CV Dominique Cahard

Melissa Hardy, Hélène Chachignon, Dominique Cahard. Advances in Asymmetric Di‐and Trifluoromethylthiolation, and Di‐ and Trifluoromethoxylation Reactions. Asian Journal of Organic Chemistry, WILEY-VCH, 2019, 8 (5), pp.591-609. ⟨10.1002/ajoc.201900004⟩. ⟨hal-02321614⟩

Satoshi Gondo, Okiya Matsubara, Hélène Chachignon, Yuji Sumii, Dominique Cahard, et al.. Asymmetric Electrophilic Difluoromethylthiolation of Indanone-Based β-Keto Esters Using Difluoromethanesulfonyl Hypervalent Iodonium Ylides. Molecules, MDPI, 2019, 24 (2), pp.221. ⟨10.3390/molecules24020221⟩. ⟨hal-02321615⟩

Alexey Romanov, Dominique Cahard, Alexander Yu. Rulev. Regioselectivity Issues in the Addition of Grignard Reagents to Trifluoromethylated α-Bromoenones. European Journal of Organic Chemistry, Wiley-VCH Verlag, 2019, 2019 (11), pp.2143-2149. ⟨10.1002/ejoc.201900155⟩. ⟨hal-02321613⟩

Hélène Chachignon, Evgeniy V. Kondrashov, Dominique Cahard. Diastereoselective Electrophilic Trifluoromethylthiolation of Chiral Oxazolidinones: Access to Enantiopure α‐SCF3 Alcohols. Advanced Synthesis and Catalysis, Wiley-VCH Verlag, 2018, 360 (5), pp.965-971. ⟨10.1002/adsc.201701474⟩. ⟨hal-02024484⟩

F.-G. Zhang, J.-L. Zeng, Y.-Q. Tian, Y. Zheng, Dominique Cahard, et al.. Telescoping Reactions with Trifluorodiazoethane-Derived Aza-Wittig Reagents and Allenyl esters. Chemistry - A European Journal, Wiley-VCH Verlag, 2018, 24 (30), pp.7749-7754. ⟨10.1002/chem.201801171⟩. ⟨hal-02024538⟩

Hélène Guyon, Hélène Chachignon, Vincent Tognetti, Laurent Joubert, Dominique Cahard. Mechanistic Insights into the Decarboxylative Electrophilic Trifluoromethylthiolation of β‐Ketocarboxylic Acids. European Journal of Organic Chemistry, Wiley-VCH Verlag, 2018, Special Issue: Organofluorine Chemistry in Europe, 2018 (27-28), pp.3756-3763. ⟨10.1002/ejoc.201800305⟩. ⟨hal-02024501⟩

Hélène Guyon, Hélène Chachignon, Dominique Cahard. CF3SO2X (X = Na, Cl) as reagents for trifluoromethylation, trifluoromethylsulfenyl-, -sulfinyl- and -sulfonylation. Part 1: Use of CF3SO2Na. Beilstein Journal of Organic Chemistry, Beilstein-Institut, 2017, 13, pp.2764-2799. ⟨10.3762/bjoc.13.272⟩. ⟨hal-02046280⟩

K. Kawada, K. Okano, J. Iskra, P. Krajnc, Dominique Cahard. SelectfluorTM on a PolyHIPE Material as Regenerative and Reusable Polymer‐Supported Electrophilic Fluorinating Agent. Advanced Synthesis and Catalysis, Wiley-VCH Verlag, 2017, 359 (4), pp.584-589. ⟨10.1002/adsc.201601312⟩. ⟨hal-02046288⟩

Hélène Chachignon, Dominique Cahard. Interrupted reduction of CF3SO2Cl using tricyclohexylphosphine allows for electrophilic trifluoromethylsulfinylation. Journal of Fluorine Chemistry, Elsevier, 2017, 198, pp.82-88. ⟨10.1016/j.jfluchem.2016.11.020⟩. ⟨hal-02046268⟩

Hélène Chachignon, Hélène Guyon, Dominique Cahard. CF3SO2X (X = Na, Cl) as reagents for trifluoromethylation, trifluoromethylsulfenyl-, -sulfinyl- and -sulfonylation and chlorination. Part 2: Use of CF3SO2Cl. Beilstein Journal of Organic Chemistry, Beilstein-Institut, 2017, 13, pp.2800-2818. ⟨10.3762/bjoc.13.273⟩. ⟨hal-02046269⟩

Jacques Maddaluno, Michaël de Paolis, Xavier Franck, Dominique Cahard. New pluses in carbanion chemistry: Editorial. Comptes Rendus. Chimie, Elsevier, 2017, 20 (6), pp.593-594. ⟨10.1016/j.crci.2017.05.002⟩. ⟨hal-02024981⟩

Jun-Liang Zeng, Hélène Chachignon, Jun-An Ma, Dominique Cahard. Nucleophilic Trifluoromethylthiolation of Cyclic Sulfamidates: Access to Chiral β- and γ-SCF3 Amines and α-Amino Esters. Organic Letters, American Chemical Society, 2017, 19 (8), pp.1974-1977. ⟨10.1021/acs.orglett.7b00501⟩. ⟨hal-02046315⟩

A.E. Cotman, Dominique Cahard, B. Mohar. Stereoarrayed CF3-Substituted 1,3-Diols by Dynamic Kinetic Resolution: Ruthenium(II)-Catalyzed Asymmetric Transfer Hydrogenation. Angewandte Chemie International Edition, Wiley-VCH Verlag, 2016, 55 (17), pp.5294-5298. ⟨10.1002/anie.201600812⟩. ⟨hal-02046198⟩

Hélène Chachignon, Dominique Cahard. State-of-the-Art in Electrophilic Trifluoromethylthiolation Reagents. Chinese Journal of Chemistry, Wiley-VCH, 2016, Special Issue: Trifluoromethylation and Trifluoromethylthiolation Reactions, 34 (5), pp.445-454. ⟨10.1002/cjoc.201500890⟩. ⟨hal-02046193⟩

Hélène Chachignon, Mayaka Maeno, H. Kondo, N. Shibata, Dominique Cahard. Novel Use of CF3SO2Cl for the Metal-Free Electrophilic Trifluoromethylthiolation. Organic Letters, American Chemical Society, 2016, 18 (10), pp.2467-2470. ⟨10.1021/acs.orglett.6b01026⟩. ⟨hal-02046194⟩

C.-L. Zhu, J.-A. Ma, Dominique Cahard. Trifluorodiazoethane (CF3CHN2) in the Uncatalyzed Cyclopropanation of 3-Arylmethylenebenzofuran-2(3H)-ones. Asian Journal of Organic Chemistry, 2016, 5 (1), pp.66-69. ⟨10.1002/ajoc.201500409⟩. ⟨hal-02046247⟩

Laëtitia Bailly, Emilie Petit, Mayaka Maeno, Norio Shibata, Oliver Trapp, et al.. Enantiomerization of Allylic Trifluoromethyl Sulfoxides Studied by HPLC Analysis and DFT Calculations. Chirality, Wiley, 2016, 28 (2), pp.136-142. ⟨10.1002/chir.22552⟩. ⟨hal-01928560⟩

Heng-Ying Xiong, Dominique Cahard, Xavier Pannecoucke, Tatiana Besset. Pd-Catalyzed Directed Chlorination of Unactivated C(sp3)–H Bonds at Room Temperature. European Journal of Organic Chemistry, Wiley-VCH Verlag, 2016, 2016 (21), pp.3625-3630. ⟨10.1002/ejoc.201600600⟩. ⟨hal-01404921⟩

Emilie Villiers, Samuel Couve-Bonnaire, Dominique Cahard, Xavier Pannecoucke. The fluoroalkene motif as a surrogate of the amide bond: syntheses of AA-Y[(Z) and (E)-CF=CH]-Pro pseudodipeptides and an Enalapril analogue. Tetrahedron, Elsevier, 2015, 71 (38), pp.7054-7062. ⟨10.1016/j.tet.2015.06.093⟩. ⟨hal-01226904⟩

J.-M. Vincent, T. Brigaud, Dominique Cahard. Preface. Journal of Fluorine Chemistry, Elsevier, 2015, 171, pp.1. ⟨10.1016/j.jfluchem.2014.10.011⟩. ⟨hal-02024989⟩

Mayaka Maeno, N. Shibata, Dominique Cahard. Trifluoromethyl Sulfoxides from Allylic Alcohols and Electrophilic SCF3 Donor by [2,3]-Sigmatropic Rearrangement. Organic Letters, American Chemical Society, 2015, 17 (8), pp.1990-1993. ⟨10.1021/acs.orglett.5b00750⟩. ⟨hal-02046161⟩

Xiaoyang Dai, Dominique Cahard. Regio- and stereocontrolled nucleophilic trifluoromethylthiolation of Morita-Baylis-Hillman carbonates. SYNLETT, Georg Thieme Verlag, 2015, 26 (1), pp.40-44. ⟨10.1055/s-0034-1379162⟩. ⟨hal-02046149⟩

Heng-Ying Xiong, Tatiana Besset, Dominique Cahard, Xavier Pannecoucke. Palladium(II)-Catalyzed Directed Trifluoromethylthiolation of Unactivated C(sp3)–H Bonds. Journal of Organic Chemistry, American Chemical Society, 2015, 80 (8), pp.4204-4212. ⟨10.1021/acs.joc.5b00505⟩. ⟨hal-01149628⟩

Dominique Cahard, Sylvain Gaillard, J.L. Renaud. Asymmetric isomerization of allylic alcohols. Tetrahedron Letters, Elsevier, 2015, 56 (45), pp.6159-6169. ⟨10.1016/j.tetlet.2015.09.098⟩. ⟨hal-01848011⟩

Vincent Bizet, Tatiana Besset, Jun-An Ma, Dominique Cahard. Recent Progress in Asymmetric Fluorination and Trifluoromethylation Reactions. Current Topics in Medicinal Chemistry, Bentham Science Publishers, 2014, 14, pp.901-940. ⟨10.2174/1568026614666140202205531⟩. ⟨hal-01149612⟩

Marie-Charlotte Belhomme, Delphine Dru, Heng-Ying Xiong, Dominique Cahard, Tatiana Besset, et al.. Copper-Mediated Direct Functionalization of Unsaturated C–C Bonds with Ethyl Bromo(difluoro)acetate: A Straightforward Access to Highly Valuable Difluoromethylated Alkenes. SYNTHESIS, Georg Thieme Verlag, 2014, 46, pp.1859-1870. ⟨10.1055/s-0033-1338637⟩. ⟨hal-01149614⟩

Tatiana Besset, Dominique Cahard, Xavier Pannecoucke. Regio- and Diastereoselective Cu-Mediated Trifluoromethylation of Functionalized Alkenes. Journal of Organic Chemistry, American Chemical Society, 2014, 79, pp.413-418. ⟨10.1021/jo402385g⟩. ⟨hal-01149530⟩

Betty Hébert, Susanna Pietropaolo, Sandra Même, Béatrice Laudier, Anthony Laugeray, et al.. Rescue of fragile X syndrome phenotypes in Fmr1 KO mice by a BKCa channel opener molecule.. Orphanet Journal of Rare Diseases, BioMed Central, 2014, 9, pp.124. ⟨10.1186/s13023-014-0124-6⟩. ⟨inserm-01089760⟩

Vincent Bizet, Xavier Pannecoucke, Jean-Luc Renaud, Dominique Cahard. Synthesis of β-CF3 ketones from trifluoromethylated allylic alcohols by ruthenium catalyzed isomerization. Journal of Fluorine Chemistry, Elsevier, 2013, pp.56-61. ⟨10.1016/j.jfluchem.2013.01.004⟩. ⟨hal-01015319⟩

Chuan-Le Zhu, Xiao-Yun Fu, Ai-Jia Wei, Dominique Cahard, Jun-An Ma. P-Spiro phosphonium salts catalyzed asymmetric fluorination of 3-substituted benzofuran-2(3H)-ones. Journal of Fluorine Chemistry, Elsevier, 2013, pp.60-66. ⟨10.1016/j.jfluchem.2013.03.007⟩. ⟨hal-01015804⟩

Dominique Cahard, Vincent Bizet, Xiaoyang Dai, Sylvain Gaillard, Jean-Luc Renaud. Iron(II) complexes are suitable catalysts for the isomerization of trifluoromethylated allylic alcohols. Synthesis of trifluoromethylated dihydrochalcones. Journal of Fluorine Chemistry, Elsevier, 2013, pp.78-82. ⟨10.1016/j.jfluchem.2013.05.028⟩. ⟨hal-01015799⟩

Vincent Bizet, Dominique Cahard, Sylvain Gaillard, Jean-Luc Renaud. Isomérisation rédox : une réaction économe en atome à fort potentiel d'innovation. Techniques de l'Ingenieur, Techniques de l'ingénieur, 2013, pp.LN159. ⟨hal-01015807⟩

Vincent Bizet, Xavier Pannecoucke, Jean-Luc Renaud, Dominique Cahard. Ruthenium-Catalyzed One-Pot Tandem Isomerization-Transfer Hydrogenation Reactions of γ-Trifluoromethylated Allylic Alcohols and β-Trifluoromethylated Enones [Erratum to document cited in CA159:515982]. Advanced Synthesis and Catalysis, Wiley-VCH Verlag, 2013, pp.2113. ⟨10.1002/adsc.201381141⟩. ⟨hal-01015313⟩

Chuan-Le Zhu, Mayaka Maeno, Faguang Zang, Taiki Shigehiro, Takumi Kagawa, et al.. Chiral N-Fluorodibenzenesulfonimide Analogues for Enantioselective Electrophilic Fluorination and Oxidative Fluorination. European Journal of Organic Chemistry, Wiley-VCH Verlag, 2013, pp.6501-6505. ⟨10.1002/ejoc.201300956⟩. ⟨hal-01015793⟩

Camille Pierry, Samuel Couve-Bonnaire, Laure Guilhaudis, Cindy Neveu, Amélie Marotte, et al.. Fluorinated pseudopeptide analogues of the neuropeptide 26RFa: synthesis, biological, and structural studies.. ChemBioChem, Wiley-VCH Verlag, 2013, 14 (13), pp.1620-33. ⟨10.1002/cbic.201300325⟩. ⟨hal-01939216⟩

Zhuo Chai, J.-P. Bouillon, Dominique Cahard. Chiral Brønsted acid-catalyzed diastereo- and enantioselective synthesis of CF3-substituted aziridines.. Chemical Communications, Royal Society of Chemistry, 2012, 48 (76), pp.9471-9473. ⟨10.1039/c2cc35246j⟩. ⟨hal-00996595⟩

Vincent Bizet, Xavier Pannecoucke, Jean-Luc Renaud, Dominique Cahard. Ruthenium-catalyzed redox isomerization of trifluoromethylated allylic alcohols: mechanistic evidence for an enantiospecific pathway.. Angewandte Chemie (English Edition), John Wiley & Sons, 2012, 51 (26), pp.6467-6470. ⟨10.1002/anie.201200827⟩. ⟨hal-00996590⟩

Norio Shibata, Kazunobu Fukushi, Tatsuya Furukawa, Satoru Suzuki, Etsuko Tokunaga, et al.. Decarboxylative allylation of trifluoroethyl sulfones and approach to difluoromethyl compounds.. Organic Letters, American Chemical Society, 2012, 14 (20), pp.5366-5369. ⟨10.1021/ol302589w⟩. ⟨hal-00996604⟩

Tatiana Besset, Cédric Schneider, Dominique Cahard. Tamed arene and heteroarene trifluoromethylation.. Angewandte Chemie (English Edition), John Wiley & Sons, 2012, 51 (21), pp.5048-5050. ⟨10.1002/anie.201201012⟩. ⟨hal-00996588⟩

Camille Pierry, Dominique Cahard, Samuel Couve-Bonnaire, Xavier Pannecoucke. Synthesis of fluorinated pseudopeptides: metal mediated reversal of stereochemistry in diastereoselective addition of organometallic reagents to N-(tert-butanesulfinyl)-α-fluoroenimines.. Organic and Biomolecular Chemistry, Royal Society of Chemistry, 2011, 9 (7), pp.2378-2386. ⟨10.1039/c0ob00773k⟩. ⟨hal-00991652⟩

Chuan-Le Zhu, Fa-Guang Zhang, Wei Meng, Jing Nie, Dominique Cahard, et al.. Enantioselective base-free electrophilic amination of benzofuran-2(3H)-ones: catalysis by binol-derived P-spiro quaternary phosphonium salts.. Angewandte Chemie (English Edition), John Wiley & Sons, 2011, 50 (26), pp.5869-72. ⟨10.1002/anie.201100283⟩. ⟨hal-00991654⟩

Václav Matoušek, Antonio Togni, Vincent Bizet, Dominique Cahard. Synthesis of α-CF3-substituted carbonyl compounds with relative and absolute stereocontrol using electrophilic CF3-transfer reagents.. Organic Letters, American Chemical Society, 2011, 13 (21), pp.5762-5765. ⟨10.1021/ol2023328⟩. ⟨hal-00991658⟩

Jing Nie, Hong-Chao Guo, Dominique Cahard, Jun-An Ma. Asymmetric construction of stereogenic carbon centers featuring a trifluoromethyl group from prochiral trifluoromethylated substrates.. Chemical Reviews, American Chemical Society, 2011, 111 (2), pp.455-529. ⟨10.1021/cr100166a⟩. ⟨hal-00991650⟩

Vitaliy Petrik, G.-V. Roeschenthaler, Dominique Cahard. Diastereoselective synthesis of trans-trifluoromethyl-β-lactams and α-alkyl-β-trifluoromethyl-β-amino esters. Tetrahedron, Elsevier, 2011, pp.3254-3259. ⟨10.1016/j.tet.2011.03.001⟩. ⟨hal-01017713⟩

Norio Shibata, Satoru Suzuki, Tatsuya Furukawa, Hiroyuki Kawai, Etsuko Tokunaga, et al.. Construction of Trifluoromethyl-Bearing Quaternary Carbon Centers by Intramolecular Decarboxylative Allylation of α-Trifluoromethyl β-Keto Esters. Advanced Synthesis and Catalysis, Wiley-VCH Verlag, 2011, pp.2037-2041. ⟨10.1002/adsc.201100359⟩. ⟨hal-01017733⟩

Norio Shibata, Andrej Matsnev, Dominique Cahard. Shelf-stable electrophilic trifluoromethylating reagents: A brief historical perspective.. Beilstein Journal of Organic Chemistry, Beilstein-Institut, 2010, 6, epub ahead of print. ⟨10.3762/bjoc.6.65⟩. ⟨hal-00991935⟩

Dominique Cahard, Xiuhua Xu, Samuel Couve-Bonnaire, Xavier Pannecoucke. Fluorine & chirality: how to create a nonracemic stereogenic carbon-fluorine centre?. Chemical Society Reviews, Royal Society of Chemistry, 2010, 39 (2), pp.558-568. ⟨10.1039/b909566g⟩. ⟨hal-00991924⟩

Camille Pierry, Ludivine Zoute, Philippe Jubault, Emmanuel Pfund, Thierry Lequeux, et al.. Diastereocontrolled addition of organometallic reagents to S-chiral N-(tert-butanesulfinyl)-α-fluoroenimines. Tetrahedron Letters, Elsevier, 2009, 50 (3), pp.264-266. ⟨10.1016/j.tetlet.2008.10.140⟩. ⟨hal-02384442⟩

Samuel Couve-Bonnaire, Dominique Cahard, Xavier Pannecoucke. Chiral dipeptide mimics possessing a fluoroolefin moiety: a relevant tool for conformational and medicinal studies. Organic and Biomolecular Chemistry, Royal Society of Chemistry, 2007, 5 (8), pp.1151. ⟨10.1039/b701559c⟩. ⟨hal-02384465⟩

Barbara Mohar, Damjan Sterk, Laurent Ferron, Dominique Cahard. Enantioselective and diastereoselective synthesis of fluorinated dipeptides by late electrophilic fluorination. Tetrahedron Letters, Elsevier, 2005, 46 (30), pp.5029-5031. ⟨10.1016/j.tetlet.2005.05.074⟩. ⟨hal-01935543⟩

Christine Baudequin, Jean-François Loubassou, Jean-Christophe Plaquevent, Dominique Cahard. Enantioselective electrophilic fluorination: a study of the fluorine-transfer from achiral N–F reagents to cinchona alkaloids. Journal of Fluorine Chemistry, Elsevier, 2003, 122 (2), pp.189-193. ⟨10.1016/S0022-1139(03)00085-X⟩. ⟨hal-02385385⟩

Christine Baudequin, Jérôme Baudoux, Jocelyne Levillain, Dominique Cahard, Annie-Claude Gaumont, et al.. Ionic liquids and chirality: opportunities and challenges. Tetrahedron: Asymmetry, Elsevier, 2003, 14 (20), pp.3081-3093. ⟨10.1016/S0957-4166(03)00596-2⟩. ⟨hal-02385379⟩

Christine Baudequin, Jean-Christophe Plaquevent, Christophe Audouard, Dominique Cahard. Enantioselective electrophilic fluorination in ionic liquids. Green Chemistry, Royal Society of Chemistry, 2002, 4 (6), pp.584-586. ⟨10.1039/B208817G⟩. ⟨hal-02385390⟩