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Clément CAMP (CNRS researcher)


 

Clément Camp is currently a CNRS researcher in the Laboratoire de Chimie, Catalyse, Polymères et Procédés (C2P2 – UMR 5265), in Lyon (France). He earned the Agrégation of Science Physiques in 2009 and graduated in 2010 from the École Normale Supérieure de Lyon (France). He received his Ph.D. degree in 2013 from the University of Grenoble (France) for his work on the coordination chemistry and reactivity of low-valent f-element compounds, performed under the supervision of Dr. Marinella Mazzanti. He then joined Prof. John Arnold’s group at the University of California, Berkeley (USA) for postdoctoral training where he studied the activation of small molecules by transition metal complexes. His current research interests deal with surface organometallic chemistry and cooperative effects in catalysis. Clément has authored 38 scientific papers, tackling problems in inorganic and organometallic chemistry with elements from across the periodic table.

 


Journal articles38 documents

  • M. Al Kharboutly, G. Veryasov, P. Gaval, A. Verchere, C. Camp, et al.. Mo(VI) dithiocarbamate with no pre-existing Mo–S–Mo core as an active lubricant additive. Tribology International, Elsevier, 2021, 154, pp.106690. ⟨10.1016/j.triboint.2020.106690⟩. ⟨hal-02968749⟩
  • Léon Escomel, Iker del Rosal, Laurent Maron, Erwann Jeanneau, Laurent Veyre, et al.. Strongly Polarized Iridium δ− –Aluminum δ+ Pairs: Unconventional Reactivity Patterns Including CO 2 Cooperative Reductive Cleavage. Journal of the American Chemical Society, American Chemical Society, 2021, 143 (12), pp.4844-4856. ⟨10.1021/jacs.1c01725⟩. ⟨hal-03357324⟩
  • Julien Petit, Paul-Alexis Pavard, Clément Camp. Unusually large "yaw" angle upon coordination of a new bulky unsymmetrical 3-hydroxyadamantyl-functionalized N- heterocyclic carbene ligand to rhodium(I). Mendeleev Communications, Elsevier, 2021, ⟨10.1016/j.mencom.2021.01.015⟩. ⟨hal-02996511⟩
  • Sébastien Lassalle, Ribal Jabbour, Iker Del rosal, Laurent Maron, Emiliano Fonda, et al.. Stepwise Construction of Silica-supported Tantalum/Iridium Heteropolymetallic Catalysts Using Surface Organometallic Chemistry. Journal of Catalysis, Elsevier, 2020, ⟨10.1016/j.jcat.2020.10.016⟩. ⟨hal-02985281⟩
  • Martin Jakoobi, Vincent Dardun, Laurent Veyre, Valérie Meille, Clément Camp, et al.. Developing a Highly Active Catalytic System Based on Cobalt Nanoparticles for Terminal and Internal Alkene Hydrosilylation. Journal of Organic Chemistry, American Chemical Society, 2020, 85 (18), pp.11732-11740. ⟨10.1021/acs.joc.0c01439⟩. ⟨hal-02998618⟩
  • Ravi Srivastava, Martin Jakoobi, Chloé Thieuleux, Elsje Alessandra Quadrelli, Clément Camp. A Family of Rhodium(I) NHC Chelates Featuring O-containing Tethers for Catalytic Tandem Alkene Isomerization-Hydrosilylation. Dalton Transactions, Royal Society of Chemistry, 2020, ⟨10.1039/D0DT03698F⟩. ⟨hal-03015981⟩
  • Ravi Srivastava, Elsje Alessandra Quadrelli, Clément Camp. Lability of Ta–NHC adducts as a synthetic route towards heterobimetallic Ta/Rh complexes. Dalton Transactions, Royal Society of Chemistry, 2020, ⟨10.1039/D0DT00344A⟩. ⟨hal-02495538⟩
  • Iker Del rosal, Sébastien Lassalle, Laurent Maron, Chiara Dinoi, Chloé Thieuleux, et al.. Mechanistic Investigations via DFT Support the Cooperative Heterobimetallic C-H and O-H Bond Activation Across Ta=Ir Multiple Bonds. Dalton Transactions, Royal Society of Chemistry, 2020, ⟨10.1039/D0DT03818K⟩. ⟨hal-03009651⟩
  • Yorck Mohr, Marc Renom-Carrasco, Clément Demarcy, Elsje Alessandra Quadrelli, Clément Camp, et al.. Regiospecificity in Ligand-Free Pd-Catalyzed C–H Arylation of Indoles: LiHMDS as Base and Transient Directing Group. ACS Catalysis, American Chemical Society, 2020, 10 (4), pp.2713-2719. ⟨10.1021/acscatal.9b04864⟩. ⟨hal-02493979⟩
  • Sébastien Lassalle, Ribal Jabbour, Pauline Schiltz, Pierrick Berruyer, Tanya Todorova, et al.. Metal–Metal Synergy in Well-Defined Surface Tantalum–Iridium Heterobimetallic Catalysts for H/D Exchange Reactions. Journal of the American Chemical Society, American Chemical Society, 2019, ⟨10.1021/jacs.9b08311⟩. ⟨hal-02382262⟩
  • Akash Kaithal, Lisa-Lou Gracia, Clément Camp, Elsje Alessandra Quadrelli, Walter Leitner. Direct Synthesis of Cycloalkanes from Diols and Secondary Alcohols or Ketones Using a Homogeneous Manganese Catalyst. Journal of the American Chemical Society, American Chemical Society, 2019, 141 (44), pp.17487-17492. ⟨10.1021/jacs.9b08832⟩. ⟨hal-02367932⟩
  • Yuanyuan Cao, Yanlin Wu, Clémence Badie, Stéphane Cadot, Clément Camp, et al.. Electrocatalytic Performance of Titania Nanotube Arrays Coated with MoS 2 by ALD toward the Hydrogen Evolution Reaction. ACS Omega, ACS Publications, 2019, 4 (5), pp.8816-8823. ⟨10.1021/acsomega.9b00322⟩. ⟨hal-02284907⟩
  • Vincent Dardun, Léon Escomel, Erwann Jeanneau, Clément Camp. On the alcoholysis of alkyl-aluminum (iii) alkoxy-NHC derivatives: reactivity of the Al-carbene Lewis pair versus Al-alkyl. Dalton Transactions, Royal Society of Chemistry, 2018, 47 (31), pp.10429--10433. ⟨10.1039/C8DT01498A⟩. ⟨hal-01877466⟩
  • Ravi Srivastava, Raphaël Moneuse, Julien Petit, Paul-Alexis Pavard, Vincent Dardun, et al.. Early/Late Heterobimetallic Tantalum/Rhodium Species Assembled Through a Novel Bifunctional NHC-OH Ligand. Chemistry - A European Journal, Wiley-VCH Verlag, 2018, 24 (17), pp.4361--4370. ⟨10.1002/chem.201705507⟩. ⟨hal-01877468⟩
  • Chia-Wei Hsu, Yi-Chou Tsai, Brandi M Cossairt, Clément Camp, John Arnold, et al.. SYNTHETIC ROUTE TO WHITE PHOSPHORUS (P4) AND ARSENIC TRIPHOSPHIDE (AsP3). Inorganic Syntheses, 2018, 37, pp.123--134. ⟨hal-01877467⟩
  • Clément Camp, Davide Toniolo, Julie Andrez, Jacques Pécaut, Marinella Mazzanti. A versatile route to homo-and hetero-bimetallic 5f−5f and 3d−5f complexes supported by a redox active ligand framework. Dalton Transactions, Royal Society of Chemistry, 2017, 46 (34), pp.11145--11148. ⟨10.1039/C7DT01993A⟩. ⟨hal-01877469⟩
  • Clément Camp, John Arnold. On the non-innocence of “Nacnacs”: ligand-based reactivity in β-diketiminate supported coordination compounds. Dalton Transactions, Royal Society of Chemistry, 2016, 45 (37), pp.14462--14498. ⟨hal-01877471⟩
  • Clément Camp, Lauren N Grant, Robert G Bergman, John Arnold. Photo-activation of d 0 niobium imido azides: en route to nitrido complexes. Chemical Communications, Royal Society of Chemistry, 2016, 52 (32), pp.5538--5541. ⟨hal-01877472⟩
  • Clément Camp, Lara Ce Naested, Kay Severin, John Arnold. N−N bond cleavage in a nitrous oxide−NHC adduct promoted by a PNP pincer cobalt (I) complex. Polyhedron, Elsevier, 2016, 103, pp.157--163. ⟨hal-01877470⟩
  • Clément Camp, Lucile Chatelain, Christos E. Kefalidis, Jacques Pécaut, Laurent Maron, et al.. CO2 conversion to isocyanate via multiple N-Si bond cleavage at a bulky uranium(III) complex. Chemical Communications, Royal Society of Chemistry, 2015, 51 (84), pp.15454-15457. ⟨10.1039/c5cc06707c⟩. ⟨hal-01588142⟩
  • Clément Camp, Nicholas Settineri, Julia Lefèvre, Andrew R Jupp, José M Goicoechea, et al.. Uranium and thorium complexes of the phosphaethynolate ion. Chemical Science , The Royal Society of Chemistry, 2015, 6 (11), pp.6379--6384. ⟨10.1039/c5sc02150b⟩. ⟨hal-01877473⟩
  • Clément Camp, Lucile Chatelain, Victor Mougel, Jacques Pécaut, Marinella Mazzanti. Ferrocene-Based Tetradentate Schiff Bases as Supporting Ligands in Uranium Chemistry. Inorganic Chemistry, American Chemical Society, 2015, 54 (12), pp.5774-5783. ⟨10.1021/acs.inorgchem.5b00467⟩. ⟨hal-01588141⟩
  • Alison B Altman, Cd Pemmaraju, Clément Camp, John Arnold, Stefan G Minasian, et al.. Theory and X-ray Absorption Spectroscopy for Aluminum Coordination Complexes−Al K-Edge Studies of Charge and Bonding in (BDI) Al,(BDI) AlR2, and (BDI) AlX2 Complexes. Journal of the American Chemical Society, American Chemical Society, 2015, 137 (32), pp.10304--10316. ⟨hal-01877474⟩
  • Clément Camp, Oliver Cooper, Julie Andrez, Jacques Pécaut, Marinella Mazzanti. CS2 activation at uranium(III) siloxide ate complexes: the effect of a Lewis acidic site. Dalton Transactions, Royal Society of Chemistry, 2015, 44 (6), pp.2650-2656. ⟨10.1039/c4dt02585g⟩. ⟨hal-01588140⟩
  • Laura Cj Pereira, Clément Camp, Joana T Coutinho, Lucile Chatelain, Pascale Maldivi, et al.. Single-Molecule-Magnet Behavior in Mononuclear Homoleptic Tetrahedral Uranium (III) Complexes. Inorganic Chemistry, American Chemical Society, 2014, 53 (22), pp.11809--11811. ⟨10.1021/ic501520c⟩. ⟨hal-01877479⟩
  • Clément Camp, Laurent Maron, Robert G Bergman, John Arnold. Activation of White Phosphorus by Low-Valent Group 5 Complexes: Formation and Reactivity of cyclo-P4 Inverted Sandwich Compounds. Journal of the American Chemical Society, American Chemical Society, 2014, 136 (50), pp.17652--17661. ⟨hal-01877475⟩
  • Clément Camp, Maria Augusta Antunes, Gregorio García, Ilaria Ciofini, Isabel C Santos, et al.. Two-electron versus one-electron reduction of chalcogens by uranium (III): synthesis of a terminal U (V) persulfide complex. Chemical Science , The Royal Society of Chemistry, 2014, 5 (2), pp.841--846. ⟨10.1039/C3SC52742E⟩. ⟨hal-01877477⟩
  • Oliver Cooper, Clément Camp, Jacques Pécaut, Christos E. Kefalidis, Laurent Maron, et al.. Multimetallic cooperativity in uranium-mediated CO2 activation. Journal of the American Chemical Society, American Chemical Society, 2014, 136 (18), pp.6716--6723. ⟨10.1021/ja5017624⟩. ⟨hal-01877478⟩
  • Sergio S Rozenel, Rosa Padilla, Clément Camp, John Arnold. Unusual activation of H 2 by reduced cobalt complexes supported by a PNP pincer ligand. Chemical Communications, Royal Society of Chemistry, 2014, 50 (20), pp.2612--2614. ⟨hal-01877476⟩
  • Clément Camp, Victor Mougel, Jacques Pécaut, Laurent Maron, Marinella Mazzanti. Cation-Mediated Conversion of the State of Charge in Uranium Arene Inverted-Sandwich Complexes. Chemistry - A European Journal, Wiley-VCH Verlag, 2013, 19 (51), pp.17528--17540. ⟨10.1002/chem.201302752⟩. ⟨hal-01877482⟩
  • Clément Camp, Jacques Pécaut, Marinella Mazzanti. Tuning uranium−nitrogen multiple bond formation with ancillary siloxide ligands. Journal of the American Chemical Society, American Chemical Society, 2013, 135 (32), pp.12101--12111. ⟨10.1021/ja405815b⟩. ⟨hal-01877481⟩
  • Clément Camp, Julie Andrez, Jacques Pécaut, Marinella Mazzanti. Synthesis of Electron-Rich Uranium (IV) Complexes Supported by Tridentate Schiff Base Ligands and Their Multi-Electron Redox Chemistry. Inorganic Chemistry, American Chemical Society, 2013, 52 (12), pp.7078--7086. ⟨10.1021/ic4006218⟩. ⟨hal-01877483⟩
  • Clément Camp, Christos E. Kefalidis, Jacques Pécaut, Laurent Maron, Marinella Mazzanti. Controlled Thermolysis of Uranium (Alkoxy) siloxy Complexes: A Route to Polymetallic Complexes of Low-Valent Uranium. Angewandte Chemie International Edition, Wiley-VCH Verlag, 2013, 52 (48), pp.12646--12650. ⟨10.1002/anie.201307291⟩. ⟨hal-01877480⟩
  • Clément Camp, Valentin Guidal, Biplab Biswas, Jacques Pécaut, Lionel Dubois, et al.. Multielectron redox chemistry of lanthanide Schiff-base complexes. Chemical Science , The Royal Society of Chemistry, 2012, 3 (8), pp.2433--2448. ⟨10.1039/C2SC20476B⟩. ⟨hal-01877485⟩
  • Elsa Mora, Leonor Maria, Biplab Biswas, Clément Camp, Isabel C Santos, et al.. Diamine bis (phenolate) as supporting ligands in organoactinide (iv) chemistry. Synthesis, structural characterization, and reactivity of stable dialkyl derivatives. Organometallics, American Chemical Society, 2012, 32 (5), pp.1409--1422. ⟨10.1021/om3010806⟩. ⟨hal-01877484⟩
  • Victor Mougel, Clément Camp, Jacques Pécaut, Christophe Copéret, Laurent Maron, et al.. Siloxides as Supporting Ligands in Uranium (III)-Mediated Small-Molecule Activation. Angewandte Chemie, Wiley-VCH Verlag, 2012, 124 (49), pp.12446--12450. ⟨10.1002/anie.201206955⟩. ⟨hal-01877486⟩
  • Clément Camp, Victor Mougel, Pawel Horeglad, Jacques Pécaut, Marinella Mazzanti. Multielectron Redox Reactions Involving C- C Coupling and Cleavage in Uranium Schiff Base Complexes. Journal of the American Chemical Society, American Chemical Society, 2010, 132 (49), pp.17374--17377. ⟨10.1021/ja1089364⟩. ⟨hal-01877487⟩
  • Clément Camp, Sandra Dorbes, Claude Picard, Eric Benoist. Efficient and tunable synthesis of new polydentate bifunctional chelating agents using click chemistry. Tetrahedron Letters, Elsevier, 2008, 49 (12), pp.1979--1983. ⟨10.1016/j.tetlet.2008.01.086⟩. ⟨hal-01877488⟩

Theses1 document

  • Clément Camp. Conception et réactivité de complexes mono- et polymétalliques d'éléments f en bas degré d'oxydation. Sciences agricoles. Université de Grenoble, 2013. Français. ⟨NNT : 2013GRENV023⟩. ⟨tel-00949379⟩