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49

Anne Dolbecq


 

Since 2009: Senior scientist, DR2 CNRS, Institut Lavoisier de Versailles, MIM group

Research topics:

Multifunctional molecular polyoxometalates

Metal Organic Frameworks with polyoxometalates building units (POMOFs)

Encapsulation of polyoxometalates into Metal Organic Frameworks (POM@MOFs)

 

Research Experience

 

1997 – 2009: Junior scientist, CR CNRS (section n°14), Institut Lavoisier de Versailles

 

1996 – 1997: Teaching and research assistant position (ATER) in the group of

Prof. M. Verdaguer, Laboratoire de Chimie des Métaux de Transition, Université Paris VI.

Research topic: Synthesis of Co-Fe Prussian blue analogues.

 

1995 – 1996: Post-doctoral researcher in the group of Prof. A. M. Stacyat the University of California at Berkeley, USA (Lavoisier fellowship). Research topic:Molten salt synthesis, structural and magnetic characterization of new cobalt and rhodium oxides.

 

 1992 – 1995: Doctoral researcher (supervision P. Batail)at theUniv. Paris Sud Orsay. Research topic: Organic-inorganic constructions based on functionalized radical salts.

 

Diplomas

2003: Accreditation to supervise research (HDR) University of Versailles Saint Quentin.

1995: PhD in Inorganic Chemistry, University Paris Sud Orsay, France.

1992: Agrégation de Physique, option Chimie

Former student of the Ecole Normale Supérieure, Paris (1988-1992)

 

Awards

 

2000: CNRS bronze medal

 

Administration and Collective Responsibilities

Since 2015: Deputy Director of Institut Lavoisier de Versailles

2008 – 2012: Member of the “Comité National du CNRS”, section n°14


Article dans une revue49 documents

  • Ahmad Naïm, Yoan Chevalier, Younes Bouzidi, Priyanka Gairola, Pierre Mialane, et al.. Aerobic oxidation catalyzed by polyoxometalates associated to an artificial reductase at room temperature and in water. Inorganic Chemistry Frontiers, Royal Society of Chemistry, 2020, 7 (12), pp.2362-2369. ⟨10.1039/d0qi00442a⟩. ⟨hal-02945308⟩
  • Hachem Dridi, Amandine Boulmier, Patricia Bolle, Anne Dolbecq, Jean-Noël Rebilly, et al.. Directing the solid-state photochromic and luminescent behaviors of spiromolecules with Dawson and Anderson polyoxometalate units. Journal of Materials Chemistry C, Royal Society of Chemistry, 2020, 8 (2), pp.637-649. ⟨10.1039/c9tc05906g⟩. ⟨hal-02572108⟩
  • Mathis Duguet, Alex Lemarchand, Youven Benseghir, Pierre Mialane, Maria Gomez-Mingot, et al.. Structure-directing role of immobilized polyoxometalates in the synthesis of porphyrinic Zr-based metal–organic frameworks. Chemical Communications, Royal Society of Chemistry, 2020, 56 (70), pp.10143-10146. ⟨10.1039/d0cc04283h⟩. ⟨hal-02945355⟩
  • Youven Benseghir, Alex Lemarchand, Mathis Duguet, Pierre Mialane, Maria Gomez-Mingot, et al.. Co-immobilization of a Rh Catalyst and a Keggin Polyoxometalate in the UiO-67 Zr-Based Metal–Organic Framework: In Depth Structural Characterization and Photocatalytic Properties for CO2 Reduction. Journal of the American Chemical Society, American Chemical Society, 2020, 142 (20), pp.9428-9438. ⟨hal-02878697⟩
  • Amandine Boulmier, Mohamed Haouas, Somia Tomane, Laurent Michely, Anne Dolbecq, et al.. Photoactive Polyoxometalate/DASA Covalent Hybrids for Photopolymerization in the Visible Range. Chemistry - A European Journal, Wiley-VCH Verlag, 2019, ⟨10.1002/chem.201902573⟩. ⟨hal-02335765⟩
  • Grégoire Paille, Amandine Boulmier, Alexandre Bensaid, Minh-Huong Ha-Thi, Thu-Trang Tran, et al.. An unprecedented {Ni 14 SiW 9 } hybrid polyoxometalate with high photocatalytic hydrogen evolution activity. Chemical Communications, Royal Society of Chemistry, 2019, 55 (29), pp.4166-4169. ⟨10.1039/C9CC01269A⟩. ⟨hal-02296053⟩
  • Grégoire Paille, Maria Gomez-Mingot, Catherine Roch-Marchal, Mohamed Haouas, Youven Ben-Seghir, et al.. Thin Films of Fully Noble Metal-Free POM@MOF for Photo- catalytic Water Oxidation. ACS Applied Materials & Interfaces, Washington, D.C. : American Chemical Society, 2019, 11 (51), pp.47837-47845. ⟨10.1021/acsami.9b13121⟩. ⟨hal-02451033⟩
  • S. Tomane, E. López-Maya, S. Boujday, V. Humblot, J. Marrot, et al.. One-pot synthesis of a new generation of hybrid bisphosphonate polyoxometalate gold nanoparticles as antibiofilm agents. Nanoscale Advances, RSC, 2019, 1 (9), pp.3400-3405. ⟨10.1039/c9na00401g⟩. ⟨hal-02335689⟩
  • William Salomon, Eric Rivière, Xavier Lopez, Nicolas Suaud, Pierre Mialane, et al.. Bicapped Keggin polyoxomolybdates: discrete species and experimental and theoretical investigations on the electronic delocalization in a chain compound. Dalton Transactions, Royal Society of Chemistry, 2018, 47 (31), pp.10636-10645. ⟨10.1039/c8dt01313f⟩. ⟨hal-02335632⟩
  • Grégoire Paille, Maria Gomez-Mingot, Catherine Roch-Marchal, Benedikt Lassalle-Kaiser, Pierre Mialane, et al.. A Fully Noble Metal-Free Photosystem Based on Cobalt- Polyoxometalates Immobilized in a Porphyrinic Metal- Organic-Framework for Water Oxidation. Journal of the American Chemical Society, American Chemical Society, 2018, ⟨10.1021/jacs.7b11788⟩. ⟨hal-02081087⟩
  • Patricia Bolle, Hélène Serier-Brault, Amandine Boulmier, Marin Puget, Clotilde Menet, et al.. Polymorphism and Structural Filiations in Five New Organic–Inorganic Hybrid Salts of the Heteroleptic Cationic Iridium(III) Complex and Polyoxometalates. Crystal Growth and Design, American Chemical Society, 2018, 18 (12), pp.7426-7434. ⟨10.1021/acs.cgd.8b01114⟩. ⟨hal-01972320⟩
  • Amandine Boulmier, Antoine Vacher, Dejin Zang, Shu Yang, Ali Saad, et al.. Anderson-Type Polyoxometalates Functionalized by Tetrathiafulvalene Groups Synthesis, Electrochemical Studies, and NLO Properties. Inorganic Chemistry, American Chemical Society, 2018, 57 (7), pp.3742-3752. ⟨10.1021/acs.inorgchem.7b02976⟩. ⟨hal-01771515⟩
  • Shuangshuang Zhang, Rongji Liu, Shiwen Li, Anne Dolbecq, Pierre Mialane, et al.. Simple and efficient polyoxomolybdate-mediated synthesis of novel graphene and metal nanohybrids for versatile applications. Journal of Colloid and Interface Science, Elsevier, 2018, 514, pp.507-516. ⟨10.1016/j.jcis.2017.12.039⟩. ⟨hal-02335660⟩
  • Shuangshuang Zhang, Olivier Oms, Long Hao, Rongji Liu, Meng Wang, et al.. High Oxygen Reduction Reaction Performances of Cathode Materials Combining Polyoxometalates, Coordination Complexes, and Carboneous Supports. ACS Applied Materials & Interfaces, Washington, D.C. : American Chemical Society, 2017, 9 (44), pp.38486-38498. ⟨10.1021/acsami.7b10989⟩. ⟨hal-02336638⟩
  • Irene Bazzan, Andrea Volpe, Anne Dolbecq, Mirco Natali, Andrea Sartorel, et al.. Cobalt based water oxidation catalysis with photogenerated Ru(bpy) 3 3+ : Different kinetics and competent species starting from a molecular polyoxometalate and metal oxide nanoparticles capped with a bisphosphonate alendronate pendant. Catalysis Today, Elsevier, 2017, 290, pp.39-50. ⟨10.1016/j.cattod.2017.03.027⟩. ⟨hal-02336697⟩
  • Amandine Boulmier, Xinxin Feng, Olivier Oms, Pierre Mialane, Eric Rivière, et al.. Anticancer Activity of Polyoxometalate-Bisphosphonate Complexes: Synthesis, Characterization, In Vitro and In Vivo Results. Inorganic Chemistry, American Chemical Society, 2017, 56 (13), pp.7558-7565. ⟨10.1021/acs.inorgchem.7b01114⟩. ⟨hal-02336688⟩
  • Irene Bazzan, Patricia Bolle, Olivier Oms, Hanène Salmi, Nadine Aubry-Barroca, et al.. The design of new photochromic polymers incorporating covalently or ionically linked spiropyran/polyoxometalate hybrids. Journal of Materials Chemistry C, Royal Society of Chemistry, 2017, 5 (25), pp.6343 - 6351. ⟨10.1039/c7tc01296a⟩. ⟨hal-01623121⟩
  • William Salomon, Grégoire Paille, Maria Gomez-Mingot, Pierre Mialane, Jérôme Marrot, et al.. Effect of Cations on the Structure and Electrocatalytic Response of Polyoxometalate-Based Coordination Polymers. Crystal Growth and Design, American Chemical Society, 2017, ⟨10.1021/acs.cgd.6b01600⟩. ⟨hal-01494047⟩
  • Arnaud Parrot, Aurélie Bernard, Aurélie Jacquart, Stefano Artin Serapian, Carles Bo, et al.. Photochromism and Dual-Color Fluorescence in a Polyoxometalate-Benzospiropyran Molecular Switch. Angewandte Chemie, Wiley-VCH Verlag, 2017, 129 (17), pp.4950-4954. ⟨10.1002/ange.201701860⟩. ⟨hal-01511158⟩
  • Yang Chu, Saad Ali, Panchao Yin, Jiayingzi Wu, Olivier Oms, et al.. Light- and Solvent-Controlled Self-Assembly Behavior of Spiropyran-Polyoxometalate-Alkyl Hybrid Molecules. Chemistry - A European Journal, Wiley-VCH Verlag, 2016, 22 (33), pp.11756-11762. ⟨10.1002/chem.201601173⟩. ⟨hal-02338891⟩
  • William Salomon, Yanhua Lan, Eric Rivière, Shu Yang, Catherine Roch-Marchal, et al.. Single-Molecule Magnet Behavior of Individual Polyoxometalate Molecules Incorporated within Biopolymer or Metal-Organic Framework Matrices. Chemistry - A European Journal, Wiley-VCH Verlag, 2016, 22 (19), pp.6564-6574. ⟨10.1002/chem.201600202⟩. ⟨hal-01971523⟩
  • Olivier Oms, Tarik Benali, Jérôme Marrot, Pierre Mialane, Marin Puget, et al.. Fully Oxidized and Mixed-Valent Polyoxomolybdates Structured by Bisphosphonates with Pendant Pyridine Groups: Synthesis, Structure and Photochromic Properties. Inorganics, MDPI AG, 2015, 3 (4), pp.279 - 294. ⟨10.3390/inorganics3020279⟩. ⟨hal-01725596⟩
  • Ali Saad, Wei Zhu, Guillaume Rousseau, Pierre Mialane, Jérôme Marrot, et al.. Polyoxomolybdate Bisphosphonate Heterometallic Complexes: Synthesis, Structure, and Activity on a Breast Cancer Cell Line. Chemistry - A European Journal, Wiley-VCH Verlag, 2015, 21 (29), pp.10537 - 10547. ⟨10.1002/chem.201406565⟩. ⟨hal-01725571⟩
  • Ali Saad, Olivier Oms, Anne Dolbecq, Clotilde Menet, Remi Dessapt, et al.. A high fatigue resistant, photoswitchable fluorescent spiropyran–polyoxometalate–BODIPY single-molecule. Chemical Communications, Royal Society of Chemistry, 2015, 51 (89), pp.16088 - 16091. ⟨10.1039/c5cc06217a⟩. ⟨hal-01725881⟩
  • Clotilde Menet, Hélène Serier-Brault, Olivier Oms, Anne Dolbecq, Jérôme Marrot, et al.. Influence of electronic vs. steric factors on the solid-state photochromic performances of new polyoxometalate/spirooxazine and spiropyran hybrid materials. RSC Advances, Royal Society of Chemistry, 2015, 5 (97), pp.79635 - 79643. ⟨10.1039/c5ra15860e⟩. ⟨hal-01725972⟩
  • Hani El Moll, Guillaume Rousseau, Anne Dolbecq, Olivier Oms, Jerome Marrot, et al.. Properties of a Tunable Multinuclear Nickel Polyoxotungstate Platform. Chemistry - A European Journal, Wiley-VCH Verlag, 2013, 19 (21), pp.6753-6765. ⟨hal-00967243⟩
  • Arnaud Parrot, Guillaume Izzet, Lise-Marie Chamoreau, Anna Proust, Olivier Oms, et al.. Photochromic Properties of Polyoxotungstates with Grafted Spiropyran Molecules. Inorganic Chemistry, American Chemical Society, 2013, 52 (19), pp.11156. ⟨10.1021/ic401380a⟩. ⟨hal-00980500⟩
  • Khadija Hakouk, Olivier Oms, Anne Dolbecq, Hani El Moll, Jerome Marrot, et al.. Sulfonium Polyoxometalates: A New Class of Solid-State Photochromic Hybrid Organic-Inorganic Materials. Inorganic Chemistry, American Chemical Society, 2013, 52 (2), pp.555. ⟨10.1021/ic302477p⟩. ⟨hal-00981693⟩
  • Olivier Oms, Khadija Hakouk, Remi Dessapt, Philippe Deniard, Stéphane Jobic, et al.. Photo- and electrochromic properties of covalently connected symmetrical and unsymmetrical spiropyran-polyoxometalate dyads. Chemical Communications, Royal Society of Chemistry, 2012, 48 (99), pp.12103. ⟨10.1039/c2cc35376h⟩. ⟨hal-00865896⟩
  • Hani El Moll, Anne Dolbecq, Israel Martyr Mbomekalle, Jerome Marrot, Philippe Deniard, et al.. Tuning the Photochromic Properties of Molybdenum Bisphosphonate Polyoxometalates. Inorganic Chemistry, American Chemical Society, 2012, 51 (4), pp.2291. ⟨10.1021/ic202299d⟩. ⟨hal-00866364⟩
  • Hani El Moll, Anne Dolbecq, Jérôme Marrot, Guillaume Rousseau, Mohamed Haouas, et al.. A Stable Hybrid Bisphosphonate Polyoxometalate Single-Molecule Magnet. Chemistry - A European Journal, Wiley-VCH Verlag, 2012, 18 (13), pp.3845-3849. ⟨hal-00974956⟩
  • Hani El Moll, Wei Zhu, Eric Oldfield, L. Marleny Rodriguez-Albelo, Pierre Mialane, et al.. Polyoxometalates Functionalized by Bisphosphonate Ligands: Synthesis, Structural, Magnetic, and Spectroscopic Characterizations and Activity on Tumor Cell Lines. Inorganic Chemistry, American Chemical Society, 2012, 51 (14), pp.7921 - 7931. ⟨10.1021/ic3010079⟩. ⟨hal-01654928⟩
  • Jean-Daniel Compain, Pierre Mialane, Anne Dolbecq, Israël Martyr Mbomekallé, Jérôme Marrot, et al.. Structural, Magnetic, EPR, and Electrochemical Characterizations of a Spin-Frustrated Trinuclear Cr III Polyoxometalate and Study of Its Reactivity with Lanthanum Cations. Inorganic Chemistry, American Chemical Society, 2010, 49 (6), pp.2851 - 2858. ⟨10.1021/ic902341w⟩. ⟨hal-01658605⟩
  • J. Compain, Anne Dolbecq, I.M. Mbomekalle, Jerôme Marrot, Francis Sécheresse, et al.. Iron Polyoxometalate Single-Molecule Magnets. Angewandte Chemie International Edition, Wiley-VCH Verlag, 2009, 48 (17), pp.3077-3081. ⟨hal-00982380⟩
  • Anna Giusti, Gaëlle Charron, Sandra Mazerat, Jd Compain, Pierre Mialane, et al.. Magnetic Bistability of Individual Single-Molecule Magnets Grafted on Single-Wall Carbon Nanotubes. Angewandte Chemie International Edition, Wiley-VCH Verlag, 2009, 48 (27), pp.4949-4952. ⟨hal-00982383⟩
  • Céline Pichon, Anne Dolbecq, Pierre Mialane, Jérôme Marrot, Eric Rivière, et al.. Fe2 and Fe4 Clusters Encapsulated in Vacant Polyoxotungstates: Hydrothermal Synthesis, Magnetic and Electrochemical Properties, and DFT Calculations. Chemistry - A European Journal, Wiley-VCH Verlag, 2008, 14 (10), pp.3189 - 3199. ⟨10.1002/chem.200700896⟩. ⟨hal-01889642⟩
  • Laurent Lisnard, Pierre Mialane, Anne Dolbecq, Jérôme Marrot, Juan-Modesto Clemente-Juan, et al.. Effect of Cyanato, Azido, Carboxylato, and Carbonato Ligands on the Formation of Cobalt(II) Polyoxometalates: Characterization, Magnetic, and Electrochemical Studies of Multinuclear Cobalt Clusters. Chemistry - A European Journal, Wiley-VCH Verlag, 2007, 13, pp.3525-3536. ⟨hal-00143918⟩
  • Anne Dolbecq, Laurent Lisnard, Pierre Mialane, Jérôme Marrot, Marc Bénard, et al.. Synthesis and characterization of octa- and hexanuclear polyoxomolybdate wheels: Role of the inorganic Template and of the counterion. Inorganic Chemistry, American Chemical Society, 2006, 45(15), pp.5898-5910. ⟨hal-00104112⟩
  • Pierre Mialane, Anne Dolbecq, Francis Sécheresse. Functionalization of polyoxometalate by carboxylato and azido ligands: macromolecular complexes and extended compounds. Chemical Communications, Royal Society of Chemistry, 2006, pp.3477-3485. ⟨hal-00104103⟩
  • Pierre Mialane, Carole Duboc, Jerome Marrot, Eric Riviere, Anne Dolbecq, et al.. Structural and magnetic properties of MnIII and CuII tetranuclear azido polyoxometalate complexes: multifrequency high-field EPR spectroscopy of Cu4 clusters with S = 1 and S = 2 ground states. Chemistry - A European Journal, Wiley-VCH Verlag, 2006, 12, pp.1950-1959. ⟨hal-00022802⟩
  • Pierre Mialane, Carole Duboc, Jérôme Marrot, Eric Riviere, Anne Dolbecq, et al.. Structural and magnetic properties of Mn-III and Cu-II tetranuclear azido polyoxometalate complexes: Multifrequency high-field EPR spectroscopy of Cu-4 clusters with S=1 and S=2 ground states. Chemistry - A European Journal, Wiley-VCH Verlag, 2006, 12 (7), pp.1950-1959. ⟨hal-00104055⟩
  • Laurent Lisnard, Anne Dolbecq, Pierre Mialane, Jérôme Marrot, Eric Rivière, et al.. Synthesis and characterizations of cyclic octanuclear mixed-valence vanadium( iv , v ) clusters with polyoxometalate counterions. Dalton Transactions, Royal Society of Chemistry, 2006, pp.5141 - 5148. ⟨10.1039/b610735d⟩. ⟨hal-01906900⟩
  • Laurent Lisnard, Anne Dolbecq, Pierre Mialane, Jérôme Marrot, Epiphane Codjovi, et al.. Molecular and multidimensional polyoxotungstates functionalized by {Cu(bpy)}2+ groups. Dalton Transactions, Royal Society of Chemistry, 2005, pp.3913. ⟨10.1039/b507124k⟩. ⟨hal-02326785⟩
  • Laurent Lisnard, Anne Dolbecq, Pierre Mialane, Jérôme Marrot, Francis Sécheresse. Hydrothermal syntheses and characterizations of 0D to 3D polyoxotungstates linked by copper ions. Inorganica Chimica Acta Reviews, Elsevier, 2004, 357 (3), pp.845-852. ⟨10.1016/j.ica.2003.09.007⟩. ⟨hal-02326805⟩
  • Charlotte Du Peloux, Anne Dolbecq, Philippe Barboux, Guillaume Laurent, Jérôme Marrot, et al.. Octanuclear Oxothiomolybdate(V) Rings: Structure and Ionic-Conducting Properties. Chemistry - A European Journal, Wiley-VCH Verlag, 2004, 10 (12), pp.3026-3032. ⟨10.1002/chem.200400068⟩. ⟨hal-02050133⟩
  • Anne Dolbecq, Pierre Mialane, Laurent Lisnard, Jérôme Marrot, Francis Sécheresse. Hybrid Organic–Inorganic 1D and 2D Frameworks with -Keggin Polyoxomolybdates as Building Blocks. Chemistry - A European Journal, Wiley-VCH Verlag, 2003, 9 (12), pp.2914-2920. ⟨10.1002/chem.200204670⟩. ⟨hal-02326208⟩
  • Laurent Lisnard, Pierre Mialane, Anne Dolbecq, Jérôme Marrot, Francis Sécheresse. A tetranuclear oxomolybdenum(V) complex with bridging squarate ligands, [MoV4O8(OH)2(H2O)2(C4O4)2]2−. Inorganic Chemistry Communications, Elsevier, 2003, 6 (5), pp.503-505. ⟨10.1016/S1387-7003(03)00028-5⟩. ⟨hal-02326217⟩
  • Pierre Mialane, Anne Dolbecq, Laurent Lisnard, Alain Mallard, Jérôme Marrot, et al.. [e-PMo12O36(OH)4{La(H2O)4}4]5+: The First e-PMo12O40 Keggin Ion and Its Association with the Two-Electron-Reduced α-PMo12O40 Isomer. Angewandte Chemie International Edition, Wiley-VCH Verlag, 2002, 41 (13), pp.2398. ⟨10.1002/1521-3773(20020703)41:13<2398::AID-ANIE2398>3.0.CO;2-A⟩. ⟨hal-02326189⟩
  • Pierre Mialane, Anne Dolbecq, Geoffrey Costaz, Laurent Lisnard, Jérôme Marrot, et al.. Synthesis and structure of the first dinuclear lanthanide oxalato complexes [{MoV2O4(C2O4)2(H2O)2}2{(Ln2(H2O)4)2(C2O4)}]·7H2O (Ln=La3+,Ce3+). Inorganic Chemistry Communications, Elsevier, 2002, 5 (9), pp.702-705. ⟨10.1016/S1387-7003(02)00541-5⟩. ⟨hal-02326161⟩