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80

Christophe Tournassat

Christophe Tournassat holds B.Sc. and M.Sc. degrees in Earth Sciences from the Ecole Normale Supérieure de Lyon, France, a Ph.D. in Environmental Geochemistry from the University of Grenoble, France, and an "Habilitation à diriger des recherches" in Geology from the University of Nantes, France.  In 2003 he joined the French Geological Survey (BRGM) as a staff Scientist.  Since 2010, he has been heading the BRGM scientific program on geological barriers performances, which includes BRGM’s researches on radioactive waste storage. In 2017, he took the lead of the group "Porous Media"  in the framework of the renewal of the collaboration between BRGM, CNRS and the University of Orléans in the ISTO laboratory (Institut des Science de la Terre d'Orléans). In addition, he took a part-time position at the Energy Geoscience Division of the Lawrence Berkeley Laboratory in 2017, in order to pursue its collaboration with Carl Steefel and Benjamin Gilbert at LBL in the framework of the LBNL-BRGM collaboration agreement. His scientific interest covers a wide range of topics from thermodynamics and kinetics of low temperature water/solutes/rock interactions to multi-scale numerical modeling of retention and transfer processes in geological media.

Journal articles75 documents

  • Sergey Kraevsky, Christophe Tournassat, Marylène Vayer, Fabienne Warmont, Sylvain Grangeon, et al.. Identification of montmorillonite particle edge orientations by atomic-force microscopy. Applied Clay Science, Elsevier, 2020, 186, 105442 (8 p.). ⟨10.1016/j.clay.2020.105442⟩. ⟨insu-02476314⟩
  • Xiandong Liu, Christophe Tournassat, Carl I. Steefel. Preface to Multiscale Simulation in Geochemistry. Geochimica et Cosmochimica Acta, Elsevier, In press, ⟨10.1016/j.gca.2020.09.011⟩. ⟨insu-02942528⟩
  • Myriam Agnel, Sylvain Grangeon, François Fauth, Erik Elkaim, Francis Claret, et al.. Mechanistic and Thermodynamic Insights into Anion Exchange by Green Rust. Environmental Science & Technology, American Chemical Society, 2020, 54 (2), pp.851-861. ⟨10.1021/acs.est.9b05632⟩. ⟨hal-02488822⟩
  • Christophe Tournassat, Carl Steefel, Thomas Gimmi. Solving the Nernst‐Planck Equation in Heterogeneous Porous Media with Finite Volume Methods: Averaging Approaches at Interfaces. Water Resources Research, American Geophysical Union, 2020, 56 (3), 10 p. ⟨10.1029/2019WR026832⟩. ⟨insu-02496420⟩
  • Sébastien Le Crom, Christophe Tournassat, Jean-Charles Robinet, Virginie Marry. Influence of Polarizability on the Prediction of the Electrical Double Layer Structure in a Clay Mesopore: A Molecular Dynamics Study. Journal of Physical Chemistry C, American Chemical Society, 2020, 124 (11), pp.6221-6232. ⟨10.1021/acs.jpcc.0c00190⟩. ⟨hal-02875380⟩
  • Christophe Tournassat, Carl Steefel. Modeling diffusion processes in the presence of a diffuse layer at charged mineral surfaces: a benchmark exercise. Computational Geosciences, Springer Verlag, 2019, ⟨10.1007/s10596-019-09845-4⟩. ⟨insu-02280189⟩
  • Chi Zhang, Xiandong Liu, Ruth Tinnacher, Christophe Tournassat. Mechanistic Understanding of Uranyl Ion Complexation on Montmorillonite Edges: A Combined First-Principles Molecular Dynamics–Surface Complexation Modeling Approach. Environmental Science & Technology, American Chemical Society, 2018, 52 (15), pp.8501 - 8509. ⟨10.1021/acs.est.8b02504⟩. ⟨insu-01868517⟩
  • Nicolas Marty, Adeline Lach, Catherine Lerouge, Sylvain Grangeon, Francis Claret, et al.. Weathering of an argillaceous rock in the presence of atmospheric conditions: A flow-through experiment and modelling study. Applied Geochemistry, Elsevier, 2018, 96, pp.252-263. ⟨10.1016/j.apgeochem.2018.07.005⟩. ⟨insu-02356015⟩
  • Esra Orucoglu, Christophe Tournassat, Jean-Charles Robinet, Benoît Made, Mélanie Lundy. From experimental variability to the sorption related retention parameters necessary for performance assessment models for nuclear waste disposal systems: The example of Pb adsorption on clay minerals. Applied Clay Science, Elsevier, 2018, 163, pp.20 - 32. ⟨10.1016/j.clay.2018.07.003⟩. ⟨insu-01857042⟩
  • Mathieu Debure, Christophe Tournassat, Catherine Lerouge, Benoît Made, Jean-Charles Robinet, et al.. Retention of arsenic, chromium and boron on an outcropping clay-rich rock formation (the Tégulines Clay, eastern France). Science of the Total Environment, Elsevier, 2018, 642, pp.216-229. ⟨10.1016/j.scitotenv.2018.06.037⟩. ⟨insu-01817676⟩
  • Catherine Lerouge, Jean-Charles Robinet, Mathieu Debure, Christophe Tournassat, Alain Bouchet, et al.. A Deep Alteration and Oxidation Profile in a Shallow Clay Aquitard: Example of the Tégulines Clay, East Paris Basin, France. Geofluids, Wiley, 2018, 2018, pp.1 - 20. ⟨10.1155/2018/1606753⟩. ⟨insu-01719398⟩
  • Bin Ma, Alejandro Fernandez-Martinez, Sylvain Grangeon, Christophe Tournassat, Nathaniel Findling, et al.. Selenite Uptake by Ca–Al LDH: A Description of Intercalated Anion Coordination Geometries. Environmental Science & Technology, American Chemical Society, 2018, 52 (3), pp.1624 - 1632. ⟨10.1021/acs.est.7b04644⟩. ⟨insu-01882419⟩
  • Christophe Tournassat, R.M. Tinnacher, S. Grangeon, J.A. Davis. Modeling uranium(VI) adsorption onto montmorillonite under varying carbo- nate concentrations: A surface complexation model accounting for the spillover effect on surface potential. Geochimica et Cosmochimica Acta, Elsevier, 2018, 220, pp.291-308. ⟨10.1016/j.gca.2017.09.049⟩. ⟨insu-01614123v2⟩
  • Nicolas Marty, Sylvain Grangeon, Erik Elkaim, Christophe Tournassat, Clémence Fauchet, et al.. Thermodynamic and crystallographic model for anion uptake by hydrated calcium aluminate (AFm): an example of molybdenum. Scientific Reports, Nature Publishing Group, 2018, 8, pp.7943. ⟨10.1038/s41598-018-26211-z⟩. ⟨insu-01817891⟩
  • Francis Claret, Sylvain Grangeon, Annick Loschetter, Christophe Tournassat, Wout de Nolf, et al.. Deciphering mineralogical changes and carbonation development during hydration and ageing of a consolidated ternary blended cement paste. IUCrJ = International Union of Crystallography journal, International Union of Crystallography 2018, 5 (2), pp.150 - 157. ⟨10.1107/S205225251701836X⟩. ⟨insu-01766385⟩
  • Philippe Leroy, Maximilian Weigand, Guillaume Mériguet, Egon Zimmermann, Christophe Tournassat, et al.. Spectral induced polarization of Na-montmorillonite dispersions. Journal of Colloid and Interface Science, Elsevier, 2017, 505, pp.1093-1110. ⟨10.1016/j.jcis.2017.06.071⟩. ⟨insu-01546901⟩
  • Stéphane Gaboreau, Dimitri Pret, Valerie Montouillout, Pierre Henocq, Jean-Charles Robinet, et al.. Quantitative mineralogical mapping of hydrated low pH concrete. Cement and Concrete Composites, Elsevier, 2017, 83, pp.360 - 373. ⟨10.1016/j.cemconcomp.2017.08.003⟩. ⟨hal-01619711⟩
  • Sylvain Grangeon, Fabienne Warmont, Christophe Tournassat, Bruno Lanson, Martine Lanson, et al.. Nucleation and growth of feitknechtite from nanocrystalline vernadite precursor. European Journal of Mineralogy, Copernicus, 2017, 29, pp.767-776. ⟨10.1127/ejm/2017/0029-2665⟩. ⟨insu-01598457⟩
  • Bin Ma, Alejandro Fernandez-Martinez, Sylvain Grangeon, Christophe Tournassat, Nathaniel Findling, et al.. Evidence of Multiple Sorption Modes in Layered Double Hydroxides Using Mo As Structural Probe. Environmental Science & Technology, American Chemical Society, 2017, 51 (10), pp.5531 - 5540. ⟨10.1021/acs.est.7b00946⟩. ⟨hal-01849363⟩
  • Hélène Gailhanou, Catherine Lerouge, Mathieu Debure, Stéphane Gaboreau, Eric C. Gaucher, et al.. Effects of a thermal perturbation on mineralogy and pore water composition in a clay-rock: an experimental and modeling study. Geochimica et Cosmochimica Acta, Elsevier, 2017, 197, pp.193-214. ⟨10.1016/j.gca.2016.10.004⟩. ⟨insu-01387039v2⟩
  • Sylvain Grangeon, Alejandro Fernandez-Martinez, Francis Claret, Nicolas Marty, Christophe Tournassat, et al.. In-situ determination of the kinetics and mechanisms of nickel adsorption by nanocrystalline vernadite. Chemical Geology, Elsevier, 2017, 459, pp.24 - 31. ⟨10.1016/j.chemgeo.2017.03.035⟩. ⟨hal-01849472⟩
  • Ian C. Bourg, Sang Soo Lee, Paul Fenter, Christophe Tournassat. Stern Layer Structure and Energetics at Mica–Water Interfaces. Journal of Physical Chemistry C, American Chemical Society, 2017, 121 (17), pp.9402 - 9412. ⟨10.1021/acs.jpcc.7b01828⟩. ⟨insu-01580064⟩
  • Christophe Tournassat, James Davis, Christophe Chiaberge, Sylvain Grangeon, Ian C. Bourg. Modeling the Acid-Base Properties of Montmorillonite Edge Surfaces. Environmental Science & Technology, American Chemical Society, 2016, 50 (24), pp.13436-13445. ⟨10.1021/acs.est.6b04677⟩. ⟨insu-01415340⟩
  • Jebril Hadi, Christophe Tournassat, Catherine Lerouge. Pitfalls in using the hexaamminecobalt method for cation exchange capacity measurements on clay minerals and clay-rocks: Redox interferences between the cationic dye and the sample.. Applied Clay Science, Elsevier, 2016, 119 (1), ⟨10.1016/j.clay.2015.03.017⟩. ⟨hal-01269877⟩
  • Christophe Tournassat, Ian C. Bourg, Michael Holmboe, Garrison Sposito, Carl I. Steefel. Molecular dynamics simulations of anion exclusion in clay interlayer nanopores.. Clays and Clay Minerals, Clay Minerals Society, 2016, 4, pp.374-388. ⟨10.1346/CCMN.2016.0640403⟩. ⟨insu-01406301⟩
  • Ruth M. Tinnacher, Michael Holmboe, Christophe Tournassat, Ian C. Bourg, James A. Davis. Ion adsorption and diffusion in smectite : molecular, pore, and continuum scale views. Geochimica et Cosmochimica Acta, Elsevier, 2016, 177, pp.130-149. ⟨10.1016/j.gca.2015.12.010⟩. ⟨hal-01368176⟩
  • Philippe Leroy, Christophe Tournassat, Olivier Bernard, Nicolas Devau, Mohamed Azaroual. The electrophoretic mobility of montmorillonite. Zeta potential and surface conductivity effects. Journal of Colloid and Interface Science, Elsevier, 2015, 451, pp.21-39. ⟨10.1016/j.jcis.2015.03.047⟩. ⟨hal-01269931⟩
  • Nicolas Marty, Francis Claret, Arnault Lassin, Joachim Tremosa, Philippe Blanc, et al.. A database of dissolution and precipitation rates for clay-rocks minerals. Applied Geochemistry, Elsevier, 2015, 55, pp.108-118. ⟨10.1016/j.apgeochem.2014.10.012⟩. ⟨hal-01355409⟩
  • Christophe Tournassat, Carl I. Steefel. Ionic Transport in Nano-Porous Clays with Consideration of Electrostatic Effects. Reviews in Mineralogy and Geochemistry, Mineralogical Society, 2015, 80, pp.287-330. ⟨10.2138/rmg.2015.80.09⟩. ⟨hal-01269893⟩
  • Peter Alt-Epping, Christophe Tournassat, P. Rasouli, C. I. Steefel, K. U. Mayer, et al.. Benchmark reactive transport simulations of a column experiment in compacted bentonite with multispecies diffusion and explicit treatment of electrostatic effects. Computational Geosciences, Springer Verlag, 2015, 19 (3), pp.535-550. ⟨10.1007/s10596-014-9451-x⟩. ⟨hal-01192890⟩
  • Aurélie Chagneau, Christophe Tournassat, Carl I. Steefel, Ian C. Bourg, Stéphane Gaboreau, et al.. Complete restriction of 36Cl-diffusion by celestite precipitation in densely compacted illite. Environmental Science & Technology Letters, 2015, 2 (5), pp.139-143. ⟨10.1021/acs.estlett.5b00080⟩. ⟨hal-01269920⟩
  • Sylvain Grangeon, Agnès Vinsot, Christophe Tournassat, Catherine Lerouge, Eric Giffaut, et al.. The influence of natural trace element distribution on the mobility of radionuclides. The exemple of nickel in a clay-rock. Applied Geochemistry, Elsevier, 2015, 52, pp.155-173. ⟨10.1016/j.apgeochem.2014.11.009⟩. ⟨hal-01192891⟩
  • Myriam Kars, Catherine Lerouge, Sylvain Grangeon, Charles Aubourg, Christophe Tournassat, et al.. Identification of nanocrystalline goethite in reduced clay formations: Application to the Callovian-Oxfordian formation of Bure (France). American mineralogist, 2015, 100 (7), ⟨10.2138/am-2015-5096⟩. ⟨hal-01269885⟩
  • Z. Chen, Gilles Montavon, S. Ribet, Z. Guo, J.C. Robinet, et al.. Key factors to understand in-situ behavior of Cs in Callovo-Oxfordian clay rock. Chemical Geology, Elsevier, 2014, 387, pp.47-58. ⟨10.1016/j.chemgeo.2014.08.008⟩. ⟨in2p3-01154526⟩
  • Catherine Lerouge, Francis Claret, Christophe Tournassat, Sylvain Grangeon, Stéphane Gaboreau, et al.. Constraints from sulfur isotopes on the origin of gypsum at concrete/claystone interfaces. Physics and Chemistry of The Earth, Elsevier, 2014, 70-71, pp.84-95. ⟨10.1016/j.pce.2014.01.003⟩. ⟨hal-01055790⟩
  • A.M. Fernandez, D.M. Sánchez-Ledesma, Christophe Tournassat, A. Melón, Eric C. Gaucher. Applying the squeezing technique to highly consolidated clayrocks for pore water characterisation: Lessons learned from experiments at the Mont Terri Rock Laboratory. Applied Geochemistry, Elsevier, 2014, 49, pp.2-21. ⟨10.1016/j.apgeochem.2014.07.003⟩. ⟨hal-01172036⟩
  • Nicolas Marty, Isabelle Munier, Eric C. Gaucher, Christophe Tournassat, Stéphane Gaboreau, et al.. Simulation of Cement/Clay Interactions: Feedback on the Increasing Complexity of Modelling Strategies. Transport in Porous Media, Springer Verlag, 2014, 104 (2), pp.385-405. ⟨10.1007/s11242-014-0340-5⟩. ⟨hal-01176615⟩
  • Christophe Tournassat, Sylvain Grangeon, Philippe Leroy, E. Giffaut. Modeling specific pH dependent sorption of divalent metals on montmorillonite surfaces. A review of pitfalls, recent achievements and current challenges. American journal of science, American Journal of Science, 2013, 313 (5), pp.395-451. ⟨10.2475/05.2013.01⟩. ⟨hal-01027680⟩
  • Jebril Hadi, Christophe Tournassat, Ioannis Ignatiadis, Jean-Marc Greneche, Laurent Charlet. Modelling CEC variations versus structural iron reduction levels in dioctahedral smectites. Existing approaches, new data and model refinements. Journal of Colloid and Interface Science, Elsevier, 2013, 407, pp.397-409. ⟨10.1016/j.jcis.2013.05.014⟩. ⟨hal-01024553⟩
  • J. Tremosa, D. Arcos, J.M. Matray, F. Bensenouci, Eric C. Gaucher, et al.. Geochemical characterization and modelling of the Toarcian/Domerian porewater at the Tournemire underground research laboratory. Applied Geochemistry, Elsevier, 2012, 27 (7), pp.1417-1431. ⟨10.1016/j.apgeochem.2012.01.005⟩. ⟨hal-00675192⟩
  • Stéphane Gaboreau, Francis Claret, Catherine Crouzet, Eric Giffaut, Christophe Tournassat. Caesium uptake by Callovian-Oxfordian clayrock under alkaline perturbation. Applied Geochemistry, Elsevier, 2012, 27 (6), pp.1194-1201. ⟨10.1016/j.apgeochem.2012.02.002⟩. ⟨hal-00861257⟩
  • Scott Altmann, Christophe Tournassat, Goutelard Florence, J.C. Parneix, Thomas Gimmi, et al.. Diffusion-driven transport in clayrock formations. Applied Geochemistry, Elsevier, 2012, 27, pp.463-478. ⟨10.1016/j.apgeochem.2011.09.015⟩. ⟨hal-00664227⟩
  • Nicolas Marty, Jordi Cama, Tsutomo Sato, Daisuke Chino, Frédéric Villiéras, et al.. Dissolution kinetics of synthetic Na-smectite. An integrated experimental approach. Geochimica et Cosmochimica Acta, Elsevier, 2011, 75 (20), pp.5849-5864. ⟨10.1016/j.gca.2011.06.037⟩. ⟨hal-00665321⟩
  • Paul Wersin, S. Stroes-Gascoyne, F.J. Pearson, Christophe Tournassat, O.X. Leupin, et al.. Biogeochemical processes in a clay formation in situ experiment: Part G - Key interpretations and conclusions. Implications for repository safety. Applied Geochemistry, Elsevier, 2011, 26, pp.1023-1034. ⟨10.1016/j.apgeochem.2011.03.010⟩. ⟨hal-00597107⟩
  • Christophe Tournassat, Peter Alt-Epping, Eric C. Gaucher, Thomas Gimmi, O.X. Leupin, et al.. Biogeochemical processes in a clay formation in situ experiment: Part F - Reactive transport modelling. Applied Geochemistry, Elsevier, 2011, 26, pp.1009-1022. ⟨10.1016/j.apgeochem.2011.03.009⟩. ⟨hal-00597122⟩
  • Francis Claret, Christophe Tournassat, Catherine Crouzet, Eric C. Gaucher, Thorsten Schäfer, et al.. Metal speciation in landfill leachates with a focus on the influence of organic matter. Waste Management, Elsevier, 2011, 31 (9-10), pp.2036-2045. ⟨10.1016/j.wasman.2011.05.014⟩. ⟨hal-00605888⟩
  • Christophe Tournassat, C. A. J. Appelo. Modelling approaches for anion-exclusion in compacted Na-bentonite. Geochimica et Cosmochimica Acta, Elsevier, 2011, 75 (13), pp.3698-3710. ⟨10.1016/j.gca.2011.04.001⟩. ⟨hal-00597084⟩
  • Philippe Leroy, Christophe Tournassat, Mohamed Bizi. Influence of surface conductivity on the apparent zeta potential of TiO2 nanoparticles. Journal of Colloid and Interface Science, Elsevier, 2011, 356 (2), pp.442-453. ⟨10.1016/j.jcis.2011.01.016⟩. ⟨hal-00600299⟩
  • F.J. Pearson, Christophe Tournassat, Eric C. Gaucher. Biogeochemical Processes in a Clay Formation In-Situ Experiment: Part E - Equilibrium Controls on Chemistry of Pore Water from the Opalinus Clay, Mont Terri Underground Research Laboratory, Switzerland. Applied Geochemistry, Elsevier, 2011, 26, pp.990-1008. ⟨10.1016/j.apgeochem.2011.03.008⟩. ⟨hal-00597132⟩
  • Christophe Tournassat, Mohamed Bizi, Gilles Braibant, Catherine Crouzet. Influence of montmorillonite tactoid size on Na-Ca cation exchange reactions.. Journal of Colloid and Interface Science, Elsevier, 2011, 15 (2), pp.443-454. ⟨10.1016/j.jcis.2011.07.039⟩. ⟨hal-00664233⟩
  • Catherine Lerouge, S. Grangeon, Eric C. Gaucher, Christophe Tournassat, Pierre Agrinier, et al.. Mineralogical and isotopic record of biotic and abiotic diagenesis of the Callovian-Oxfordian clayey formation of Bure (France). Geochimica et Cosmochimica Acta, Elsevier, 2011, 75 (10), pp.2633-2663. ⟨10.1016/j.gca.2011.02.025⟩. ⟨insu-00587526⟩
  • Mariem Ghayaza, Lydie Le Forestier, Fabrice Muller, Christophe Tournassat, Jean-Michel Bény. Pb(II) and Zn(II) adsorption onto Na- and Ca-montmorillonites in acetic acid/acetate medium: Experimental approach and geochemical modelling. Journal of Colloid and Interface Science, Elsevier, 2011, 361, pp.238-246. ⟨10.1016/j.jcis.2011.05.028⟩. ⟨insu-00595248⟩
  • Catherine Lerouge, Eric C. Gaucher, Christophe Tournassat, Philippe Négrel, Catherine Crouzet, et al.. Strontium distribution and origins in a natural clayey formation (Callovian-Oxfordian, Paris Basin, France): A new sequential extraction procedure. Geochimica et Cosmochimica Acta, Elsevier, 2010, 74 (10), p. 2926-2942. ⟨10.1016/j.gca.2010.02.013⟩. ⟨hal-00552939⟩
  • Francis Claret, Catherine Lerouge, Thierry Laurioux, Mohamed Bizi, Thibauld Conte, et al.. Natural iodine in a clay formation: Implications for iodine fate in geological disposals. Geochimica et Cosmochimica Acta, Elsevier, 2010, 74 (1), pp.16-29. ⟨10.1016/j.gca.2009.09.030⟩. ⟨hal-00563956⟩
  • Gilles Montavon, Z. Guo, Christophe Tournassat, Bernd Grambow, Didier Le Botlan. Porosities accessible to HTO and iodide on water-saturated compacted clay materials and relation with the forms of water: A low field proton NMR study. Geochimica et Cosmochimica Acta, Elsevier, 2009, 73 (24), pp.7290-7302. ⟨10.1016/j.gca.2009.09.014⟩. ⟨hal-00450881⟩
  • T. Melkior, Eric C. Gaucher, C. Brouard, S. Yahiaoui, D. Thoby, et al.. Na+ and HTO diffusion in compacted bentonite: Effect of surface chemistry and related texture. Journal of Hydrology, Elsevier, 2009, 370 (1-4), p. 9-20. ⟨10.1016/j.jhydrol.2009.02.035⟩. ⟨hal-00512714⟩
  • Nicolas Marty, Christophe Tournassat, André Burnol, Eric Giffaut, Eric C. Gaucher. Influence of reaction kinetics and mesh refinement on the numerical modelling of concrete/clay interactions. Journal of Hydrology, Elsevier, 2009, 364 (1-2), p. 58-72. ⟨10.1016/j.jhydrol.2008.10.013⟩. ⟨hal-00512711⟩
  • Eric C. Gaucher, Christophe Tournassat, F.J. Pearson, Philippe Blanc, Catherine Crouzet, et al.. A robust model for pore-water chemistry of clayrock. Geochimica et Cosmochimica Acta, Elsevier, 2009, 73 (21), p.6470-6483. ⟨10.1016/j.gca.2009.07.021⟩. ⟨hal-00512606⟩
  • Christophe Tournassat, Yves Chapron, Philippe Leroy, Mohamed Bizi, Faïza Boulahya. Comparison of molecular dynamics simulations with triple layer and modified Gouy-Chapman models in a 0.1 M NaCl-montmorillonite system. Journal of Colloid and Interface Science, Elsevier, 2009, 339 (2), p. 533-541. ⟨10.1016/j.jcis.2009.06.051⟩. ⟨hal-00514041⟩
  • Christophe Tournassat, Hélène Gailhanou, Catherine Crouzet, Gilles Braibant, Anne Gautier, et al.. Cation Exchange Selectivity Coeffi cient Values on Smectite and Mixed-Layer Illite/Smectite Minerals. Soil Science Society of America Journal, Soil Science Society of America, 2009, 73 (3), p. 928-942. ⟨10.2136/sssaj2008.0285⟩. ⟨hal-00514039⟩
  • Christophe Tournassat, Catherine Lerouge, Philippe Blanc, Jocelyne Brendle, Jean-Marc Greneche, et al.. Cation exchanged Fe(II) and Sr compared to other divalent cations (Ca, Mg) in the Bure Callovian-Oxfordian formation. Implications for porewater composition modelling.. Applied Geochemistry, Elsevier, 2008, 23 (4), pp.641-654. ⟨10.1016/j.apgeochem.2007.11.002⟩. ⟨hal-00597171⟩
  • Philippe Leroy, André Revil, Scott Altmann, Christophe Tournassat. Modeling the composition of the pore water in a clay-rock geological formation (Callovo-Oxfordian, France). Geochimica et Cosmochimica Acta, Elsevier, 2007, 71 (5), pp.1087 à 1097. ⟨10.1016/j.gca.2006.11.009⟩. ⟨insu-00404284⟩
  • L. Charlet, A.C. Scheinost, Christophe Tournassat, Jean-Marc Greneche, A. GÉhin, et al.. Electron transfer at the mineral/water interface: Selenium reduction by ferrous iron sorbed on clay. Geochimica et Cosmochimica Acta, Elsevier, 2007, 71 (23), pp.5731-5749. ⟨10.1016/j.gca.2007.08.024⟩. ⟨hal-00261713⟩
  • Christophe Tournassat, Hélène Gailhanou, Catherine Crouzet, Gilles Braibant, Anne Gautier, et al.. Two cation exchange models for direct and inverse modelling of solution major cation composition in equilibrium with illite surfaces. Geochimica et Cosmochimica Acta, Elsevier, 2007, 71 (5), pp.1098-1114. ⟨10.1016/j.gca.2006.11.018⟩. ⟨hal-00597198⟩
  • A. Gehin, Jean-Marc Greneche, Christophe Tournassat, Jocelyne Brendle, Denis G. Rancourt, et al.. Reversible surface-sorption-induced electron-transfer oxidation of Fe(II) at reactive sites on a synthetic clay mineral. Geochimica et Cosmochimica Acta, Elsevier, 2007, 71 (4), pp.863-876. ⟨10.1016/j.gca.2006.10.019⟩. ⟨hal-00597192⟩
  • Christophe Tournassat, Eric C. Gaucher, M. Fattahi, Bernd Grambow. On the mobility and potential retention of iodine in the Callovovian-Oxfordian formation. Physics and Chemistry of the Earth, Parts A/B/C, Elsevier, 2007, 32, pp.539-551. ⟨10.1016/j.pce.2005.12.004⟩. ⟨hal-00597205⟩
  • Eric C. Gaucher, Philippe Blanc, Frédérique Bardot, Gilles Braibant, Stéphane Buschaert, et al.. Modelling the porewater chemistry of the Callovian-Oxfordian formation at a regional scale. Comptes Rendus Géoscience, Elsevier Masson, 2006, 338, pp.917-930. ⟨10.1016/j.crte.2006.06.002⟩. ⟨hal-00664798⟩
  • Ewen Silvester, Laurent Charlet, Christophe Tournassat, Antoine Gehin, Jean-Marc Greneche, et al.. Redox potential measurements and Mössbauer spectrometry of FeII adsorbed onto FeIII (oxyhydr)oxides. Geochimica et Cosmochimica Acta, Elsevier, 2005, 69, pp.4801-4815. ⟨10.1016/j.gca.2005.06.013⟩. ⟨hal-00597392⟩
  • Eric Ferrage, Christophe Tournassat, Emmanuel Rinnert, Laurent Charlet, Bruno Lanson. Experimental evidence for calcium-chloride ion pairs in the interlayer of montmorillonite. A XRD profile modeling approach.. Clays and Clay Minerals, Clay Minerals Society, 2005, 53, pp.348-360. ⟨10.1346/CCMN.2005.0530403⟩. ⟨hal-00105762⟩
  • Laurent Charlet, Christophe Tournassat. Fe(II)-Na(I)-Ca(II) cation exchange on montmorillonite in chloride medium; evidence for preferential clay adsorption of chloride - metal ion pairs in seawater. Aquatic Geochemistry, Springer Verlag, 2005, 11 (2), pp.115-137. ⟨10.1007/s10498-004-1166-5⟩. ⟨hal-00664218⟩
  • Laurent Charlet, Christophe Tournassat. Fe(II)-Na(I)-Ca(II) cation exchange on montmorillonite in chloride medium: Evidence for preferential clay adsorption of chloride - Metal ion pairs in seawater.. Aquatic Geochemistry, Springer Verlag, 2005, 11 (2), pp.115-137. ⟨10.1007/s10498-004-1166-5⟩. ⟨hal-00109237⟩
  • Eric Ferrage, Christophe Tournassat, Emmanuel Rinnert, Bruno Lanson. Influence of pH on the interlayer cationic composition and hydration state of Ca-montmorillonite: analytical chemistry, chemical modelling and XRD profile modelling study.. Geochimica et Cosmochimica Acta, Elsevier, 2005, 69, pp.2797-2812. ⟨10.1016/j.gca.2004.12.008⟩. ⟨hal-00106998⟩
  • E. Silvester, Laurent Charlet, Christophe Tournassat, A. Gehin, Jean-Marc Greneche, et al.. Redox potential measurements and Mossbauer spectrometry of Fe-II adsorbed onto Fe-III (oxyhydr)oxydes.. Geochimica et Cosmochimica Acta, Elsevier, 2005, 69 (20), pp.4801-4815. ⟨10.1016/j.gca.2005.06.013⟩. ⟨hal-00109251⟩
  • Christophe Tournassat, Jean-Marc Greneche, Delphine Tisserand, Laurent Charlet. The titration of clay minerals I. Discontinuous backtitration technique combined with CEC measurements.. Journal of Colloid and Interface Science, Elsevier, 2004, 273 (1), pp.224-233. ⟨10.1016/j.jcis.2003.11.021⟩. ⟨hal-00109236⟩
  • Christophe Tournassat, Eric Ferrage, Christiane Poinsignon, Laurent Charlet. The titration of clay minerals II. Structure-based model and implications for clay reactivity.. Journal of Colloid and Interface Science, Elsevier, 2004, 273 (1), pp.234-246. ⟨10.1016/j.jcis.2003.11.022⟩. ⟨hal-00109235⟩

Book sections3 documents

  • Francis Claret, Nicolas Marty, Christophe Tournassat. Modeling the Long‐term Stability of Multi‐barrier Systems for Nuclear Waste Disposal in Geological Clay Formations. Reactive Transport Modelin. Reactive Transport Modeling: Applications in Subsurface Energy and Environmental Problems, 1, Chapitre 8, Wiley, 2018. ⟨insu-01744775⟩
  • Christophe Tournassat, Stéphane Gaboreau, Jean-Charles Robinet, Ian C. Bourg, Carl I. Steefel. Impact of microstructure on anion exclusion in compacted clay media. Thorsten Schäfer; Reiner Dohrmann; H.C. Greenwell. The Clay Minerals Society Workshop Lectures Series, 21, pp.137-149, 2016, FILLING THE GAPS – FROM MICROSCOPIC PORE STRUCTURES TO TRANSPORT PROPERTIES IN SHALES, ⟨10.1346/CMS-WLS-21.11⟩. ⟨hal-01368169⟩
  • Mariette Wolthers, Laurent Charlet, Christophe Tournassat. Reactivity of bentonite : an additive model applied to uranyl sorption. J. Lützenkirchen. Surface complexation modelling, Elsevier, pp.539-552, 2006, Interface Science and Technology, ⟨10.1016/S1573-4285(06)80064-5⟩. ⟨hal-00597245⟩

Directions of work or proceedings1 document

  • Christophe Tournassat, Carl I. Steefel, Ian C. Bourg, Faiza Bergaya. Natural and engineered clay barriers. Christophe Tournassat; Carl I. Steefel; Ian C. Bourg; Faiza Bergaya. France. 6, Elsevier, 432 p., 2015, Developments in clay science, 9780081000274. ⟨hal-01269869⟩

Theses1 document

  • Christophe Tournassat. Interactions cations - argiles : le cas du Fe(II). Application au contexte de stockage profond des déchets radioactifs. Ingénierie de l'environnement. Université Joseph-Fourier - Grenoble I, 2003. Français. ⟨tel-00710111⟩