Emmanuel Nicolas

Ingénieur-Chercheur

76%

Libre accès

Documents

Affiliations actuelles

247338

Publications

	Fluorophosphoniums as Lewis acids in organometallic catalysis: application in cobalt-catalyzed carbonylation of β-lactones Marie-Hélène Pietraru , Louise Ponsard , Nicolas Lentz , Pierre Thuéry , Emmanuel Nicolas Chemical Communications, 2023, 60 (8), pp.1043-1046. ⟨10.26434/chemrxiv-2023-d3r4g⟩ Article dans une revue cea-04440608v1
	Metal‐Free Catalytic Hydrogenolysis of Chlorosilanes into Hydrosilanes with “Inverse” Frustrated Lewis Pairs Gabriel Durin , Jean‐claude Berthet , Pierre Thuéry , Emmanuel Nicolas , Thibault Cantat Chemistry - A European Journal, 2023, 29 (61), ⟨10.1002/chem.202302155⟩ Article dans une revue hal-04236744v1
	Evaluation of acetophenone as a novel alcohol-cycloalkane bifunctional liquid organic hydrogen carrier (LOHC) Florian d'Ambra , Julia Levy , Parviz Hajiyev , Thibault Cantat , Gérard Gébel International Journal of Hydrogen Energy, 2023, 48 (85), pp.33207-33222. ⟨10.1016/j.ijhydene.2023.05.024⟩ Article dans une revue cea-04440528v1
	Catalytic Carbonylation of Acrylic Acid to Succinic Anhydride Marie‐Hélène Pietraru , Nicolas Lentz , Louise Ponsard , Emmanuel Nicolas , Thibault Cantat ChemCatChem, 2023, 15 (21), ⟨10.1002/cctc.202300720⟩ Article dans une revue cea-04440571v1
	Vers la synthèse de réducteurs renouvelables à base de silicium Gabriel Durin , Jean-Claude Berthet , Emmanuel Nicolas , Thibault Cantat L'Actualité Chimique, 2023, 487, pp.14-20 Article dans une revue cea-04440659v1
	Metal‐Free Catalytic Hydrogenolysis of Silyl Triflates and Halides into Hydrosilanes Gabriel Durin , Albane Fontaine , Jean‐claude Berthet , Emmanuel Nicolas , Pierre Thuéry Angewandte Chemie International Edition, 2022, 61 (23), pp.e202200911. ⟨10.1002/anie.202200911⟩ Article dans une revue hal-04097568v1
	The Role of ($^{tBu}$POCOP)Ir(I) and iridium(III) pincer complexes in the catalytic hydrogenolysis of silyl triflates into hydrosilanes Gabriel Durin , Jean-Claude Berthet , Emmanuel Nicolas , Thibault Cantat Organometallics, 2021, 2021 (41), pp.1786-1796. ⟨10.1021/acs.organomet.1c00576⟩ Article dans une revue cea-03547778v1
	Coupling electrocatalytic CO2 reduction with thermocatalysis enables the formation of a lactone monomer Marc Fontecave , Louise Ponsard , Emmanuel Nicolas , Ngoc Huan Tran , Sarah Lamaison ChemSusChem, 2021, 14 (10), pp.2198-2204. ⟨10.1002/cssc.202100459⟩ Article dans une revue cea-03166022v1
	A copper(I)‐catalyzed sulfonylative Hiyama cross‐coupling Aurélien Adenot , Lucile Anthore-Dalion , Emmanuel Nicolas , Jean-Claude Berthet , Pierre Thuéry Chemistry - A European Journal, 2021, 27 (72), pp.18047-18053. ⟨10.1002/chem.202103371⟩ Article dans une revue cea-03547768v1
	Additive-free formic acid dehydrogenation catalyzed by a cobalt complex Lentz Nicolas , Alicia Aloisi , Pierre Thuéry , Emmanuel Nicolas , Thibault Cantat Organometallics, 2021, 40 (5), pp.565-569. ⟨10.1021/acs.organomet.0c00777⟩ Article dans une revue cea-02933763v2
	Copper–Ligand Cooperativity in H 2 Activation Enables the Synthesis of Copper Hydride Complexes Alicia Aloisi , Étienne Crochet , Emmanuel Nicolas , Jean-Claude Berthet , Camille Lescot Organometallics, 2021, 40 (13), pp.2064-2069. ⟨10.1021/acs.organomet.1c00212⟩ Article dans une revue hal-03432183v1
	Catalytic challenges and strategies for the carbonylation of $\sigma$-bonds Tawfiq Nasr Allah , Louise Ponsard , Emmanuel Nicolas , Thibault Cantat Green Chemistry, 2021, 23, pp.723-739. ⟨10.1039/d0gc02343d⟩ Article dans une revue cea-03096007v1
	Photocatalytic deoxygenation of N–O bonds with Rhenium complexes: from the reduction of nitrous oxide to pyridine N-oxides Marianne Kjellberg , Alexia Ohleier , Pierre Thuéry , Emmanuel Nicolas , Lucile Anthore-Dalion Chemical Science, 2021, 2021 (12), pp.10266-10272. ⟨10.1039/D1SC01974K⟩ Article dans une revue cea-03277737v2
	Unlocking the catalytic hydrogenolysis of chlorosilanes into hydrosilanes with superbases Gabriel Durin , Jean-Claude Berthet , Emmanuel Nicolas , Thibault Cantat ACS Catalysis, 2021, 11 (17), pp.10855-10861. ⟨10.1021/acscatal.1c01515⟩ Article dans une revue cea-03547774v2
	[(dcpp)Ni( η 2 -Arene)] Precursors: Synthesis, Reactivity, and Catalytic Application to the Suzuki–Miyaura Reaction Florian D’accriscio , Alexia Ohleier , Emmanuel Nicolas , Matthieu Demange , Olivier Thillaye Du Boullay Organometallics, 2020, 39 (10), pp.1688-1699. ⟨10.1021/acs.organomet.9b00834⟩ Article dans une revue hal-02911077v1
	Carbonylation of C-N Bonds in Tertiary Amines Catalyzed by Low Valent Iron Catalysts Tawfiq Nasr Allah , Solène Savourey , Jean-Claude Berthet , Emmanuel Nicolas , Thibault Cantat Angewandte Chemie International Edition, 2019, 58, pp.10884-10887. ⟨10.1002/anie.201903740⟩ Article dans une revue cea-02145076v1
	[4+2] versus [2+2] Homodimerization in P(V) Derivatives of 2,4-Disubstituted Phospholes Guillaume Bousrez , Emmanuel Nicolas , Agathe Martinez , Sylviane Chevreux , Florian Jaroschik Heteroatom Chemistry, 2019, 2019, pp.2596405. ⟨10.1155/2019/2596405⟩ Article dans une revue cea-02092318v1
	Catalytic Metal-Free Deoxygenation of Nitrous Oxide with Disilanes Lucile Anthore-Dalion , Emmanuel Nicolas , Thibault Cantat ACS Catalysis, 2019, 9, pp.11563-11567. ⟨10.1021/acscatal.9b04434⟩ Article dans une revue cea-02372787v1
	Synthesis, Characterization and Reactivity of Formal 20 Electron Zirconocene-Pentafulvene Complexes Florian Jaroschik , Manfred Penkhues , Bernard Bahlmann , Emmanuel Nicolas , Malte Fischer Organometallics, 2017, 36 (10), pp.2004-2013. ⟨10.1021/acs.organomet.7b00213⟩ Article dans une revue hal-01996040v1
	A Significant but Constrained Geometry Pt→Al Interaction: Fixation of CO 2 and CS 2 , Activation of H 2 and PhCONH 2 Marc Devillard , Richard Declercq , Emmanuel Nicolas , Andreas Ehlers , Jana Backs Journal of the American Chemical Society, 2016, 138 (14), pp.4917-4926. ⟨10.1021/jacs.6b01320⟩ Article dans une revue hal-03539232v1
	“(Diphosphine)Nickel”-Catalyzed Negishi Cross-Coupling: An Experimental and Theoretical Study Emmanuel Nicolas , Alexia Ohleier , Florian d'Accriscio , Anne-Frédérique Pécharman , Matthieu Demange Chemistry - A European Journal, 2015, 21 (21), pp.7690-7694 Article dans une revue hal-02001069v1
	Dative Au→Al Interactions: Crystallographic Characterization and Computational Analysis Marc Devillard , Emmanuel Nicolas , Andreas Ehlers , Jana Backs , Sonia Mallet-Ladeira Chemistry - A European Journal, 2015, 21 (1), pp.74-79. ⟨10.1002/chem.201405610⟩ Article dans une revue hal-03539254v1
	Ti-mediated intramolecular cyclopropanation of N-alkenyl thioamides: scope and mechanistic study Fabien Hermant , Emmanuel Nicolas , Yvan Six Tetrahedron, 2014, 70 (25), pp.3924-3930. ⟨10.1016/j.tet.2014.04.006⟩ Article dans une revue hal-01015278v1
	Novel zwitterionic complexes arising from the coordination of an ambiphilic phosphorus–aluminum ligand to gold Marc Devillard , Emmanuel Nicolas , Christian Appelt , Jana Backs , Sonia Mallet-Ladeira Chemical Communications, 2014, 50 (94), pp.14805-14808. ⟨10.1039/C4CC06992G⟩ Article dans une revue hal-03539248v1
	Reductive Alkylation of Thioamides with Grignard Reagents in the Presence of Ti(OiPr)4: Insight and Extension Fabien Hermant , Ewelina Urbańska , Sarah Seizilles de Mazancourt , Thomas Maubert , Emmanuel Nicolas Organometallics, 2014, 33 (20), pp.5643-5653. ⟨10.1021/om500603v⟩ Article dans une revue hal-01098819v1
	Reactivity differences between 2,4- and 2,5-disubstituted zirconacyclopentadienes: a highly selective and general approach to 2,4-disubstituted phospholes. Guillaume Bousrez , Florian Jaroschik , Agathe Martinez , Dominique Harakat , Emmanuel Nicolas Dalton Transactions, 2013, epub ahead of print. ⟨10.1039/c3dt51158h⟩ Article dans une revue hal-00839784v1
	CO Activation by (Diphosphane)platinum(0): Carbonate and Acetone Formation - Experimental and Mechanistic Study Nicolas Mézailles , Grégory Nocton , Emmanuel Nicolas European Journal of Inorganic Chemistry, 2013, 22-23, pp.4000-4007. ⟨10.1002/ejic.201300182⟩ Article dans une revue hal-00906325v1
	Room temperature reversible C-H activation mediated by a Pt(0) center, and stoichiometric biphenyl formation via solvent activation. Emmanuel Nicolas , X. F Le Goff , Stéphane Bouchonnet , Nicolas Mézailles Chemical Communications, 2012, 48 (67), pp.8350-2. ⟨10.1039/c2cc33847e⟩ Article dans une revue hal-00823000v1

	Photocatalytic deoxygenation of nitrogen oxide compounds Marianne Kjellberg , Emmanuel Nicolas , Lucile Anthore-Dalion , Alexia Ohleier , Annamaria Quaranta GECOM-CONCOORD 2022, May 2022, Sévrier, France Communication dans un congrès cea-03662299v1
	Catalytic carbonylation of acrylic acid to succinic anhydride: en route to the synthesis of a bio-based monomer Marie-Hélène Pietraru , Louise Ponsard , Nicolas Lentz , Emmanuel Nicolas , Thibault Cantat Symposium International sur la chimie durable (ISGC 2022), May 2022, La Rochelle, France Communication dans un congrès cea-03675178v1
	Catalytic carbonylation of acrylic acid to succinic anhydride: en route to the synthesis of a bio-based monomer Marie-Hélène Pietraru , Louise Ponsard , Nicolas Lentz , Emmanuel Nicolas , Thibault Cantat GreenCAt 2022 - 4th International Green Catalysis Symposium, Apr 2022, Rennes, France Communication dans un congrès cea-03654519v1
	Photocatalytic deoxygenation of nitrogen oxide compounds Marianne Kjellberg , Annamaria Quaranta , Emmanuel Nicolas , Lucile Anthore-Dalion , Alexia Ohleier Symposium International sur la chimie durable (ISGC 2022), May 2022, La Rochelle, France Communication dans un congrès cea-03675180v1

	Catalytic carbonylation of acrylic acid to succinic anhydride: en route to the synthesis of a bio-based monomer Marie-Hélène Pietraru , Louise Ponsard , Nicolas Lentz , Emmanuel Nicolas , Thibault Cantat Catalysis at the Energy - Chemistry Nexus 2022 Winter School, Mar 2022, Aussois, France. Poster de conférence cea-03654542v1
	Understanding the catalytic carbonylation of epoxides for the valorization of carbon monoxide Louise Ponsard , Emmanuel Nicolas , Thibault Cantat GECOM-CONCOORD 2019, May 2019, Erquy, France Poster de conférence cea-02339556v1
	Catalytic hydrogenolysis of silyl triflates to hydrosilanes using iridium pincer complexes Gabriel Durin , Jean-Claude Berthet , Emmanuel Nicolas , Pierre Thuéry , Thibault Cantat 12th International Scholl on Organometallic Chemistry “Marcial Moreno Mañas”, Jun 2019, Castellon, Spain Poster de conférence cea-02329217v1
	Formic acid disproportionation to methanol and CO$_2$ reduction Emmanuel Nicolas , Alicia Aloisi , Solene Savourey , Thibault Cantat GYSS@one-North, Jan 2018, Singapore, Singapore Poster de conférence cea-02339603v1
	To Bend or Not to Bend: Is CO2 Bending Required to Promote its Reduction? Emmanuel Nicolas , Niklas von Wolff , Thibault Cantat EuCOMC 2017, Jul 2017, Amsterdam, Netherlands Poster de conférence cea-02346348v1

	Metal-free catalytic hydrogenolysis of silyl triflates and halides into hydrosilanes Gabriel Durin , Albane Fontaine , Jean-Claude Berthet , Emmanuel Nicolas , Pierre Thuéry 2022 Pré-publication, Document de travail cea-03540549v1
	A copper(I)-catalyzed sulfonylative Hiyama cross-coupling Aurélien Adenot , Emmanuel Nicolas , Lucile Anthore-Dalion , Jean-Claude Berthet , Pierre Thuéry 2021 Pré-publication, Document de travail cea-03284987v1
	The Role of (tBuPOCOP)Ir(I) and iridium(III) Pincer Complexes in the Catalytic Hydrogenolysis of Silyl Triflates into Hydrosilanes Gabriel Durin , Jean-Claude Berthet , Emmanuel Nicolas , Pierre Thuéry , Thibault Cantat 2021 Pré-publication, Document de travail cea-03320572v1
	Copper-Ligand Cooperativity in H$_2$ Activation Enables the Synthesis of Copper Hydride Complexes Alicia Aloisi , Étienne Crochet , Emmanuel Nicolas , Jean-Claude Berthet , Camille Lescot 2021 Pré-publication, Document de travail cea-03132894v1

	Complexes de métaux réduits : Activation de liaisons C H et de petites molécules Emmanuel Nicolas Chimie inorganique. Ecole Polytechnique, 2013. Français. ⟨NNT : ⟩ Thèse tel-01348272v1

Emmanuel Nicolas

Publications

Fluorophosphoniums as Lewis acids in organometallic catalysis: application in cobalt-catalyzed carbonylation of β-lactones

Metal‐Free Catalytic Hydrogenolysis of Chlorosilanes into Hydrosilanes with “Inverse” Frustrated Lewis Pairs

Evaluation of acetophenone as a novel alcohol-cycloalkane bifunctional liquid organic hydrogen carrier (LOHC)

Catalytic Carbonylation of Acrylic Acid to Succinic Anhydride

Vers la synthèse de réducteurs renouvelables à base de silicium

Metal‐Free Catalytic Hydrogenolysis of Silyl Triflates and Halides into Hydrosilanes

The Role of ($^{tBu}$POCOP)Ir(I) and iridium(III) pincer complexes in the catalytic hydrogenolysis of silyl triflates into hydrosilanes

Coupling electrocatalytic CO2 reduction with thermocatalysis enables the formation of a lactone monomer

A copper(I)‐catalyzed sulfonylative Hiyama cross‐coupling

Additive-free formic acid dehydrogenation catalyzed by a cobalt complex

Copper–Ligand Cooperativity in H 2 Activation Enables the Synthesis of Copper Hydride Complexes

Catalytic challenges and strategies for the carbonylation of $\sigma$-bonds

Photocatalytic deoxygenation of N–O bonds with Rhenium complexes: from the reduction of nitrous oxide to pyridine N-oxides

Unlocking the catalytic hydrogenolysis of chlorosilanes into hydrosilanes with superbases

[(dcpp)Ni( η 2 -Arene)] Precursors: Synthesis, Reactivity, and Catalytic Application to the Suzuki–Miyaura Reaction

Carbonylation of C-N Bonds in Tertiary Amines Catalyzed by Low Valent Iron Catalysts

[​4+2] versus [​2+2] Homodimerization in P(V) Derivatives of 2,4-Disubstituted Phospholes

Catalytic Metal-Free Deoxygenation of Nitrous Oxide with Disilanes

Synthesis, Characterization and Reactivity of Formal 20 Electron Zirconocene-Pentafulvene Complexes

A Significant but Constrained Geometry Pt→Al Interaction: Fixation of CO 2 and CS 2 , Activation of H 2 and PhCONH 2

“(Diphosphine)Nickel”-Catalyzed Negishi Cross-Coupling: An Experimental and Theoretical Study

Dative Au→Al Interactions: Crystallographic Characterization and Computational Analysis

Ti-mediated intramolecular cyclopropanation of N-alkenyl thioamides: scope and mechanistic study

Novel zwitterionic complexes arising from the coordination of an ambiphilic phosphorus–aluminum ligand to gold

Reductive Alkylation of Thioamides with Grignard Reagents in the Presence of Ti(OiPr)4: Insight and Extension

Reactivity differences between 2,4- and 2,5-disubstituted zirconacyclopentadienes: a highly selective and general approach to 2,4-disubstituted phospholes.

CO Activation by (Diphosphane)platinum(0): Carbonate and Acetone Formation - Experimental and Mechanistic Study

Room temperature reversible C-H activation mediated by a Pt(0) center, and stoichiometric biphenyl formation via solvent activation.

Photocatalytic deoxygenation of nitrogen oxide compounds

Catalytic carbonylation of acrylic acid to succinic anhydride: en route to the synthesis of a bio-based monomer

Catalytic carbonylation of acrylic acid to succinic anhydride: en route to the synthesis of a bio-based monomer

Photocatalytic deoxygenation of nitrogen oxide compounds

Catalytic carbonylation of acrylic acid to succinic anhydride: en route to the synthesis of a bio-based monomer

Understanding the catalytic carbonylation of epoxides for the valorization of carbon monoxide

Catalytic hydrogenolysis of silyl triflates to hydrosilanes using iridium pincer complexes

Formic acid disproportionation to methanol and CO$_2$ reduction

To Bend or Not to Bend: Is CO2 Bending Required to Promote its Reduction?

Metal-free catalytic hydrogenolysis of silyl triflates and halides into hydrosilanes

A copper(I)-catalyzed sulfonylative Hiyama cross-coupling

The Role of (tBuPOCOP)Ir(I) and iridium(III) Pincer Complexes in the Catalytic Hydrogenolysis of Silyl Triflates into Hydrosilanes

Copper-Ligand Cooperativity in H$_2$ Activation Enables the Synthesis of Copper Hydride Complexes

Complexes de métaux réduits : Activation de liaisons C H et de petites molécules

[4+2] versus [2+2] Homodimerization in P(V) Derivatives of 2,4-Disubstituted Phospholes