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Carbenes and phosphonium ylides: a fruitful association in coordination chemistry
Dmitry A. Valyaev
,
Yves Canac
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Experimental and Theoretical Insights into the Electronic Properties of Anionic N-Heterocyclic Dicarbenes through the Rational Synthesis of Their Transition Metal Complexes
Alina A Grineva
,
Oleg A Filippov
,
Yves Canac
,
Jean-Baptiste Sortais
,
Sergei E Nefedov
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et al.
Article dans une revue
hal-03200528v1
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Manganese-mediated synthesis of an NHC core non-symmetric pincer ligand and evaluation of its coordination properties
Dmitry A. Valyaev
,
Jérémy Willot
,
Loïc P. Mangin
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Davit Zargarian
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Noël Lugan
Article dans une revue
hal-01938382v1
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Half-Sandwich Manganese Complexes Bearing Cp Tethered N-Heterocyclic Carbene Ligands: Synthesis and Mechanistic Insights into the Catalytic Ketone Hydrosilylation
Dmitry A. Valyaev
,
Duo Wei
,
Saravanakumar Elangovan
,
Matthieu Cavailles
,
Vincent Dorcet
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et al.
Article dans une revue
hal-01475468v1
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Dual reactivity pattern of Mn(I) carbyne complexes Cp(CO)2Mn+≡C–R (R = Ar, Alk) vs. dppm: Subtle balance between double intramolecular nucleophilic addition and nucleophilic addition followed by migratory CO insertion
Dmitry A. Valyaev
,
Kamil I. Utegenov
,
Vassily V. Krivykh
,
Jérémy Willot
,
Nikolai A. Ustynyuk
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et al.
Article dans une revue
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Generation of α-Phosphinocarbene Complexes and Their Evolution: New Light on Relevant Isomerization Pathways
Dmitry A. Valyaev
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Noël Lugan
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Guy Lavigne
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Nikolai Ustynyuk
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Palladium( ii ) pincer complexes of a C , C , C -NHC, diphosphonium bis(ylide) ligand
Rachid Taakili
,
Christine Lepetit
,
Carine Guyard-Duhayon
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Dmitry A. Valyaev
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Noël Lugan
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et al.
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NHC Core Phosphonium Ylide-based Palladium(II) Pincer Complexes: The Second Ylide Extremity Makes the Difference
Rachid Taakili
,
Cécile Barthes
,
Amel Goëffon
,
Christine Lepetit
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Carine Guyard-Duhayon
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et al.
Article dans une revue
hal-02612432v1
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Umpolung of methylenephosphonium ions in their manganese half-sandwich complexes and application to the synthesis of chiral phosphorus-containing ligand scaffolds
Dmitry A. Valyaev
,
Oleg A. Filippov
,
Noël Lugan
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Guy Lavigne
,
Nikolai A. Ustynyuk
Article dans une revue
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Bis[diphenylphosphino]methane and its bridge-substituted analogues as chemically non-innocent ligands for H 2 activation
Nikolay Kireev
,
Oleg Filippov
,
Ekaterina Gulyaeva
,
Elena V Shubina
,
Laure Vendier
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et al.
Article dans une revue
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Binuclear Cu(I) and Mn(0) Complexes with a Tridentate Pyridine-NHC-Phosphane Ligand in a µ-κ 2 Ĉ,N -M;κ 1 P -M Coordination Mode
Jérémy Willot
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Noël Lugan
,
Dmitry A. Valyaev
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hal-02361486v1
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The Dichotomy of Mn–H Bond Cleavage and Kinetic Hydricity of Tricarbonyl Manganese Hydride Complexes
Elena S Osipova
,
Sergey A Kovalenko
,
Ekaterina S Gulyaeva
,
Nikolay V Kireev
,
Alexander A Pavlov
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et al.
Article dans une revue
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Characterisation by X-ray diffraction of bidentate and tridentate PCP and PCN NHC core pincer-type Mn(I) complexes
Carine Duhayon
,
Ruqaya Buhaibeh
,
Dmitry A. Valyaev
,
Jean-Baptiste Sortais
,
Yves Canac
Article dans une revue
hal-04288540v1
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Half-sandwich manganese complexes Cp(CO) 2 Mn(NHC) as redox-active organometallic fragments
Rémy Brousses
,
Vincent Maurel
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Jean-Marie Mouesca
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Vincent César
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Noël Lugan
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et al.
Article dans une revue
hal-03403199v1
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Organometallic Manganese Compounds in Organic Synthesis
Alina A Grineva
,
Noël Lugan
,
Dmitry A. Valyaev
Jean-Baptiste Sortais. Manganese Catalysis in Organic Synthesis, Wiley-VCH, pp.1-37, 2021, 978-3-527-34730-8. ⟨10.1002/9783527826131.ch1⟩
Chapitre d'ouvrage
hal-03376634v1
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Unveiling the redox-active character of imidazolin-2-thiones derived from amino-substituted N-heterocyclic carbenes
Mirko Ruamps
,
S. Bastin
,
Lionel Rechignat
,
Alix Sournia-Saquet
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Dmitry A. Valyaev
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et al.
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hal-01948412v1
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Post-coordination backbone functionalization of an imidazol-2-ylidene and its application to synthesize heteropolymetallic complexes incorporating the ambidentate IMes(CO2-) ligand
Dmitry A. Valyaev
,
Marina A. Uvarova
,
Alina A Grineva
,
Vincent César
,
Sergei N. Nefedov
,
et al.
Article dans une revue
hal-01925254v1
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Conformation of half-sandwich Mn(I) O-alkyl and O-aryl Fischer carbene complexes: a joined experimental-theoretical study
N. Lugan
,
I. Fernández
,
Dmitry A. Valyaev
,
R. Brousses
,
M. Sierra
,
et al.
Acta Crystallographica Section A : Foundations of Crystallography [1968-2013], 2011, 67 (a1), pp.C452-C452. ⟨10.1107/S0108767311088611⟩
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Direct Access to IMes F and IMes F 2 by Electrophilic Fluorination of Abnormal N-Heterocyclic Carbenes
Alina A Grineva
,
Oleg Filippov
,
Sergei Nefedov
,
Noël Lugan
,
Vincent César
,
et al.
Article dans une revue
hal-02333068v1
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Two active species from a single metal halide precursor: a case study of highly productive Mn-catalyzed dehydrogenation of amine-boranes via intermolecular bimetallic cooperation
Ekaterina S Gulyaeva
,
Elena S Osipova
,
Sergey A Kovalenko
,
Oleg A Filippov
,
Natalia V Belkova
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et al.
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hal-04428086v1
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Intermolecular Hydrogen Bonding between Neutral Transition Metal Hydrides (η 5 -C 5 H 5 )M(CO) 3 H (M = Mo, W) and Bases
Natalia Belkova
,
Evgenii Gutsul
,
Oleg Filippov
,
Vladislava Levina
,
Dmitry A. Valyaev
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et al.
Article dans une revue
istex
hal-03739923v1
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Phosphine-NHC-Phosphonium Ylide Pincer Ligand: Complexation with Pd(II) and Unconventional P-Coordination of the Ylide Moiety
Mohammad Ameskal
,
Rachid Taakili
,
Ekaterina S Gulyaeva
,
Carine Duhayon
,
Jérémy Willot
,
et al.
Article dans une revue
hal-04284085v1
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Redox induced reactions of transition metal vinylidene and related complexes
Dmitry A. Valyaev
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Oleg Semeikin
,
Nikolai Ustynyuk
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hal-03739927v1
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Hydrosilylation of Aldehydes and Ketones Catalyzed by Half-Sandwich Manganese(I) N-Heterocyclic Carbene Complexes
Jianxia Zheng
,
Saravanakumar Elangovan
,
Dmitry A. Valyaev
,
Rémy Brousses
,
Vincent César
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et al.
Article dans une revue
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hal-01114930v1
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Cationic PCP and PCN NHC Core Pincer-Type Mn(I) Complexes: From Synthesis to Catalysis
Ruqaya Buhaibeh
,
Carine Guyard-Duhayon
,
Dmitry A. Valyaev
,
Jean-Baptiste Sortais
,
Yves Canac
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hal-03128901v1
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Hydrogenation of Carbonyl Derivatives Catalysed by Manganese Complexes Bearing Bidentate Pyridinyl-Phosphine Ligands
Duo Wei
,
Antoine Bruneau-Voisine
,
Teo Chauvin
,
Vincent Dorcet
,
Thierry Roisnel
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et al.
Article dans une revue
hal-01737372v1
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Grafting a homogeneous transition metal catalyst onto a silicon AFM probe: a promising strategy for chemically constructive nanolithography
Dmitry A. Valyaev
,
Sylvain Clair
,
Lionel Patrone
,
Mathieu Abel
,
Louis Porte
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et al.
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hal-00861617v1
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Hydrogenation of carboxylic esters catalyzed by manganese catalysts supported by bidentate NHC-phosphine ligands
Karim Azouzi
,
Romane Pointis
,
Ruqaya Buhaibeh
,
Pablo Hermosilla Fernández
,
Lucie Pedussaut
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et al.
Article dans une revue
hal-04432103v1
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Catalytic Scanning Probe Nanolithography (cSPL): Control of the AFM Parameters in Order to Achieve Sub-100-nm Spatially Resolved Epoxidation of Alkenes Grafted onto a Surface
Vincent Mesquita
,
Julien Botton
,
Dmitry A. Valyaev
,
Cyril François
,
Lionel Patrone
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et al.
Article dans une revue
hal-01415128v1
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Protonation of Zwitterionic Manganese and Rhenium Phosphoniostyryl Complexes (η 5 ‐C 5 H 5 )(CO) 2 M – –C( + PR 3 )=C(H)Ph: Experimental and DFT Study
Vasily Krivykh
,
Dmitry A. Valyaev
,
Kamil Utegenov
,
Andrei Mazhuga
,
Elena Taits
,
et al.
Article dans une revue
hal-03739903v1
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