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Cyclopent-2-enylaluminium as allylzinc precursor for the diastereoselective allylmetallation of non-racemic imines: applications to the synthesis of enantiomerically enriched heterocycles

Michaël Coffinet , Samantha Lamy , Florian Jaroschik , Jean-Luc Vasse
Organic & Biomolecular Chemistry, 2016, 14 (1), pp.69-73. ⟨10.1039/C5OB02184G⟩
Article dans une revue hal-01996271v1

Journées de la Division de Chimie de Coordination de la Société Française de Chimie

Florian Jaroschik
L'influence des ligands phospholyles sur la stabilité et la réactivité de complexes organométalliques de thulium divalents, Jan 2007, Paris, France
Communication dans un congrès hal-00197163v1

Dinitrogen Reduction and C-H Activation by the Divalent Organoneodymium Complex [(C5H2tBu3)2Nd(mu-I)K([18]crown-6)]

Florian Jaroschik , Aurélien Momin , François Nief , X. F Le Goff , Glen B. Deacon , et al.
Angewandte Chemie International Edition, 2009, 48, pp.1117-1121
Article dans une revue hal-00394043v1

Lewis Acid Catalyzed Regioselective Hydroheteroarylation of Pentafulvenes

S. Sarath Chand , Greeshma Gopalan , P. Santhini , P. Preethanuj , Jubi John , et al.
Organic Letters, 2016, 18 (5), pp.964-967. ⟨10.1021/acs.orglett.6b00047⟩
Article dans une revue hal-01996262v1
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Lanthanides and actinides: Annual survey of their organometallic chemistry covering the year 2019

Joy Farnaby , Tajrian Chowdhury , Samuel Horsewill , Bradley Wilson , Florian Jaroschik
Coordination Chemistry Reviews, 2021, 437, pp.213830. ⟨10.1016/j.ccr.2021.213830⟩
Article dans une revue hal-03264385v1

Synthesis and Characterization of 1,1′-Diphosphaplumbocenes: Oxidative Ligand Transfer Reactions with Divalent Thulium Complexes

Florian Jaroschik , Aurélien Momin , Agathe Martinez , Dominique Harakat , Louis Ricard , et al.
Organometallics, 2016, 35 (11), pp.2032-2038. ⟨10.1021/acs.organomet.6b00313⟩
Article dans une revue hal-01996254v1

Divalent Tetra- and Penta-phenylcyclopentadienyl Europium and Samarium Sandwich and Half-Sandwich Complexes: Synthesis, Characterization, and Remarkable Luminescence Properties

Rory P Kelly , Toby Bell , Rosalind Cox , Daisy Daniels , Glen Deacon , et al.
Organometallics, 2015, 34 (23), pp.5624-5636. ⟨10.1021/acs.organomet.5b00842⟩
Article dans une revue hal-01996332v1
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Reactivity differences between 2,4- and 2,5-disubstituted zirconacyclopentadienes: a highly selective and general approach to 2,4-disubstituted phospholes.

Guillaume Bousrez , Florian Jaroschik , Agathe Martinez , Dominique Harakat , Emmanuel Nicolas , et al.
Dalton Transactions, 2013, epub ahead of print. ⟨10.1039/c3dt51158h⟩
Article dans une revue hal-00839784v1

Inorganic Chemistry Laboratory, University of Sussex

Florian Jaroschik
New stable organothulium(II) and the first organodysprosium(II) complexes by reduction of their trivalent precursors., Apr 2006, Brighton, United Kingdom
Communication dans un congrès hal-00107957v1

(+)-Camphor-mediated kinetic resolution of allylalanes: a strategy towards enantio-enriched cyclohex-2-en-1-ylalane

Michaël Coffinet , Fabien Massicot , Jomy Joseph , Jean-Bernard Behr , Florian Jaroschik , et al.
Chemical Communications, 2017, 53 (1), pp.111-114. ⟨10.1039/C6CC08649G⟩
Article dans une revue hal-01996082v1

Lewis Acid Catalyzed Three-Component [3+2] Cycloaddition Reaction Using Pentafulvene as 2π Component: An Easy Way to Construct Pentaleno(1,2-b)indoles

P. Santhini , S. Sarath Chand , Jubi John , R. Varma , Florian Jaroschik , et al.
SYNLETT, 2017, 28 (08), pp.951-956. ⟨10.1055/s-0036-1588696⟩
Article dans une revue hal-01996107v1

Lanthanides and actinides: Annual survey of their organometallic chemistry covering the year 2018

Frank Edelmann , Joy Farnaby , Florian Jaroschik , Bradley Wilson
Coordination Chemistry Reviews, 2019, 398, pp.113005. ⟨10.1016/j.ccr.2019.07.002⟩
Article dans une revue hal-02307350v1

Titanocene dichloride complexes bonded to carbosilane dendrimers via a spacer of variable length – Molecular dynamics calculations and catalysis of allylic coupling reactions

Tomáš Strašák , Florian Jaroschik , Marek Maly , Jan Čermák , Jan Sykora , et al.
Inorganica Chimica Acta, 2014, 409, pp.137-146. ⟨10.1016/j.ica.2013.07.020⟩
Article dans une revue hal-01995951v1

Zirconocenes vs. Alanes: a Crucial Choice of the Allyl Source for Highly Diastereoselective Allylzincation of Nonracemic Chiral Imines

Michaël Coffinet , Florian Jaroschik , Jean-Luc Vasse
European Journal of Organic Chemistry, 2016, 2016 (13), pp.2319-2327. ⟨10.1002/ejoc.201600214⟩
Article dans une revue istex hal-01996246v1

Recent Advances in the Chemistry of Pentafulvenes

Preethanuj Preethalayam , K. Syam Krishnan , Sreeja Thulasi , S. Sarath Chand , Jomy Joseph , et al.
Chemical Reviews, 2017, 117 (5), pp.3930-3989. ⟨10.1021/acs.chemrev.6b00210⟩
Article dans une revue hal-01990575v1
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Photo‐induced Desulfurative Processes for Carbon Radical Generation

Lilian Geniller , Marc Taillefer , Florian Jaroschik , Alexis Prieto
ChemCatChem, In press, ⟨10.1002/cctc.202300808⟩
Article dans une revue hal-04214603v1

Picking One out of Three: Selective Single C−F Activation in Trifluoromethyl Groups

Florian Jaroschik
Chemistry - A European Journal, 2018, 24 (55), pp.14572 - 14582. ⟨10.1002/chem.201801702⟩
Article dans une revue hal-01901168v1
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Photo‐Induced Halogen‐Atom Transfer: Generation of Halide Radicals for Selective Hydrohalogenation Reactions

Lilian Geniller , Marc Taillefer , Florian Jaroschik , Alexis Prieto
Chemistry - A European Journal, In press, ⟨10.1002/chem.202201495⟩
Article dans une revue hal-03694755v1

Synthesis, Characterization and Reactivity of Mono(phospholyl)lanthanoid(III) Bis(dimethylaminobenzyl) Complexes.

Florian Jaroschik , Takanori Shima , Xiaofang Li , Kyouchi Mori , Louis Ricard , et al.
Organometallics, 2007, 26, pp.5654-5660
Article dans une revue hal-00168883v1
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A new divalent organoeuropium(II) fluoride and serendipitous discovery of an alkoxide complex from pentaphenylcyclopentadiene precursors

Angus Shephard , Aymeric Delon , Rory Kelly , Zhifang Guo , Sylviane Chevreux , et al.
Australian Journal of Chemistry, 2022, 75, in press. ⟨10.1071/CH21324⟩
Article dans une revue hal-03653823v1
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Synthesis of organophosphores complexes of di -and trivalent lanthanides and their application in catalysis.

Florian Jaroschik
Chemical Sciences. Ecole Polytechnique X, 2007. English. ⟨NNT : ⟩
Thèse pastel-00003025v1

GECOM CONCOORD 2006

Thibault Cantat , Florian Jaroschik , Louis Ricard , François Nief , Nicolas Mézailles , et al.
Utilisation de nouveaux dianions géminaux comme précurseurs carbéniques., May 2006, Noirmoutier, France
Communication dans un congrès hal-00108145v1

Application of Elemental Lanthanides in the Selective C-F Activation of Trifluoromethylated Benzofulvenes Providing Access to Various Difluoroalkenes

Tarun Kumar , Amira Ben Hassine , Agathe Martinez , Dominique Harakat , Sylviane Chevreux , et al.
Journal of visualized experiments : JoVE, 2018, 137, ⟨10.3791/57948⟩
Article dans une revue hal-01887678v1

Titanium-Catalyzed Hydroalumination of Conjugated Dienes: Access to Fulvene-Derived Allylaluminium Reagents and Their Diastereoselective Reactions with Carbonyl Compounds

Jomy Joseph , Florian Jaroschik , Dominique Harakat , K. Radhakrishnan , Jean-Luc Vasse , et al.
Chemistry - A European Journal, 2014, 20 (18), pp.5433-5438. ⟨10.1002/chem.201304775⟩
Article dans une revue istex hal-01995984v1

Bulky Group 2 Octaphenylmetallocenes and Direct Access to Calcium and Ytterbium Pseudo-Grignard Complexes

Glen Deacon , Florian Jaroschik , Peter Junk , Rory P Kelly
Organometallics, 2014, 34 (11), pp.2369-2377. ⟨10.1021/om501150b⟩
Article dans une revue hal-01996293v1

Thulium alkylidene complexes: synthesis, x-ray structures, and reactivity

Thibault Cantat , Florian Jaroschik , Louis Ricard , Pascal Le Floch , François Nief , et al.
Organometallics, 2006, 25, pp.1329. ⟨10.1021/om050877c⟩
Article dans une revue istex hal-00090426v1

Isolation of Stable Organodysprosium(II) Complexes by Chemical Reduction of Dysprosium(III) Precursors

Florian Jaroschik , François Nief , X. F Le Goff , Louis Ricard
Organometallics, 2007, 26 (5), pp.1123 -1125. ⟨10.1021/om0700213⟩
Article dans une revue istex hal-00168526v1

Fullerene matrices in the MALDI-TOF mass spectroscopic characterisation of organometallic compounds

Glen Deacon , Leslie Field , Keith Fisher , Florian Jaroschik , Danielle Kay , et al.
Journal of Organometallic Chemistry, 2014, 751, pp.482-492. ⟨10.1016/j.jorganchem.2013.10.025⟩
Article dans une revue hal-01995967v1
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Selective carbon-phosphorus bond cleavage: expanding the toolbox for accessing bulky divalent lanthanoid sandwich complexes

Angus Shephard , Daisy Daniels , Glen Deacon , Zhifang Guo , Florian Jaroschik , et al.
Chemical Communications, 2022, 58 (27), pp.4344-4347. ⟨10.1039/d2cc00698g⟩
Article dans une revue hal-03628397v1
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Tuning the Regioselective Functionalization of Trifluoromethylated Dienes via Lanthanum‐Mediated Single C−F Bond Activation

Tarun Kumar , Yan Yang , Sirine Sghaier , Yassir Zaid , X. F Le Goff , et al.
Chemistry - A European Journal, 2021, 27 (12), pp.4016-4021. ⟨10.1002/chem.202005239⟩
Article dans une revue hal-03264465v1