Electrochemical deprotection of a substrate binding site in [Mo2(cp)2-(μ-SMe)3(μ-Cl)] (cp = η5-C5H5) via chloride-bridge opening. Kinetics of MeCN and ButNC binding at this site
Frédéric Barrière
,
Yves Le Mest
,
François Y. Pétillon
,
Sylvie Poder-Guillou
,
Philippe P. Schollhammer
,
et al.
Article dans une revue
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hal-02296678v1
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Incorporation of alkyne and vinylidene ligands into tetrazolate groups at a sulfur-rich dimolybdenum site using sodium azide
Philippe P. Schollhammer
,
Nolwenn Cabon
,
A.-C. Kervella
,
François Pétillon
,
R. Rumin
,
et al.
Article dans une revue
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hal-01763906v1
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Controlled nucleophilic activation of different sites in [Mo 2Cp2L2(μ-SMe)2(μ-L′)] + cations (L = ButNC, xylNC, CO; L′ = SMe or PPh2)
Nolwenn Cabon
,
François Pétillon
,
Pierre Yves Orain
,
Philippe P. Schollhammer
,
Jean Talarmin
,
et al.
Article dans une revue
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hal-01763754v1
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Triiron clusters derived from dinuclear complexes related to the active site of [Fe-Fe] hydrogenases: Steric effect of the dithiolate bridge on redox properties, a DFT analysis.
Ahmad Hobballah
,
Federica Arrigoni
,
Catherine Elleouet
,
Claudio Greco
,
Maxime Laurans
,
et al.
Article dans une revue
hal-03138212v1
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The effect of replacing carbonyl with acetonitrile on the reactivity of the bimetallic system [Mo2Cp2(μ-SMe)3(L)2]+ (L=CO, CH3CN). Crystal structure of [Mo2Cp2(μ-SMe)2(CH3CN) 4](BF4)2
Philippe P. Schollhammer
,
François Pétillon
,
J. Talarmin
,
K.W. Muir
Article dans une revue
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hal-01771400v1
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Halogenation and alkylation at a MoIII2(μ-S) site. Crystal structure of the metal - sulfenyl halide complex [Mo2(η5-C5 Me5)2(μ-SMe)2(μ-SI) (CO)2]I5
P. Schollhammer
,
François Pétillon
,
J. Talarmin
,
K.W. Muir
,
H.K. Fun
,
et al.
Article dans une revue
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hal-01771368v1
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Insights into Triazolylidene Ligands Behaviour at a Di-Iron Site Related to [FeFe]-Hydrogenases
Andrea Mele
,
Federica Arrigoni
,
Catherine Elleouet
,
François Pétillon
,
Philippe Schollhammer
,
et al.
Article dans une revue
hal-03917886v1
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First insights into the protonation of dissymetrically disubstituted di-iron azadithiolate models of the [FeFe]H2ases active site
Salah Ezzaher
,
Pierre-Yves Orain
,
Jean-François Capon
,
Frederic Gloaguen
,
François Y. Pétillon
,
et al.
Article dans une revue
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hal-01580431v1
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Novel μ-η2:η2 coordination of a thiophenium cation
J.-F. Capon
,
Philippe P. Schollhammer
,
François Pétillon
,
J. Talarmin
,
K.W. Muir
Organometallics , 1999, 18, pp.2055--2057
Article dans une revue
hal-01771397v1
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A Bridging Side-on Allenylidene Dimolybdenum Complex without Carbonyl Stabilization
Wilfried-Solo Ojo
,
François Y. Pétillon
,
Philippe P. Schollhammer
,
Jean Talarmin
,
Kenneth W. Muir
Article dans une revue
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hal-01582977v1
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Influence of the Dithiolate Bridge on the Oxidative Processes of Diiron Models Related to the Active Site of [FeFe] Hydrogenases
Federica Arrigoni
,
Salma Mohamed bouh
,
Luca De gioia
,
Catherine Elleouet
,
François Y. Pétillon
,
et al.
Article dans une revue
hal-01520734v1
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Electrochemical Insights into the Mechanisms of Proton Reduction by [Fe2(CO)6{μ-SCH2N(R)CH2S}] Complexes Related to the [2Fe]H Subsite of [FeFe]Hydrogenase
Jean-François Capon
,
Salah Ezzaher
,
Frederic Gloaguen
,
François Y. Pétillon
,
Philippe P. Schollhammer
,
et al.
Article dans une revue
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hal-01580430v1
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Reactions of di- and poly-nuclear complexes 13. Synthesis, structure and fluxional behaviour of hydrido- and thiolato- or selenato-bridged complexes [Mo2Cp2(μ-H)(μ-ER)(CO)4] (E S, R Me, tBu, Bz, or Ph; E Se, R Ph)
Philippe P. Schollhammer
,
F.Y. Pétillon
,
R. Pichon
,
S. Poder-Guillou
,
J. Talarmin
,
et al.
Article dans une revue
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hal-02296666v1
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Electrochemical reduction of a bridging imide: Generation of ammonia at a dimolybdenum tris(μ-thiolate) site
Jean Yves Cabon
,
Christine Leroy
,
K.W. Muir
,
François Pétillon
,
F. Quentel
,
et al.
Article dans une revue
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hal-01771375v1
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Reactivity of [Fe 2 (CO) 6 (μ-S 2 )] toward a Base-Containing Diphosphine (Ph 2 PCH 2 ) 2 NCH 3 : Formation of Diiron Carbonyl Compounds Having Polydentate Heterofunctionalized Phosphine (PNS = Ph 2 PCH 2 N(CH 3 )CH 2 S) and Bidentate Thiophosphinito (Ph 2 PS = PS) Bridges
Sondès Lounissi
,
Jean-François Capon
,
Frederic Gloaguen
,
Fatma Matoussi
,
François Y. Pétillon
,
et al.
Article dans une revue
hal-01577278v1
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Carbon−Sulfur and Carbon−Halogen Bond Cleavage of Acyclic or Cyclic Thioethers, Thiophenes, and Dihaloalkanes with the Trithiolato-Bridged Cation [Mo 2 Cp 2 (μ-SMe) 3 (MeCN) 2 ] +
Wilfried-Solo Ojo
,
François Y. Pétillon
,
Philippe P. Schollhammer
,
Jean Talarmin
Article dans une revue
hal-01577275v1
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A dimolybdenum(III) azido compound Its decomposition into amido and nitrido derivatives. Crystal structure of [Mo3(O)(N)Cp3(SMe)4]
Philippe P. Schollhammer
,
F.Y. Pétillon
,
J. Talarmin
,
K.W. Muir
Article dans une revue
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hal-02296679v1
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Activation and functionalization of vinylic C-F bonds by transition metal compounds: The factors determining reactions between nucleophiles and a (Perfluorovinyl)diiron(I) complex; syntheses of diiron derivatives containing new C-N, C-S, C-H and C-O bonds
K. Guennou de Cadenet
,
R. Rumin
,
François Pétillon
,
D.S. Yufit
,
K.W. Muir
European Journal of Inorganic Chemistry , 2002, pp.639--657
Article dans une revue
hal-01771321v1
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Modeling [FeFe] hydrogenase: Synthesis and protonation of a diiron dithiolate complex containing a phosphine-N-heterocyclic-carbene ligand
Didier Morvan
,
Jean-François Capon
,
Frederic Gloaguen
,
François Y. Pétillon
,
Philippe P. Schollhammer
,
et al.
Article dans une revue
hal-01580265v1
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On the electrochemistry of diiron dithiolate complexes related to the active site of the FeFe H(2)ase
Jean-François Capon
,
Frederic Gloaguen
,
François Y. Pétillon
,
Philippe P. Schollhammer
,
Jean Talarmin
Comptes Rendus. Chimie , 2008, 11 (8), pp.842-851
Article dans une revue
hal-00456300v1
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Electrochemical generation of substrate-binding sites in organometallic complexes with the {Mo2(µ-SR)n} core. Electrosynthesis of cyanide and isocyanide derivatives
Frederic Gloaguen
,
C. Le Floc’h
,
François Y. Pétillon
,
Philippe P. Schollhammer
,
Jean Talarmin
,
et al.
Chapitre d'ouvrage
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hal-02127056v1
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Use of 1,10-phenanthroline in diiron dithiolate derivatives related to the [Fe–Fe] hydrogenase active site
Pierre-Yves Orain
,
Jean-François Capon
,
Nelly Kervarec
,
Frederic Gloaguen
,
François Y. Pétillon
,
et al.
Article dans une revue
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hal-01581437v1
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Di-iron aza diphosphido complexes: Mimics for the active site of Fe-only hydrogenase, and effects of changing the coordinating atoms of the bridging ligand in [Fe2μ-(ECH2)2NR(CO)6]
P. Das
,
Jean-François Capon
,
Frederic Gloaguen
,
François Pétillon
,
Philippe P. Schollhammer
,
et al.
Article dans une revue
hal-01763877v1
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Reductive Behavior of [Fe 2 (CO) 4 (κ 2 -dmpe){μ-(SCH 2 ) 2 NBn}]: Effect of Symmetrization on the Rotated Conformation in Fe I -Fe I Models of [2Fe] H Subsite of [Fe-Fe]H 2 ases
Luca de Gioia
,
Catherine Elleouet
,
Sabrina Munery
,
François Y. Pétillon
,
Philippe P. Schollhammer
,
et al.
Article dans une revue
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hal-01520730v1
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Mixed μ-phosphido or μ-thiolato μ-halo-dimolybdenum(III) compounds [Mo2Cp2(μ-SMe)2(μ-X)(μ-Y)] (X=PPh2, Y=Cl; X=SCH3, Y=Br, I): Electrochemical and structural comparisons – The X-ray structure of [{Mo2Cp2Br(μ-O)(μ-SMe)2}2(μ-MoO4)]
Christine Leroy
,
François Y. Pétillon
,
Kenneth W. Muir
,
Philippe P. Schollhammer
,
Jean Talarmin
Article dans une revue
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hal-01582157v1
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Reactions of Di- and Polynuclear Complexes. 14. Synthesis of Permethylated-Cyclopentadienyl Chalcogeno-Bridged Compounds A Route to the Stable Thiolatosulfidocarbonyldimolybdenum(III) complex [Cp*2Mo2(CO)2(μ-SMe)2(μ-S)]. Crystal Structure Determination of [Cp*2Mo2(CO)2(μ-SMe)2(μ-SH)] [BF4]
Philippe P. Schollhammer
,
F.Y. Pétillon
,
R. Pichon
,
S. Poder-Guillou
,
J. Talarmin
,
et al.
Article dans une revue
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hal-02296669v1
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Thermal Generation and Structures of the Unsaturated Doubly Bridged Complex [Mo 2 Cp 2 Cl 2 (μ-SMe) 2 ] and Its Quadruply Bridged Isomer [Mo 2 Cp 2 (μ-Cl) 2 (μ-SMe) 2 ]
Wilfried-Solo Ojo
,
John E. Mcgrady
,
François Y. Pétillon
,
Philippe P. Schollhammer
,
Jean Talarmin
Article dans une revue
hal-01577036v1
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Unexpected coupling of Cp and two RNC ligands at a Mo2(μ-SMe)3 nucleus
Nolwenn Cabon
,
E. Paugam
,
François Pétillon
,
Philippe P. Schollhammer
,
Jean Talarmin
,
et al.
Article dans une revue
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hal-01763900v1
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Transformations and agostic interactions of hydrocarbyl ligands bonded to the sulfur-rich dimolybdenum site Mo2Cp2(μ-SMe) 3: Chemical and electrochemical formation of μ-alkyl and μ-vinyl compounds from a μ-alkylidene derivative
Nolwenn Cabon
,
A. Le Goff
,
Christine Leroy
,
François Pétillon
,
Philippe P. Schollhammer
,
et al.
Article dans une revue
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hal-01763766v1
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[FeFe] Hydrogenase Models: an Overview
Ulf-Peter Apfel
,
François Y. Pétillon
,
Philippe P. Schollhammer
,
Jean Talarmin
,
Wolfgang Weigand
Bioinspired Catalysis, Metal-Sulfur Complexes. , chapitre 4, Wiley‐VCH, pp.79-104, 2015, Part II : Model Complexes of the Active Site of Hydrogenases-Proton and Dihydrogen Activation, 9783527333080.
⟨10.1002/9783527664160.ch4⟩
Chapitre d'ouvrage
hal-02127128v1
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