel , et al.
Chemistry - A European Journal, 2000, 6, pp.3033--3042. ⟨10.1002/1521-3765(20000818)6:16<3033::AID-CHEM3033>3.0.CO;2-A⟩
Article dans une revue istex hal-01771375v1

Reactivity of [Fe 2 (CO) 6 (μ-S 2 )] toward a Base-Containing Diphosphine (Ph 2 PCH 2 ) 2 NCH 3 : Formation of Diiron Carbonyl Compounds Having Polydentate Heterofunctionalized Phosphine (PNS = Ph 2 PCH 2 N(CH 3 )CH 2 S) and Bidentate Thiophosphinito (Ph 2 PS = PS) Bridges

Sondès Lounissi , Jean-François Capon , Frederic Gloaguen , Fatma Matoussi , François Y. Pétillon , et al.
Organometallics, 2010, 29 (5), pp.1296 - 1301. ⟨10.1021/om9011054⟩
Article dans une revue hal-01577278v1

Carbon−Sulfur and Carbon−Halogen Bond Cleavage of Acyclic or Cyclic Thioethers, Thiophenes, and Dihaloalkanes with the Trithiolato-Bridged Cation [Mo 2 Cp 2 (μ-SMe) 3 (MeCN) 2 ] +

Wilfried-Solo Ojo , François Y. Pétillon , Philippe P. Schollhammer , Jean Talarmin
Organometallics, 2010, 29 (2), pp.448 - 462. ⟨10.1021/om900901s⟩
Article dans une revue hal-01577275v1

A dimolybdenum(III) azido compound Its decomposition into amido and nitrido derivatives. Crystal structure of [Mo3(O)(N)Cp3(SMe)4]

Philippe P. Schollhammer , F.Y. Pétillon , J. Talarmin , K.W. Muir
Journal of Organometallic Chemistry, 1998, 560 (1-2), pp.245-251. ⟨10.1016/S0022-328X(98)00516-6⟩
Article dans une revue istex hal-02296679v1

Activation and functionalization of vinylic C-F bonds by transition metal compounds: The factors determining reactions between nucleophiles and a (Perfluorovinyl)diiron(I) complex; syntheses of diiron derivatives containing new C-N, C-S, C-H and C-O bonds

K. Guennou de Cadenet , R. Rumin , François Pétillon , D.S. Yufit , K.W. Muir
European Journal of Inorganic Chemistry, 2002, pp.639--657
Article dans une revue hal-01771321v1

Modeling [FeFe] hydrogenase: Synthesis and protonation of a diiron dithiolate complex containing a phosphine-N-heterocyclic-carbene ligand

Didier Morvan , Jean-François Capon , Frederic Gloaguen , François Y. Pétillon , Philippe P. Schollhammer , et al.
Journal of Organometallic Chemistry, 2009, 694 (17), pp.2801 - 2807. ⟨10.1016/j.jorganchem.2009.01.018⟩
Article dans une revue hal-01580265v1

On the electrochemistry of diiron dithiolate complexes related to the active site of the FeFe H(2)ase

Jean-François Capon , Frederic Gloaguen , François Y. Pétillon , Philippe P. Schollhammer , Jean Talarmin
Comptes Rendus. Chimie, 2008, 11 (8), pp.842-851
Article dans une revue hal-00456300v1

Electrochemical generation of substrate-binding sites in organometallic complexes with the {Mo2(µ-SR)n} core. Electrosynthesis of cyanide and isocyanide derivatives

Frederic Gloaguen , C. Le Floc’h , François Y. Pétillon , Philippe P. Schollhammer , Jean Talarmin , et al.
Molecular Electrochemistry of Inorganic, Bioinorganic and Organometallic Compounds, springer, pp.33-38, 1993, NATO ASI Series, ⟨10.1007/978-94-011-1628-2_3⟩
Chapitre d'ouvrage istex hal-02127056v1

Use of 1,10-phenanthroline in diiron dithiolate derivatives related to the [Fe–Fe] hydrogenase active site

Pierre-Yves Orain , Jean-François Capon , Nelly Kervarec , Frederic Gloaguen , François Y. Pétillon , et al.
Dalton Transactions, 2007, 34, ⟨10.1039/B709287C⟩
Article dans une revue istex hal-01581437v1

Di-iron aza diphosphido complexes: Mimics for the active site of Fe-only hydrogenase, and effects of changing the coordinating atoms of the bridging ligand in [Fe2μ-(ECH2)2NR(CO)6]

P. Das , Jean-François Capon , Frederic Gloaguen , François Pétillon , Philippe P. Schollhammer , et al.
Inorganic Chemistry, 2004, 43 (26), pp.8203-8205. ⟨10.1021/ic048772+⟩
Article dans une revue hal-01763877v1

Reductive Behavior of [Fe 2 (CO) 4 (κ 2 -dmpe){μ-(SCH 2 ) 2 NBn}]: Effect of Symmetrization on the Rotated Conformation in Fe I -Fe I Models of [2Fe] H Subsite of [Fe-Fe]­H 2 ases

Luca de Gioia , Catherine Elleouet , Sabrina Munery , François Y. Pétillon , Philippe P. Schollhammer , et al.
European Journal of Inorganic Chemistry, 2014, 2014 (22), pp.3456 - 3461. ⟨10.1002/ejic.201402335⟩
Article dans une revue istex hal-01520730v1

Mixed μ-phosphido or μ-thiolato μ-halo-dimolybdenum(III) compounds [Mo2Cp2(μ-SMe)2(μ-X)(μ-Y)] (X=PPh2, Y=Cl; X=SCH3, Y=Br, I): Electrochemical and structural comparisons – The X-ray structure of [{Mo2Cp2Br(μ-O)(μ-SMe)2}2(μ-MoO4)]

Christine Leroy , François Y. Pétillon , Kenneth W. Muir , Philippe P. Schollhammer , Jean Talarmin
Journal of Organometallic Chemistry, 2006, 691 (5), pp.898 - 906. ⟨10.1016/j.jorganchem.2005.10.033⟩
Article dans une revue istex hal-01582157v1

Reactions of Di- and Polynuclear Complexes. 14. Synthesis of Permethylated-Cyclopentadienyl Chalcogeno-Bridged Compounds A Route to the Stable Thiolatosulfidocarbonyldimolybdenum(III) complex [Cp*2Mo2(CO)2(μ-SMe)2(μ-S)]. Crystal Structure Determination of [Cp*2Mo2(CO)2(μ-SMe)2(μ-SH)] [BF4]

Philippe P. Schollhammer , F.Y. Pétillon , R. Pichon , S. Poder-Guillou , J. Talarmin , et al.
Organometallics, 1995, 14 (5), pp.2277-2287. ⟨10.1021/om00005a029⟩
Article dans une revue istex hal-02296669v1

Thermal Generation and Structures of the Unsaturated Doubly Bridged Complex [Mo 2 Cp 2 Cl 2 (μ-SMe) 2 ] and Its Quadruply Bridged Isomer [Mo 2 Cp 2 (μ-Cl) 2 (μ-SMe) 2 ]

Wilfried-Solo Ojo , John E. Mcgrady , François Y. Pétillon , Philippe P. Schollhammer , Jean Talarmin
Organometallics, 2011, 30 (3), pp.649 - 652. ⟨10.1021/om101061y⟩
Article dans une revue hal-01577036v1

Unexpected coupling of Cp and two RNC ligands at a Mo2(μ-SMe)3 nucleus

Nolwenn Cabon , E. Paugam , François Pétillon , Philippe P. Schollhammer , Jean Talarmin , et al.
Organometallics, 2003, 22 (21), pp.4178-4180. ⟨10.1021/om030447r⟩
Article dans une revue istex hal-01763900v1

Transformations and agostic interactions of hydrocarbyl ligands bonded to the sulfur-rich dimolybdenum site Mo2Cp2(μ-SMe) 3: Chemical and electrochemical formation of μ-alkyl and μ-vinyl compounds from a μ-alkylidene derivative

Nolwenn Cabon , A. Le Goff , Christine Leroy , François Pétillon , Philippe P. Schollhammer , et al.
Organometallics, 2005, 24 (25), pp.6268-6278. ⟨10.1021/om050761g⟩
Article dans une revue istex hal-01763766v1

[FeFe] Hydrogenase Models: an Overview

Ulf-Peter Apfel , François Y. Pétillon , Philippe P. Schollhammer , Jean Talarmin , Wolfgang Weigand
Bioinspired Catalysis, Metal-Sulfur Complexes., chapitre 4, Wiley‐VCH, pp.79-104, 2015, Part II : Model Complexes of the Active Site of Hydrogenases-Proton and Dihydrogen Activation, 9783527333080. ⟨10.1002/9783527664160.ch4⟩
Chapitre d'ouvrage hal-02127128v1