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Éva JAKAB TÓTH


JAKAB TÓTH Éva

 

Directrice de recherche 1ère classe CNRS

Adresse professionnnelle : Centre de Biophysique Moléculaire, CNRS, Rue Charles Sadron, 45071 Orléans, Cedex 2, France

Phone: +33 2 38 25 55 89

E-mail : eva.jakabtoth@cnrs-orleans.fr

http://cbm.cnrs-orleans.fr/

FORMATION - TITRES SCIENTIFIQUES

1990   Diplôme universitaire en chimie "Summa cum laude" (Université de Debrecen, Hongrie)

1994   Doctorat en chimie de l'Université de Debrecen, Hongrie (avec félicitations du jury ; summa cum laude)

2004   Habilitation auprès de l'Académie des Sciences de Hongrie

2007   Qualification "Professeurs des Universités" - Section 32

 

EXPÉRIENCES PROFESSIONNELLES

1995-2000   Stage post-doctoral et première assistante à l'Université de Lausanne, Suisse

2001   Maître assistante à l'Université de Lausanne

2001-2005   Chargée de cours à l'École Polytechnique Fédérale de Lausanne, Suisse

2005   Directrice de Recherche CNRS (DR2) au Centre de Biophysique Moléculaire - CNRS, Orléans, France

2013   Promotion DR1

2012 -    Directrice du Centre de Biophysique Moléculaire (140 personnes)

 

DISTINCTIONS

1990   Prix de la Faculté des Sciences, Université de Debrecen, Hongrie

2018   Médaille d'argent du CNRS

 

ACTIVITÉS DE RECHERCHE

Conception, synthèse et caractérisation de nouvelles sondes à base de complexes de lanthanides pour l'imagerie biomédicale

Auteur de 162 publications dans des journaux internationaux, 14 chapitres de livre, 3 brevets.

Co-editeur du livre "The Chemistry of Contrats Agents in Medical Magnetic Resonance Imaging" (Wiley & sons 2001 (1st edition), 2013 (2nd edition). h-factor: 50.

78 invited conferences and seminars.

 

ACTIVITÉS DE FORMATION

Direction de 14 thèses, 6 post-docs

Accueil de 28 étudiants et post-doctorants en échange ; 6 professeurs invités

Enseignement au Master International "Bioimaging" Paris Descartes (2011- )

 

RESPONSABILITÉS SCIENTIFIQUES - ACTIVITÉS DE MANAGEMENT

  • Chair du réseau européen COST D38 "Metal-based systems for molecular imaging applications" (2008-2012 ; 50 laboratoires participants) ; Grant holder de l'Action COST TD1004 "Theranostics " (2012-2015)
  • Directrice du Groupement de Recherche (GDR) "Agents d'Imagerie Moléculaire" , France (~ 40 laboratoires partenaires)
  • Directrice du laboratoire International Associé "MirTANGO bis" avec l'Université Jaggelon de Cracovie, Pologne (2016-2020)
  • Membre de "Scientific Advisory Board" de Max Planck Institute for Biological Cybernetics, Tübingen, Germany (2008-2016)
  • Membre de "Scientific Advisory Board" of Maloposka Institute of biotechnology, Cracovie, Pologne (2016 - )
  • Membre du conseil Scientifique de l'Institut Multidisciplinaire Hubert Curien, Strasbourg (2011-)
  • Co-coordinator of the working Group "Chemistry for probes and contrast" in France Life Imaging
  • Membre de "International Advisory Board of Inorganic Chemistry" (ACS ; 2015-2017)
  • Membre de "International Advisory board of ChemMedChem" (Wiley ; 2017 - )

 

ORGANISATION DE CONFÉRENCES

  • Final COST D18 meeting "Lanthanide Chemistry for Diagnosis and Therapy", 31 march - 1 April 2006, Orléans, France
  • 1st Working Group Meeting "MRI Contrast Agents" du COST D38, Orléans, 8-9 Dec. 2006 ; 2nd Working Group Meeting "MRI Contrast Agents" du COST D38, Orléans, 29 Febr. - 1 March 2008 ; 3ème journées du groupe Polyamines, 14-16 June 2011, Orléans
  • 2010-2012: Member of the Scientific Organizing Committee of the european Molecular Imaging Meeting (EMIM), responsable for "Imaging Probe Design" sessions
  • Member of the Scientific Organizing Committee for Dalton discussions: Metal ions in Medical Imaging, York, Sept. 2014
  • Member of the National Organizing Committee for ICC42 in Brest, France, 2016
  • Convenor for the session "Methods and Application at the chemistry-Biology interface" at EuChems 2016, Sevilla
  • Medical Flavour of Metal Complexes, Studium Conference, Orléans, 8-10 Dec. 2015
  • Being Smart in Coordination Chemistry, Studium conference, Orléans, 26-28 Sept. 2016
  • Is Multimodal Imaging an Invention with future ? The input of chemistry, Studium conference, Orléans, 11-12 Dec. 2017
  • Journées scientifiques du GDR AIM, juin 2018, Orléans

 

 

 

 


Journal articles166 documents

  • Sara Pinto, Mário Calvete, Mariana Ghica, Sérgio Soler, Iluminada Gallardo, et al.. A biocompatible redox MRI probe based on a Mn( ii )/Mn( iii ) porphyrin. Dalton Transactions, Royal Society of Chemistry, 2019, 48 (10), pp.3249-3262. ⟨10.1039/c8dt04775h⟩. ⟨hal-02071232⟩
  • Markus Bödenler, Kyangwi Malikidogo, Jean-François Morfin, Christoph Aigner, Eva Toth, et al.. High‐Field Detection of biomarkers with Fast Field‐Cycling MRI: The Example of Zinc Sensing. Chemistry - A European Journal, Wiley-VCH Verlag, 2019, ⟨10.1002/chem.201901157⟩. ⟨hal-02117697⟩
  • Eva Toth, Sara Lacerda. Theranostics and Image Guided Drug Delivery. Edited by Maya Thanou. ChemMedChem, Wiley-VCH Verlag, 2018, 13 (17), pp.1851-1852. ⟨hal-01966410⟩
  • Kyangwi Malikidogo, Isidro da Silva, Jean-François Morfin, Sara Lacerda, Laurent Barantin, et al.. A cocktail of 165 Er( iii ) and Gd( iii ) complexes for quantitative detection of zinc using SPECT and MRI. Chemical Communications, Royal Society of Chemistry, 2018, 54 (55), pp.7597 - 7600. ⟨10.1039/c8cc03407a⟩. ⟨hal-01904447⟩
  • Pedro Miguel Costa, Julie Tzu-Wen Wang, Jean-François Morfin, Tamanna Khanum, Wan To, et al.. Functionalised Carbon Nanotubes Enhance Brain Delivery of Amyloid-Targeting Pittsburgh Compound B (PiB)-Derived Ligands. Nanotheranostics, 2018, 2 (2), pp.168-183. ⟨10.7150/ntno.23125⟩. ⟨hal-02080078⟩
  • Enikő Molnár, Balázs Váradi, Zoltán Garda, Richárd Botár, Ferenc Kálmán, et al.. Remarkable differences and similarities between the isomeric Mn(II)- cis - and trans- 1,2-diaminocyclohexane- N , N , N ′, N ′-tetraacetate complexes. Inorganica Chimica Acta Reviews, Elsevier, 2018, 472, pp.254-263. ⟨hal-01966166⟩
  • Julie Schmitt, Sébastien Jenni, Angélique Sour, Valérie Heitz, Frédéric Bolze, et al.. A Porphyrin Dimer–GdDOTA Conjugate as a Theranostic Agent for One- and Two-Photon Photodynamic Therapy and MRI. Bioconjugate Chemistry, American Chemical Society, 2018, 29 (11), pp.3726-3738. ⟨10.1021/acs.bioconjchem.8b00634⟩. ⟨hal-02071234⟩
  • Bedika Phukan, Kyangwi Malikidogo, Célia Bonnet, Éva Tóth, Samsuzzoha Mondal, et al.. A Bishydrated, Eight-Coordinate Gd(III) Complex with Very Fast Water Exchange: Synthesis, Characterization, and Phantom MR Imaging. ChemistrySelect, Wiley, 2018, 3 (27), pp.7668-7673. ⟨10.1002/slct.201801629⟩. ⟨hal-02071241⟩
  • Sophie Laine, Célia Bonnet, Ferenc Kálmán, Zoltán Garda, Agnès Pallier, et al.. Mn 2+ complexes of open-chain ligands with a pyridine backbone: less donor atoms lead to higher kinetic inertness. New Journal of Chemistry, Royal Society of Chemistry, 2018, 42 (10), pp.8012-8020. ⟨hal-01966154⟩
  • Florian Mayer, Sriram Tiruvadi Krishnan, Daniel Schühle, Svetlana Eliseeva, Stéphane Petoud, et al.. Luminescence Properties of Self-Aggregating TbIII-DOTA-Functionalized Calix[4]arenes. Frontiers in Chemistry, Frontiers, 2018, 6. ⟨hal-01966160⟩
  • Janet Morrow, Éva Tóth. Next-Generation Magnetic Resonance Imaging Contrast Agents. Inorganic Chemistry, American Chemical Society, 2017, 56 (11), pp.6029-6034. ⟨10.1021/acs.inorgchem.7b01277⟩. ⟨hal-02071700⟩
  • Christian Vanasschen, Enikő Molnár, Gyula Tircsó, Ferenc K. Kálmán, Éva Tóth, et al.. Novel CDTA-based, Bifunctional Chelators for Stable and Inert Mn II Complexation: Synthesis and Physicochemical Characterization. Inorganic Chemistry, American Chemical Society, 2017, 56 (14), pp.7746 - 7760. ⟨10.1021/acs.inorgchem.7b00460⟩. ⟨hal-01632898⟩
  • Rodolphe Pollet, Celia Bonnet, Pascal Retailleau, Philippe Durand, Eva Tóth. Proton-exchange in a paramagnetic chemical exchange saturation transfer agent from experimental studies and ab initio metadynamics simulation. Inorganic Chemistry, American Chemical Society, 2017, 56, pp.4317-4323. ⟨http://pubs.acs.org/doi/abs/10.1021/acs.inorgchem.6b02773⟩. ⟨10.1021/acs.inorgchem.6b02773⟩. ⟨cea-01496904⟩
  • Goran Angelovski, Éva Tóth. Strategies for sensing neurotransmitters with responsive MRI contrast agents. Chemical Society Reviews, Royal Society of Chemistry, 2017, 46 (2), pp.324 - 336. ⟨10.1039/C6CS00154H⟩. ⟨hal-01632884⟩
  • Jonathan Pansieri, Marie Plissonneau, Nathalie Stransky-Heilkron, Mireille Dumoulin, Laurence Heinrich-Balard, et al.. Multimodal imaging Gd-nanoparticles functionalized with Pittsburgh compound B or a nanobody for amyloid plaques targeting.. Nanomedicine, Future Medicine, 2017, 12 (14), pp.1675-1687. ⟨10.2217/nnm-2017-0079⟩. ⟨hal-01561318⟩
  • S. Lacerda, J.-F. Morfin, C. Geraldes, É. Tóth. Metal complexes for multimodal imaging of misfolded protein-related diseases. Dalton Transactions, Royal Society of Chemistry, 2017, 46 (42), pp.14461-14474. ⟨10.1039/C7DT02371E⟩. ⟨hal-02068723⟩
  • Wuyuan Zhang, Jonathan Martinelli, Joop A. Peters, Jacob M.A. van Hengst, Hans Bouwmeester, et al.. Surface PEG Grafting Density Determines Magnetic Relaxation Properties of Gd-Loaded Porous Nanoparticles for MR Imaging Applications. ACS Applied Materials & Interfaces, Washington, D.C. : American Chemical Society, 2017, 9 (28), pp.23458 - 23465. ⟨10.1021/acsami.7b05912⟩. ⟨hal-01632905⟩
  • Sara Lacerda, Éva Tóth. Lanthanide Complexes in Molecular Magnetic Resonance Imaging and Theranostics. ChemMedChem, Wiley-VCH Verlag, 2017, 12 (12), pp.883 - 894. ⟨10.1002/cmdc.201700210⟩. ⟨hal-01618333⟩
  • Jean Wilfried Fredy, Jérémy Scelle, Gregory Ramniceanu, Bich-Thuy Doan, Célia S. Bonnet, et al.. Mechanostereoselective One-Pot Synthesis of Functionalized Head-to-Head Cyclodextrin [3]Rotaxanes and Their Application as Magnetic Resonance Imaging Contrast Agents. Organic Letters, American Chemical Society, 2017, 19 (5), pp.1136-1139. ⟨10.1021/acs.orglett.7b00153⟩. ⟨hal-01480341⟩
  • André Martins, Alexandre Oliveira, Jean-François Morfin, Douglas Laurents, Éva Tóth, et al.. Associating a negatively charged GdDOTA-derivative to the Pittsburgh compound B for targeting Aβ amyloid aggregates. Journal of Biological Inorganic Chemistry, Springer Verlag, 2016, 21 (1), pp.83-99. ⟨10.1007/s00775-015-1316-9⟩. ⟨hal-02069097⟩
  • Sara M.A. Pinto, Vanessa A. Tomé, Mário J.F. Calvete, Mariette M. Pereira, Hugh D. Burrows, et al.. The quest for biocompatible phthalocyanines for molecular imaging: Photophysics, relaxometry and cytotoxicity studies. Journal of Inorganic Biochemistry, Elsevier, 2016, 154, pp.50 - 59. ⟨10.1016/j.jinorgbio.2015.10.013⟩. ⟨hal-01407515⟩
  • D Cressier, M Dhilly, Tt Cao Pham, F Fillesoye, F Gourand, et al.. Gallium-68 Complexes Conjugated to Pittsburgh Compound B: Radiolabeling and Biological Evaluation. Molecular Imaging and Biology, Springer Verlag, 2016, 18 (3), pp.334-43. ⟨10.1007/s11307-015-0906-9⟩. ⟨hal-01575680⟩
  • Marie Plissonneau, Jonathan Pansieri, Laurence Heinrich-Balard, Jean-François Morfin, Nathalie Stransky-Heilkron, et al.. Gd-nanoparticles functionalization with specific peptides for ß-amyloid plaques targeting.. Journal of Nanobiotechnology, BioMed Central, 2016, 14 (1), pp.60. ⟨10.1186/s12951-016-0212-y⟩. ⟨hal-01356748⟩
  • J. Aríñez-Soriano, Albalad J., Carné-Sánchez J., Celia Bonnet, Busqué C. S., et al.. pH-responsive relaxometric behaviour of coordination polymer nanoparticles made of a stable macrocyclic gadolinium macrocyclic chelate. Chemistry - A European Journal, Wiley-VCH Verlag, 2016, 22 (37), pp.13162-13170. ⟨10.1002/chem.201602356⟩. ⟨hal-01405351⟩
  • Célia S. Bonnet, Éva Tóth. Smart Contrast Agents for Magnetic Resonance Imaging. CHIMIA, Schweizerische Chemische Gesellschaft, 2016, 70 (1), pp.102 - 108. ⟨10.2533/chimia.2016.102⟩. ⟨hal-01405839⟩
  • Julie Schmitt, Valérie Heitz, Angélique Sour, Frédéric Bolze, Pascal Kessler, et al.. A Theranostic Agent Combining a Two-Photon-Absorbing Photosensitizer for Photodynamic Therapy and a Gadolinium(III) Complex for MRI Detection. Chemistry - A European Journal, Wiley-VCH Verlag, 2016, 22 (8), pp.2775 - 2786. ⟨10.1002/chem.201503433⟩. ⟨hal-01407691⟩
  • Jiefang He, Célia S. Bonnet, Svetlana V. Eliseeva, Sara Lacerda, Thomas Chauvin, et al.. Prototypes of Lanthanide(III) Agents Responsive to Enzymatic Activities in Three Complementary Imaging Modalities: Visible/Near-Infrared Luminescence, PARACEST-, and T 1 -MRI. Journal of the American Chemical Society, American Chemical Society, 2016, 138 (9), pp.2913 - 2916. ⟨10.1021/jacs.5b12084⟩. ⟨hal-01407004⟩
  • Gyula Tircsó, Martín Regueiro-Figueroa, Viktória Nagy, Zoltán Garda, Tamás Garai, et al.. Approaching the Kinetic Inertness of Macrocyclic Gadolinium(III)-Based MRI Contrast Agents with Highly Rigid Open-Chain Derivatives. Chemistry - A European Journal, Wiley-VCH Verlag, 2016, 22 (3), pp.896 - 901. ⟨10.1002/chem.201503836⟩. ⟨hal-01407817⟩
  • Angélique Sour, Sébastien Jenni, Ana Ortí-Suárez, Julie Schmitt, Valérie Heitz, et al.. Four Gadolinium(III) Complexes Appended to a Porphyrin: A Water-Soluble Molecular Theranostic Agent with Remarkable Relaxivity Suited for MRI Tracking of the Photosensitizer. Inorganic Chemistry, American Chemical Society, 2016, 55 (9), pp.4545 - 4554. ⟨10.1021/acs.inorgchem.6b00381⟩. ⟨hal-01407711⟩
  • Ferenc Krisztián Kálmán, Andrea Végh, Martín Regueiro-Figueroa, Éva Tóth, Carlos Platas-Iglesias, et al.. H 4 octapa: Highly Stable Complexation of Lanthanide(III) Ions and Copper(II). Inorganic Chemistry, American Chemical Society, 2015, 54 (5), pp.2345-2356. ⟨10.1021/ic502966m⟩. ⟨hal-02072274⟩
  • Martín Regueiro-Figueroa, José Luis Barriada, Agnès Pallier, David Esteban-Gómez, Andrés De Blas, et al.. Stabilizing Divalent Europium in Aqueous Solution Using Size-Discrimination and Electrostatic Effects. Inorganic Chemistry, American Chemical Society, 2015, 54 (10), pp.4940-4952. ⟨10.1021/acs.inorgchem.5b00548⟩. ⟨hal-01196972⟩
  • Célia S. Bonnet, Sophie Laine, Frédéric Buron, Gyula Tircsó, Agnès Pallier, et al.. A Pyridine-Based Ligand with Two Hydrazine Functions for Lanthanide Chelation: Remarkable Kinetic Inertness for a Linear, Bishydrated Complex. Inorganic Chemistry, American Chemical Society, 2015, 54 (12), pp.5991-6003. ⟨10.1021/acs.inorgchem.5b00804⟩. ⟨hal-01196977⟩
  • Fatima Oukhatar, Sandra Même, William Même, Frédéric Szeremeta, Nikos K. Logothetis, et al.. MRI Sensing of Neurotransmitters with a Crown Ether Appended Gd3+ Complex. ACS Chemical Neuroscience, American Chemical Society (ACS), 2015, 6 (2), pp.219-225. ⟨10.1021/cn500289y⟩. ⟨hal-01171764⟩
  • Fatima Oukhatar, Hervé Meudal, Céline Landon, Nikos K Logothetis, Carlos Platas-Iglesias, et al.. Macrocyclic Gd(3+) Complexes with Pendant Crown Ethers Designed for Binding Zwitterionic Neurotransmitters.. Chemistry - A European Journal, Wiley-VCH Verlag, 2015, 21 (31), pp.11226-11237. ⟨hal-01196981⟩
  • Slávka Kaščáková, Alexandre Giuliani, Sara Lacerda, Agnès Pallier, Pascal Mercère, et al.. X-ray-induced radiophotodynamic therapy (RPDT) using lanthanide micelles: Beyond depth limitations. Nano Research, Springer, 2015, 8, pp.2373 - 2379. ⟨http://link.springer.com/article/10.1007/s12274-015-0747-5⟩. ⟨10.1007/s12274-015-0747-5⟩. ⟨hal-01479428⟩
  • André F. Martins, David M. Dias, Jean-François Morfin, Sara Lacerda, Douglas V. Laurents, et al.. Interaction of PiB-Derivative Metal Complexes with Beta-Amyloid Peptides: Selective Recognition of the Aggregated Forms. Chemistry - A European Journal, Wiley-VCH Verlag, 2015, 21 (14), pp.5413-5422. ⟨10.1002/chem.201406152⟩. ⟨hal-01171718⟩
  • Jean-François Morfin, Jean-Claude Beloeil, Toth Eva. Agents de contraste pour l'IRM. Techniques de l'Ingenieur, Techniques de l'ingénieur, 2014, pp.AF6818-1 - AF6818-19. ⟨hal-01179490⟩
  • André F Martins, Jean-François Morfin, Carlos F G C Geraldes, Eva Tóth. Gd(3+) complexes conjugated to Pittsburgh compound B: potential MRI markers of β-amyloid plaques.. European Journal of Biochemistry, Wiley, 2014, 19 (2), pp.281-295. ⟨hal-01179355⟩
  • André F Martins, Svetlana V Eliseeva, Henrique F Carvalho, João M C Teixeira, Carlos T B Paula, et al.. A bis(pyridine N-oxide) analogue of DOTA: relaxometric properties of the Gd(III) complex and efficient sensitization of visible and NIR-emitting lanthanide(III) cations including Pr(III) and Ho(III).. Chemistry - A European Journal, Wiley-VCH Verlag, 2014, 20 (45), pp.14834-14845. ⟨hal-01179363⟩
  • Florian Mayer, Wuyuan Zhang, Thomas Brichart, Olivier Tillement, Célia S Bonnet, et al.. Nanozeolite-LTL with Gd(III) deposited in the large and Eu(III) in the small cavities as a magnetic resonance optical imaging probe.. Chemistry - A European Journal, Wiley-VCH Verlag, 2014, 20 (12), pp.3358-3364. ⟨hal-01179402⟩
  • Jean Wilfried Fredy, Jérémy Scelle, Aurélie Guenet, Elodie Morel, Ségolène Adam de beaumais, et al.. Cyclodextrin Polyrotaxanes as a Highly Modular Platform for the Development of Imaging Agents. Chemistry - A European Journal, Wiley-VCH Verlag, 2014, 20 (35), pp.10915-10920. ⟨10.1002/chem.201403635⟩. ⟨hal-01178990⟩
  • Célia S. Bonnet, Fabien Caillé, Agnès Pallier, Jean-François Morfin, Stéphane Petoud, et al.. Mechanistic Studies of Gd3+-Based MRI Contrast Agents for Zn2+ Detection: Towards Rational Design. Chemistry - A European Journal, Wiley-VCH Verlag, 2014, 20 (35), pp.10959-10969. ⟨10.1002/chem.201403043⟩. ⟨hal-01178456⟩
  • André F. Martins, Jean-François Morfin, Anna Kubícková, Vojtěch Kubícek, Frédéric Buron, et al.. PiB-Conjugated, Metal-Based Imaging Probes: Multimodal Approaches for the Visualization of β-Amyloid Plaques. Planetary and Space Science, Elsevier, 2013, 4 (5), pp.436-440. ⟨10.1021/ml400042w⟩. ⟨hal-00840181⟩
  • Sara Lacerda, Célia S Bonnet, Agnès Pallier, Sandrine Villette, Frédéric Foucher, et al.. Lanthanide-Based, Near-Infrared Luminescent and Magnetic Lipoparticles: Monitoring Particle Integrity.. Small, Wiley-VCH Verlag, 2013, 9 (16), pp.2662-2666. ⟨10.1002/smll.201201923⟩. ⟨hal-00817465⟩
  • M.F. Ferreira, A.F. Martins, C.I.O. Martins, E. TÓth, T.B. Rodrigues, et al.. Amide conjugates of the DO3A-N-(alpha-amino)propionate ligand: leads for stable, high relaxivity Contrast Agents for MRI?. Contrast Media and Molecular Imaging, Wiley, 2013, 8 (1), pp.40-49. ⟨10.1002/cmmi.1492⟩. ⟨hal-00748283⟩
  • Ana Catarina Fernandes Mendonça, André F Martins, Andrea Melchior, Sérgio M Marques, Sílvia Chaves, et al.. New tris-3,4-HOPO lanthanide complexes as potential imaging probes: complex stability and magnetic properties.. Dalton Transactions, Royal Society of Chemistry, 2013, 42 (17), pp.6046-57. ⟨10.1039/c2dt32237d⟩. ⟨hal-00817499⟩
  • Arsénio de Sá, Célia S Bonnet, Carlos F G C Geraldes, Éva Tóth, Paula M T Ferreira, et al.. Thermodynamic stability and relaxation studies of small, triaza-macrocyclic Mn(II) chelates.. Dalton Transactions, Royal Society of Chemistry, 2013, 42 (13), pp.4522-32. ⟨10.1039/c2dt32496b⟩. ⟨hal-00817441⟩
  • Arnau Carné-Sánchez, Célia Bonnet, Inhar Imaz, Julia Lorenzo, Éva Tóth, et al.. Relaxometry Studies of a Highly Stable Nanoscale Metal–Organic Framework Made of Cu(II), Gd(III), and the Macrocyclic DOTP. Journal of the American Chemical Society, American Chemical Society, 2013, 135 (47), pp.17711-17714. ⟨10.1021/ja4094378⟩. ⟨hal-02070737⟩
  • Nicolas Arlicot, Hélène Fourmy, Martin André, Johnny Vercouillie, Carlos Geraldes, et al.. Radiolabeling and initial evaluation of [In-111]AML-1, a new probe for SPECT imaging of amyloid deposits. Journal of Labelled Compounds and Radiopharmaceuticals, Wiley-Blackwell, 2013, 56 (supplément 1), pp.S307. ⟨hal-02266846⟩
  • Adrián Roca-Sabio, Célia S Bonnet, Marta Mato-Iglesias, David Esteban-Gómez, Éva Tóth, et al.. Lanthanide complexes based on a diazapyridinophane platform containing picolinate pendants.. Inorganic Chemistry, American Chemical Society, 2012, 51 (20), pp.10893-10903. ⟨10.1021/ic301369z⟩. ⟨hal-00817354⟩
  • Fabien Caillé, Célia S Bonnet, Frédéric Buron, Sandrine Villette, Lothar Helm, et al.. Isoquinoline-based lanthanide complexes: bright NIR optical probes and efficient MRI agents.. Inorganic Chemistry, American Chemical Society, 2012, 51 (4), pp.2522-32. ⟨10.1021/ic202446e⟩. ⟨hal-00721803⟩
  • L.M.P. Lima, R. Degaldo, P. Hermann, R. Sevcik, P. Lubal, et al.. Tris(phosphonomethyl)cyclen Derivatives: Thermodynamic Stability, Kinetics, Solution Structure, and Relaxivity of Ln3+ Complexes. European Journal of Inorganic Chemistry, Wiley-VCH Verlag, 2012, 2012 (15), pp.2548-2559. ⟨10.1002/ejic.201101335⟩. ⟨hal-00726233⟩
  • Bohuslav Drahos, Ivan Lukes, Eva Toth. Manganese(II) Complexes as Potential Contrast Agents for MRI. European Journal of Inorganic Chemistry, Wiley-VCH Verlag, 2012, 12 (SI), pp.1975-1986. ⟨10.1002/ejic.201101336⟩. ⟨hal-00721852⟩
  • Célia S Bonnet, Frédéric Buron, Fabien Caillé, Chad M Shade, Bohuslav Drahoš, et al.. Pyridine-based lanthanide complexes combining MRI and NIR luminescence activities.. Chemistry - A European Journal, Wiley-VCH Verlag, 2012, 18 (5), pp.1419-31. ⟨10.1002/chem.201102310⟩. ⟨hal-00720541⟩
  • Thomas Chauvin, Susana Torres, Renato Rosseto, Jan Kotek, Bernard Badet, et al.. Lanthanide(III) complexes that contain a self-immolative arm: potential enzyme responsive contrast agents for magnetic resonance imaging.. Chemistry - A European Journal, Wiley-VCH Verlag, 2012, 18 (5), pp.1408-18. ⟨10.1002/chem.201101779⟩. ⟨hal-00679094⟩
  • Gyula Tircsó, Ferenc Kálmán, Robert Pal, István Bányai, Tamas Varga, et al.. Lanthanide Complexes Formed with the Tri- and Tetraacetate Derivatives of Bis(aminomethyl)phosphinic Acid: Equilibrium, Kinetic and NMR Spectroscopic Studies. European Journal of Inorganic Chemistry, Wiley-VCH Verlag, 2012, 2012 (12), pp.2062-2073. ⟨10.1002/ejic.201101299⟩. ⟨hal-02080230⟩
  • Bohuslav Drahoš, Jan Kotek, Ivana Císařová, Petr Hermann, Lothar Helm, et al.. Mn2+ complexes with 12-membered pyridine based macrocycles bearing carboxylate or phosphonate pendant arm: crystallographic, thermodynamic, kinetic, redox, and 1H/17O relaxation studies.. Inorganic Chemistry, American Chemical Society, 2011, 50 (24), pp.12785-801. ⟨10.1021/ic201935r⟩. ⟨hal-00720603⟩
  • Jörg Henig, Ilgar Mamedov, Petra Fouskova, Éva Tóth, Nikos K Logothetis, et al.. Influence of calcium-induced aggregation on the sensitivity of aminobis(methylenephosphonate)-containing potential MRI contrast agents.. Inorganic Chemistry, American Chemical Society, 2011, 50 (14), pp.6472-81. ⟨10.1021/ic1024235⟩. ⟨hal-00720609⟩
  • Jean-François Morfin, Éva Tóth. Kinetics of Ga(NOTA) formation from weak Ga-citrate complexes.. Inorganic Chemistry, American Chemical Society, 2011, 50 (20), pp.10371-8. ⟨10.1021/ic201445e⟩. ⟨hal-00720677⟩
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  • László Burai, Éva Tóth, André Merbach. HPLC separation of diastereomers of Ln III -ethylenepropylene-triamine-pentaacetate complexes. Direct assessment of their water exchange rate. Chemical Communications, Royal Society of Chemistry, 2003, pp.2680-2681. ⟨10.1039/B308253A⟩. ⟨hal-02080482⟩
  • Sabrina Laus, Robert Ruloff, Éva Tóth, André Merbach. GdIII Complexes with Fast Water Exchange and High Thermodynamic Stability: Potential Building Blocks for High-Relaxivity MRI Contrast Agents. Chemistry - A European Journal, Wiley-VCH Verlag, 2003, 9 (15), pp.3555-3566. ⟨10.1002/chem.200204612⟩. ⟨hal-02080490⟩
  • L Burai, Éva Tóth, G. Moreau, Angélique Sour, R. Scopelliti, et al.. Novel macrocyclic EuII complexes: fast water exchange related to an extreme metal-coordinated water oxygen distance. Chemistry - A European Journal, Wiley-VCH Verlag, 2003, ⟨10.1002/chem.200390159⟩. ⟨hal-02080835⟩
  • Robert Ruloff, Eva Toth, Rosario Scopelliti, Raphaël Tripier, Henri Handel, et al.. Accelerating water exchange for GdIII chelates by steric compression around the water binding site.. Chemical Communications, Royal Society of Chemistry, 2002, pp.2630-1. ⟨hal-02080840⟩
  • Gaëlle Nicolle, Eva Toth, Heribert Schmitt-Willich, Bernd Radüchel, André Merbach. The impact of rigidity and water exchange on the relaxivity of a dendritic MRI contrast agent.. Chemistry - A European Journal, Wiley-VCH Verlag, 2002, 8 (5), pp.1040-8. ⟨10.1002/1521-3765(20020301)8:5<1040::AID-CHEM1040>3.0.CO;2-D⟩. ⟨hal-02080847⟩
  • Gaëlle Nicolle, Eva Toth, Klaus-Peter Eisenwiener, Helmut Mäcke, André Merbach. From monomers to micelles: investigation of the parameters influencing proton relaxivity.. Journal of Biological Inorganic Chemistry, Springer Verlag, 2002, 7 (7-8), pp.757-69. ⟨10.1007/s00775-002-0353-3⟩. ⟨hal-02080844⟩
  • László Burai, Rosario Scopelliti, Eva Toth. EuII-cryptate with optimal water exchange and electronic relaxation: a synthon for potential pO2 responsive macromolecular MRI contrast agents.. Chemical Communications, Royal Society of Chemistry, 2002, pp.2366-7. ⟨hal-02080842⟩
  • A. Pasquarello, P Petri, P Salmon, O. Parisel, R. Car, et al.. First solvation shell of the Cu(II) aqua ion: evidence for fivefold coordination.. Science, American Association for the Advancement of Science, 2001, 291 (5505), pp.856-9. ⟨10.1126/science.291.5505.856⟩. ⟨hal-02080849⟩
  • A Dunand, Éva Tóth, R Hollister, A Merbach. Lipari-Szabo approach as a tool for the analysis of macromolecular gadolinium(III)-based MRI contrast agents illustrated by the [Gd(EGTA-BA-(CH2)12)]nn+ polymer.. Journal of Biological Inorganic Chemistry, Springer Verlag, 2001, 6 (3), pp.247-55. ⟨hal-02080852⟩
  • Éva Tóth, László Burai, André Merbach. Similarities and differences between the isoelectronic GdIII and EuII complexes with regard to MRI contrast agent applications. Coordination Chemistry Reviews, Elsevier, 2001, 216-217, pp.363-382. ⟨10.1016/S0010-8545(01)00312-5⟩. ⟨hal-02266825⟩
  • Carlos Platas, Fernando Avecilla, Andrés de Blas, Teresa Rodríguez-Blas, Carlos Geraldes, et al.. Mono- and bimetallic lanthanide(III) phenolic cryptates obtained by template reaction: solid state structure, photophysical properties and relaxivity †. Journal of the Chemical Society Dalton Transactions, Royal Society of Chemistry, The, 2000, pp.611-618. ⟨10.1039/A906675F⟩. ⟨hal-02080879⟩
  • László Burai, Eva Toth, Sabine Seibig, Rosario Scopelliti, André Merbach. Solution and Solid-State Characterization of EuII Chelates: A Possible Route Towards Redox Responsive MRI Contrast Agents. Chemistry - A European Journal, Wiley-VCH Verlag, 2000, 6 (20), pp.3761-3770. ⟨10.1002/1521-3765(20001016)6:20<3761::AID-CHEM3761>3.0.CO;2-6⟩. ⟨hal-02080862⟩
  • Nicolas Fatin-Rouge, Eva Toth, Didier Perret, Robin Backer, André Merbach, et al.. Lanthanide Podates with Programmed Intermolecular Interactions: Luminescence Enhancement through Association with Cyclodextrins and Unusually Large Relaxivity of the Gadolinium Self-Aggregates. Journal of the American Chemical Society, American Chemical Society, 2000, 122 (44), pp.10810-10820. ⟨10.1021/ja001089b⟩. ⟨hal-02080856⟩
  • Sabine Seibig, Eva Toth, André Merbach. Unexpected Differences in the Dynamics and in the Nuclear and Electronic Relaxation Properties of the Isoelectronic [Eu II (DTPA)(H 2 O)] 3 - and [Gd III (DTPA)(H 2 O)] 2 - Complexes (DTPA = Diethylenetriamine Pentaacetate) 1. Journal of the American Chemical Society, American Chemical Society, 2000, 122 (24), pp.5822-5830. ⟨10.1021/ja9937829⟩. ⟨hal-02080866⟩
  • Alain Borel, Eva Toth, András Jánossy, Andre´ Merbach. EPR on aqueous Gd3+ complexes and a new analysis method considering both line widths and shifts. Physical Chemistry Chemical Physics, Royal Society of Chemistry, 2000, 2 (6), pp.1311-1317. ⟨10.1039/A909553E⟩. ⟨hal-02080875⟩
  • Fabrice Yerly, Franck Dunand, Éva Tóth, Arthur Figueirinha, Zoltan Kovacs, et al.. Spectroscopic Study of the Hydration Equilibria and Water Exchange Dynamics of Lanthanide(III) Complexes of 1,7-bis(carboxymethyl)-1,4,710-tetraazacyclododecane (DO2A). European Journal of Inorganic Chemistry, Wiley-VCH Verlag, 2000, pp.1001-1006. ⟨hal-02266818⟩
  • Erika Szilágyi, Eva Toth, Zoltán Kovács, Johannes Platzek, Bernd Radüchel, et al.. Equilibria and formation kinetics of some cyclen derivative complexes of lanthanides. Inorganica Chimica Acta Reviews, Elsevier, 2000, 298 (2), pp.226-234. ⟨10.1016/S0020-1693(99)00467-3⟩. ⟨hal-02080881⟩
  • M Adzamli, Éva Tóth, M Periasamy, S Koenig, M Merbach, et al.. 1H-NMRD and 17O-NMR assessment of water exchange and rotational dynamics of two potential MRI agents: MP-1177 (an extracellular agent) and MP-2269 (a blood pool agent).. Magnetic Resonance Materials in Physics, Biology and Medicine, Springer Verlag, 1999, 8 (3), pp.163-71. ⟨hal-02080889⟩
  • Eva Toth, Orla Dhubhghaill, Ghislaine Besson, Lothar Helm, André Merbach. Coordination equilibrium— a clue for fast water exchange on potential magnetic resonance imaging contrast agents?. Magnetic Resonance in Chemistry, Wiley, 1999, 37 (10), pp.701-708. ⟨10.1002/(SICI)1097-458X(199910)37:10<701::AID-MRC523>3.0.CO;2-6⟩. ⟨hal-02080894⟩
  • Eva Toth, Lothar Helm, Kenneth Kellar, André Merbach. Gd(DTPA-bisamide)alkyl Copolymers: A Hint for the Formation of MRI Contrast Agents with Very High Relaxivity. Chemistry - A European Journal, Wiley-VCH Verlag, 1999, 5 (4), pp.1202-1211. ⟨10.1002/(SICI)1521-3765(19990401)5:4<1202::AID-CHEM1202>3.0.CO;2-Y⟩. ⟨hal-02080907⟩
  • João André, Eva Toth, Holger Fischer, Anna Seelig, Helmut Mäcke, et al.. High Relaxivity for Monomeric Gd(DOTA)-Based MRI Contrast Agents, Thanks to Micellar Self-Organization. Chemistry - A European Journal, Wiley-VCH Verlag, 1999, 5 (10), pp.2977-2983. ⟨10.1002/(SICI)1521-3765(19991001)5:10<2977::AID-CHEM2977>3.0.CO;2-T⟩. ⟨hal-02080899⟩
  • Peter Caravan, Eva Toth, Antal Rockenbauer, André Merbach. Nuclear and Electronic Relaxation of Eu 2+ ( a q) : An Extremely Labile Aqua Ion 1. Journal of the American Chemical Society, American Chemical Society, 1999, 121 (44), pp.10403-10409. ⟨10.1021/ja992264v⟩. ⟨hal-02080885⟩
  • Erika Szilágyi, Eva Toth, Ernö Brücher, André Merbach. Lanthanide(III)–1,4,7,10-tetraazacyclododecane-1,4,7,10-tetraacetic acid complexes in acidic medium: significant decrease in water exchange rate . Journal of the Chemical Society Dalton Transactions, Royal Society of Chemistry, The, 1999, pp.2481-2486. ⟨10.1039/A903379C⟩. ⟨hal-02080887⟩
  • J.P. André, H Maecke, Éva Tóth, A Merbach. Synthesis and physicochemical characterization of a novel precursor for covalently bound macromolecular MRI contrast agents.. Journal of Biological Inorganic Chemistry, Springer Verlag, 1999, 4 (3), pp.341-7. ⟨hal-02080902⟩
  • Eva Toth, Lothar Helm, André Merbach, Roman Hedinger, Kaspar Hegetschweiler, et al.. Structure and Dynamics of a Trinuclear Gadolinium(III) Complex: The Effect of Intramolecular Electron Spin Relaxation on Its Proton Relaxivity 1. Inorganic Chemistry, American Chemical Society, 1998, 37 (16), pp.4104-4113. ⟨10.1021/ic980146n⟩. ⟨hal-02080926⟩
  • Roman Hedinger, Michele Ghisletta, Kaspar Hegetschweiler, Eva Toth, André Merbach, et al.. Trinuclear Lanthanoid Complexes of 1,3,5-Triamino-1,3,5-trideoxy-cis-inositol with a Unique, Sandwich-Type Cage Structure(1).. Inorganic Chemistry, American Chemical Society, 1998, 37 (26), pp.6698-6705. ⟨hal-02080909⟩
  • Eva Toth, Ingrid van Uffelen, Lothar Helm, André Merbach, David Ladd, et al.. Gadolinium-based linear polymer with temperature-independent proton relaxivities: a unique interplay between the water exchange and rotational contributions. Magnetic Resonance in Chemistry, Wiley, 1998, 36 (S1), pp.S125-S134. ⟨10.1002/(SICI)1097-458X(199806)36:1+3.0.CO;2-9⟩. ⟨hal-02080930⟩
  • Éva Tóth, André E. Merbach. Water exchange dynamics: The key for high relaxivity contrast agents in medical resonance imaging. ACH-MODELS IN CHEMISTRY, 1998, 135 (5), pp.873-884. ⟨hal-02266813⟩
  • Eva Toth, Fabienne Connac, Lothar Helm, Kofi Adzamli, André Merbach. 17O-NMR, EPR and NMRD Characterization of [Gd(DTPA-BMEA)(H2O)]: A Neutral MRI Contrast Agent. European Journal of Inorganic Chemistry, Wiley-VCH Verlag, 1998, 1998 (12), pp.2017-2021. ⟨10.1002/(SICI)1099-0682(199812)1998:12<2017::AID-EJIC2017>3.0.CO;2-Z⟩. ⟨hal-02080922⟩
  • Éva Tóth, Fabienne Connac, Lothar Helm, Kofi Adzamli, André Merbach. Direct assessment of water exchange on a Gd(III) chelate bound to a protein. Journal of Biological Inorganic Chemistry, Springer Verlag, 1998, 3 (6), pp.606-613. ⟨10.1007/s007750050273⟩. ⟨hal-02080916⟩
  • László Burai, Vesa Hietapelto, Róbert Király, Eva Toth, Ernő Brücher. Stability constants and1H relaxation effects of ternary complexes formed between gd-dtpa, gd-dtpa-bma, gd-dota, and gd-edta and citrate, phosphate, and carbonate ions. Magnetic Resonance in Medicine, Wiley, 1997, 38 (1), pp.146-150. ⟨10.1002/mrm.1910380120⟩. ⟨hal-02080946⟩
  • Eva Toth, László Burai, Ernö Brücher, André Merbach. Tuning water-exchange rates on (carboxymethyl)iminobis(ethylenenitrilo)tetraacetate (dtpa)-type gadolinium(III) complexes. Journal of the Chemical Society Dalton Transactions, Royal Society of Chemistry, The, 1997, pp.1587-1594. ⟨10.1039/A608505I⟩. ⟨hal-02080942⟩
  • Éva Tóth, Sylvain Vauthey, Dirk Pubanz, André Merbach. Water Exchange and Rotational Dynamics of the Dimeric Gadolinium(III) Complex [BO{Gd(DO3A)(H 2 O)} 2 ]: A Variable-Temperature and -Pressure 17 O NMR Study 1. Inorganic Chemistry, American Chemical Society, 1996, 35 (11), pp.3375-3379. ⟨10.1021/ic951492x⟩. ⟨hal-02266810⟩
  • A. Sherry, J. Ren, J. Huskens, E. Brücher, Éva Tóth, et al.. Characterization of Lanthanide(III) DOTP Complexes: Thermodynamics, Protonation, and Coordination to Alkali Metal Ions. Inorganic Chemistry, American Chemical Society, 1996, 35 (16), pp.4604-4612. ⟨10.1021/ic9600590⟩. ⟨hal-02080958⟩
  • Eva Toth, Dirk Pubanz, Sylvain Vauthey, Lothar Helm, André Merbach. The Role of Water Exchange in Attaining Maximum Relaxivities for Dendrimeric MRI Contrast Agents. Chemistry - A European Journal, Wiley-VCH Verlag, 1996, 2 (12), pp.1607-1615. ⟨10.1002/chem.19960021220⟩. ⟨hal-02080951⟩
  • Éva Tóth, R. Király, J. Platzek, B. Radüchel, E. Brücher. Equilibrium and kinetic studies on complexes of 10-[2,3-dihydroxy-(1-hydroxymethyl)-propyl]-1,4,7,10-tetraazacyclododecane-1,4,7-triacetate. Inorganica Chimica Acta Reviews, Elsevier, 1996, 249 (2), pp.191-199. ⟨10.1016/0020-1693(96)05094-3⟩. ⟨hal-02081004⟩
  • E. TÓth, E. Brücher. Stability constants of the lanthanide(III)-1,4,7,10-tetraazacyclododecane-N,N′,N″,N‴-tetraacetate complexes. Inorganica Chimica Acta Reviews, Elsevier, 1994, 221 (1-2), pp.165-167. ⟨10.1016/0020-1693(94)03964-X⟩. ⟨hal-02081015⟩
  • Eva Toth, Erno Brucher, Istvan Lazar, Imre Toth. Kinetics of Formation and Dissociation of Lanthanide(III)-DOTA Complexes. Inorganic Chemistry, American Chemical Society, 1994, 33 (18), pp.4070-4076. ⟨10.1021/ic00096a036⟩. ⟨hal-02081012⟩

Books1 document

  • Éva Tóth, André Merbach. The Chemistry of Contrast Agents in Medical Magnetic Resonance Imaging. John Wiley & Sons, Ltd, 2001. ⟨hal-02266853⟩

Book sections11 documents

  • Carlos F.G.C. Geraldes, Sara Lacerda, Eva Toth. Molecular Probes for Magnetic Resonance Imaging of Amyloid β Peptides. Reference Module in Chemistry, Molecular Sciences and Chemical Engineering, Elsevier, 2018, 9780124095472. ⟨10.1016/B978-0-12-409547-2.13926-5⟩. ⟨hal-02080790⟩
  • Célia Bonnet, Eva Toth. Molecular Magnetic Resonance Imaging Probes Based on Ln3+ Complexes. Advances in Inorganic Chemistry, pp.43-96, 2016, ⟨10.1016/bs.adioch.2015.09.002⟩. ⟨hal-02081246⟩
  • E. TÓth, L. Helm, A.E. Merbach. Metal Complexes as MRI Contrast Enhancement Agents. Reference Module in Chemistry, Molecular Sciences and Chemical Engineering, Elsevier, 2015, 978-0-12-409547-2. ⟨10.1016/B978-0-12-409547-2.11263-6⟩. ⟨hal-02081242⟩
  • Célia Bonnet, Eva Toth. MRI Contrast Agents. Ligand Design in Medicinal Inorganic Chemistry, John Wiley & Sons, Ltd, pp.321-354, 2014, ⟨10.1002/9781118697191.ch12⟩. ⟨hal-02081236⟩
  • Celia S. Bonnet, Lorenzo Tei, Mauro Botta, Eva Toth. Responsive Probes. Merbach Andre S., Helm Lothar, Tóth Eva. The Chemistry of Contrast Agents in Medical Magnetic Resonance Imaging, John Wiley & Sons, pp.343-385, 2013, 978-1-119-99176-2. ⟨hal-00876916⟩
  • Éva Tóth, Lothar Helm, André Merbach. Relaxivity of Gadolinium(III) Complexes: Theory and Mechanism. The Chemistry of Contrast Agents in Medical Magnetic Resonance Imaging, Second Edition, John Wiley & Sons, Ltd, pp.25-81, 2013, ⟨10.1002/9781118503652.ch2⟩. ⟨hal-02070939⟩
  • Eva Jakab-Toth, Célia Bonnet. MRI Contrast Agents, In Supramolecular Chemistry : From Molecules to Nanomaterials. Jonathan W. Steed, Philip A. Gale. Self-Assembly and Supramolecular Devices, 5, John Wiley & Sons, Ltd, pp.2693-2723, 2012, 978-0-470-74640-0. ⟨10.1002/9780470661345.Smc104⟩. ⟨hal-02071809⟩
  • Lothar Helm, Eva Toth. Gadolinium-Based Bionanomaterials for Magnetic Resonance Imaging. BALAJI SITHARAMAN. Nanobiomaterials Handbook, CRC Press, pp.1-34, 2011, ⟨10.1201/b10970-19⟩. ⟨hal-00614947⟩
  • Éva Tóth, L. Helm, André E. Merbach. Metal Complexes as MRI Contrast Enhancement Agents. Jon A. Mc Cleverty, J. Thomas. Compréhensive Coordination Chemistry II, 9, Elsevier, pp.841-881, 2004. ⟨hal-02266849⟩
  • Lothar Helm, Éva Tóth, André Merbach. Lanthanide ions as magnetic resonance imaging agents. Nuclear and electronic relaxation properties. Applications.. Metal Ionsin Biological Systems, 40 (15), Marcel Dekker INC., pp.589-642, 2003. ⟨hal-02266852⟩
  • Éva Tóth, Lothar Helm, André Merbach. Relaxivity of MRI Contrast Agents. Topics in Current Chemistry, 221 (2), pp.61-101, 2002, 978-3-540-42247-1. ⟨hal-02266848⟩

Directions of work or proceedings1 document

  • Alain Borel, Ingrid van Uffelen, Lothar Helm, Éva Tóth, André E. Merbach. Développement d'agents de contraste de haute relaxivité pour l'Imagerie par Résonance Magnétique - Proceedings of the "Deuxième Colloque Franco-Québecois en Chimie Inorganique et Organométallique" 1997. 1997, Castres, France. 1998. ⟨hal-02266811⟩

Patents1 document

  • Éva Tóth, Stephane Petoud, Célia Bonnet, S. Lacerda. Particles Comprising Luminescent Lanthanide Complexes. France, Patent n° : 13305291.0. 2014. ⟨hal-02081138⟩