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41

Prof. Alexandre CHAGNES

Directeur des Partenariats Industriels (http://ensg.univ-lorraine.fr)

 

Directeur Scientifique du Labex Ressources21 (http://ressources21.univ-lorraine.fr)

 

École Nationale Supérieure de Géologie (ENSG) - Géoressources (UMR CNRS 7359)
2 rue du Doyen Marcel Roubault - BP 10162 - 54505 Vandoeuvre-les Nancy Cedex (France)

 

Google Scholar : https://scholar.google.fr/citations?user=YEgejnQAAAAJ&hl=fr

 Research Gate : http://www.researchgate.net/profile/Alexandre_Chagnes2

 

ACTIVITES DE RECHERCHE

Procédés hydrométallurgiques, chimie des solutions, thermodynamique, électrochimie, batteries Li-ion. 

123 articles dans des journaux à comité de lecture dont 18 articles dans des actes de congrès à comité de lecture, 6 livres, 8 chapitres de livre, 135 conférences dont 59 conférences invitées, 41 présentations par affiches, 2 brevets.

ENSEIGNEMENT

Thermodynamique, électrochimie, chimie des solutions, physicochimie des procédés hydrométallurgiques. 

DIPLOMES-FORMATION

HDR

Université d’Orsay, 24 Septembre 2012. La physicochimie au service des ressources et de l’énergie.

Doctorat

Université de Tours, France (chimie-physique), 16 Septembre 2002. 

Etude thermodynamique et électrochimique d’électrolytes organiques pour les batteries lithium-ion.

 

  

EMPLOIS

2016-…

Professeur des Universités, École Nationale Supérieure de Géologie (Université de Lorraine) – titulaire de la Prime d’Encadrement Doctorale (PEDR) depuis Septembre 2014.

Procédés hydrométallurgiques

2005-2016       

 

 

Maître de Conférences, Chimie ParisTech, Ecole Nationale Supérieure de Chimie Paris (France). 

- Métallurgie extractive : Procédés de purification par voie hydrométallurgique.

- Batteries lithium-ion : Electrolytes et interface électrode/électrolyte.

2004-2005    

Chercheur post-doctoral, Commissariat à l’Energie Atomique, Saclay (France).

Chimie des solutions dans les réacteurs à eau pressurisée.

2003-2004    

Attaché Temporaire d’Enseignement et de Recherche, Laboratoire de Physicochimie des Interfaces et des Milieux Réactionnels, Université de Tours (France).

Electrochimie et thermodynamique des liquides ioniques à basse température.

2002-2003    

Chercheur postdoctoral, Centre de Recherche en Electrochimie et Electrocatalyse, Université de Sherbrooke (Québec, Canada).

Matériaux pour l’électrocatalyse.

1999-2002

Doctorant,Laboratoire de Physicochimie des Interfaces et des Milieux Réactionnels, Université de Tours (France).

Electrochimie et chimie des solutions pour les batteries lithium-ion.

 

 

Journal articles33 documents

  • Rodolfomarin Rivera, Alexandre Chagnes, Michel Cathelineau, Marie-Christine Boiron. Conditioning of poultry manure ash for subsequent phosphorous separation and assessment for a process design. Sustainable Materials and Technologies, Elsevier, 2022, 31, pp.e00377. ⟨10.1016/j.susmat.2021.e00377⟩. ⟨hal-03489461⟩
  • Soumaya Gmar, Alexandre Chagnes, Florence Lutin, Laurence Muhr. Application of Electrodialysis for the Selective Lithium Extraction towards Cobalt, Nickel and Manganese from Leach Solutions Containing High Divalent Cations/Li Ratio. Construction & Demolition Recycling, CDR Editorial & Sales Office, 2022, 7, ⟨10.3390/recycling7020014⟩. ⟨hal-03594578⟩
  • Wen Xuan, Alexandre Chagnes, Xiong Xiao, Richard Olsson, Kerstin Forsberg. Antisolvent Precipitation for Metal Recovery from Citric Acid Solution in Recycling of NMC Cathode Materials. Metals, MDPI, 2022, 12 (4), pp.607. ⟨10.3390/met12040607⟩. ⟨hal-03627309⟩
  • Lucas Mangold, Hubert Halleux, Sébastien Leclerc, Aurélien Moncomble, Gérard Cote, et al.. New insights for titanium(iv) speciation in acidic media based on UV-visible and 31P NMR spectroscopies and molecular modeling. RSC Advances, Royal Society of Chemistry, 2021, 11 (43), pp.27059 - 27073. ⟨10.1039/d1ra04284j⟩. ⟨hal-03324044⟩
  • Wen Xuan, Antônio de Souza Braga, Chloé Korbel, Alexandre Chagnes. New insights in the leaching kinetics of cathodic materials in acidic chloride media for lithium-ion battery recycling. Hydrometallurgy, Elsevier, 2021, 204, pp.105705. ⟨10.1016/j.hydromet.2021.105705⟩. ⟨hal-03297024⟩
  • Allen yushark Fosu, Ndue Kanari, Danièle Bartier, Harrison Hodge, James Vaughan, et al.. Physico-Chemical Characteristics of Spodumene Concentrate and Its Thermal Transformations. Materials, MDPI, 2021, 14 (23), pp.7423. ⟨10.3390/ma14237423⟩. ⟨hal-03465518⟩
  • Olga Chernoburova, Alexandre Chagnes. The Future of Scandium Recovery from Wastes. Materials Proceedings, MDPI, 2021, 5 (1), pp.55. ⟨10.3390/materproc2021005055⟩. ⟨hal-03465544⟩
  • Soumaya Gmar, Fabrice Mutelet, Alexandre Chagnes. Effect of the Addition of Amine in Organophosphorus Compounds on Molecular Structuration of Ionic Liquids–Application to Solvent Extraction. Molecules, MDPI, 2020, 25 (11), pp.2584. ⟨10.3390/molecules25112584⟩. ⟨hal-02922253⟩
  • Allen yushark Fosu, Ndue Kanari, James Vaughan, Alexandre Chagnes. Literature Review and Thermodynamic Modelling of Roasting Processes for Lithium Extraction from Spodumene. Metals, MDPI, 2020, 10 (10), pp.1312. ⟨10.3390/met10101312⟩. ⟨hal-02953994⟩
  • Sushanta Kumar, Maryam Kargar Razi, Mathieu Beuscher, Alexandre Chagnes. Recovery of Metal Values from Ni-Cd Cake Waste Residue of an Iranian Zinc Plant by Hydrometallurgical Route. Metals, MDPI, 2020, 10 (5), ⟨10.3390/met10050655⟩. ⟨hal-02922251⟩
  • Agathe Hubau, Michel Minier, Alexandre Chagnes, Catherine Joulian, Charline Silvente, et al.. Recovery of metals in a double-stage continuous bioreactor for acidic bioleaching of printed circuit boards (PCBs). Separation and Purification Technology, Elsevier, 2020, 238, pp.116481. ⟨10.1016/j.seppur.2019.116481⟩. ⟨hal-02431903⟩
  • Benjamin Flamme, Jolanta Światowska, Mansour Haddad, Phannarath Phansavath, Virginie Ratovelomanana-Vidal, et al.. Sulfone Based-Electrolytes for Lithium-Ion Batteries: Cycling Performances and Passivation Layer Quality of Graphite and LiNi 1/3 Mn 1/3 Co 1/3 O 2 Electrodes. Journal of The Electrochemical Society, Electrochemical Society, 2020, 167 (7), pp.070508. ⟨10.1149/1945-7111/ab63c3⟩. ⟨hal-02436737⟩
  • Benjamin Flamme, Jolanta Swiatowska, Mansour Haddad, Phannarath Phansavath, Virginie Ratovelomanana-Vidal, et al.. Sulfone Based-Electrolytes for Lithium-Ion Batteries: Cycling Performances and Passivation Layer Quality of Graphite and LiNi 1/3 Mn 1/3 Co 1/3 O 2 Electrodes. Journal of The Electrochemical Society, Electrochemical Society, 2020. ⟨hal-03009869⟩
  • Alexandre Chagnes. Simulation of Solvent Extraction Flowsheets by a Global Model Combining Physicochemical and Engineering Approaches-Application to Cobalt(II) Extraction by D2EHPA. Solvent Extraction and Ion Exchange, Taylor & Francis, 2020, 38 (1), pp.3-13. ⟨10.1080/07366299.2019.1691135⟩. ⟨hal-02424027v2⟩
  • Agathe Hubau, Alexandre Chagnes, Michel Minier, Solène Touzé, Simon Chapron, et al.. Recycling-oriented methodology to sample and characterize the metal composition of waste Printed Circuit Boards. Waste Management, Elsevier, 2019, 91, pp.62-71. ⟨10.1016/j.wasman.2019.04.041⟩. ⟨hal-02161758⟩
  • Gauthier J.-P. Deblonde, David Bengio, Denis Beltrami, Sarah Bélair, Gérard Cote, et al.. Niobium and tantalum processing in oxalic-nitric media: Nb2O5·nH2O and Ta2O5·nH2O precipitation with oxalates and nitrates recycling. Separation and Purification Technology, Elsevier, 2019, 226, pp.209-217. ⟨10.1016/j.seppur.2019.05.087⟩. ⟨hal-02182964⟩
  • Gauthier J.-P. Deblonde, David Bengio, Denis Beltrami, Sarah Bélair, Gérard Cote, et al.. A fluoride-free liquid-liquid extraction process for the recovery and separation of niobium and tantalum from alkaline leach solutions. Separation and Purification Technology, Elsevier, 2019, 215, pp.634-643. ⟨10.1016/j.seppur.2019.01.052⟩. ⟨hal-02182966⟩
  • Agathe Hubau, Alexandre Chagnes, Michel Minier, Solène Touzé, Simon Chapron, et al.. Recycling-oriented methodology to sample and characterize the metal composition of waste Printed Circuit Boards. Waste Management, Elsevier, 2019, 91, pp.62-71. ⟨10.1016/j.wasman.2019.04.041⟩. ⟨hal-02182965⟩
  • Wen Xuan, Akira Otsuki, Alexandre Chagnes. Investigation of the leaching mechanism of NMC 811 (LiNi 0.8 Mn 0.1 Co 0.1 O 2 ) by hydrochloric acid for recycling lithium ion battery cathodes. RSC Advances, Royal Society of Chemistry, 2019, ⟨10.1039/c9ra06686a⟩. ⟨hal-02383642⟩
  • Alexandre Chagnes. Advances in Hydrometallurgy. Metals, MDPI, 2019, 9 (2), pp.211. ⟨10.3390/met9020211⟩. ⟨hal-02182967⟩
  • Kateryna Omelchuk, Moncef Stambouli, Alexandre Chagnes. Investigation of aggregation and acid dissociation of new cationic exchangers for liquid-liquid extraction. Journal of Molecular Liquids, Elsevier, 2018, 262, pp.111-118. ⟨10.1016/j.molliq.2018.04.082⟩. ⟨hal-01813755⟩
  • Agathe Hubau, Michel Minier, Alexandre Chagnes, Catherine Joulian, Cédric Perez, et al.. Continuous production of a biogenic ferric iron lixiviant for the bioleaching of printed circuit boards (PCBs). Hydrometallurgy, Elsevier, 2018, 180, pp.180-191. ⟨10.1016/j.hydromet.2018.07.001⟩. ⟨hal-02182968⟩
  • Kateryna Omelchuk, Alexandre Chagnes. New cationic exchangers for the recovery of cobalt(II), nickel(II) and manganese(II) from acidic chloride solutions: Modelling of extraction curves. Hydrometallurgy, Elsevier, 2018, 180, pp.96-103. ⟨10.1016/j.hydromet.2018.07.003⟩. ⟨hal-02182969⟩
  • Alexandre Chagnes, Gérard Cote. Chemical Degradation of a Mixture of tri-n-Octylamine and 1-Tridecanol in the Presence of Chromium(VI) in Acidic Sulfate Media. Metals, MDPI, 2018, 8 (1), pp.57. ⟨10.3390/met8010057⟩. ⟨hal-02182973⟩
  • Bénédicte Simon, Christine Bouyer, Stéphanie de Sio, Claude Berthon, Nathalie Boubals, et al.. Characterization of palladium species after γ-irradiation of a TBP–alkane–Pd(NO 3 ) 2 system. RSC Advances, Royal Society of Chemistry, 2018, 8 (38), pp.21513-21527. ⟨10.1039/C8RA02695E⟩. ⟨hal-02182974⟩
  • Benjamin Flamme, Mansour Haddad, Phannarath Phansavath, Virginie Ratovelomanana-Vidal, Alexandre Chagnes. Anodic Stability of New Sulfone-Based Electrolytes for Lithium-Ion Batteries. ChemElectroChem, Weinheim : Wiley-VCH, 2018, 5 (16), pp.2279-2287. ⟨10.1002/celc.201701343⟩. ⟨hal-02182970⟩
  • Alexandre Chagnes. Les sels de lithium, à la base du stockage d'électricité. Géosciences, BRGM, 2018, Le sel, "aux confins de la terre et de l'eau", pp.72. ⟨hal-02265130⟩
  • Guangze yang, Véronique Pointeau, Etienne Tevissen, Alexandre Chagnes. A review on clogging of recirculating steam generators in Pressurized-Water Reactors. Progress in Nuclear Energy, Elsevier, 2017, 97, pp.182-196. ⟨10.1016/j.pnucene.2017.01.010⟩. ⟨cea-02388689⟩
  • Gauthier J.-P. Deblonde, Cristina Coelho-Diogo, Alexandre Chagnes, Gérard Cote, Mark E. Smith, et al.. Multinuclear Solid-State NMR Investigation of Hexaniobate and Hexatantalate Compounds. Inorganic Chemistry, American Chemical Society, 2016, 55 (12), pp.5946 - 5956. ⟨10.1021/acs.inorgchem.6b00345⟩. ⟨hal-01429965⟩
  • Rafael M. Rios-Vera, Juliette Sirieix-Plénet, Laurent Gaillon, Cécile Rizzi, Mario Ávila-Rodríguez, et al.. Physicochemical properties of novel cholinium ionic liquids for the recovery of silver from nitrate media. RSC Advances, Royal Society of Chemistry, 2015, 5 (95), pp.78268 - 78277. ⟨10.1039/c5ra14101j⟩. ⟨hal-01519102⟩
  • Denis Beltrami, Florence F. Mercier-Bion, Gérard Cote, Hamid Mokhtari, Bruno Courtaud, et al.. Investigation of the speciation of uranium(VI) in concentrated phosphoric acid and in synergistic extraction systems by time-resolved laser-induced fluorescence spectroscopy (TRLFS). Journal of Molecular Liquids, Elsevier, 2014, 190, pp.42-49. ⟨10.1016/j.molliq.2013.10.013⟩. ⟨hal-01157709⟩
  • Catarina Pereira-Nabais, Jolanta Swiatowska, Alexandre Chagnes, Francois Ozanam, Aurelien Gohier, et al.. Interphase chemistry of Si electrodes used as anodes in Li-ion batteries. Applied Surface Science, Elsevier, 2013, 266, pp.5-16. ⟨10.1016/j.apsusc.2012.10.165⟩. ⟨hal-00793814⟩
  • Antonio Prestianni, Laurent Joubert, Alexandre Chagnes, Gerard Cote, Marie-Noelle Ohnet, et al.. IR Fingerprints of U(VI) Nitrate Monoamides Complexes: A Joint Experimental and Theoretical Study. Journal of Physical Chemistry A, American Chemical Society, 2010, 114 (40), pp.10878-10884. ⟨10.1021/JP106467P⟩. ⟨cea-03095730⟩

Conference papers5 documents

  • Lucas Mangold, Hubert Halleux, Aurélien Moncomble, Gérard Cote, Alexandre Chagnes. The speciation of titanium(IV) in concentrated phosphoric acid : A spectroscopical and TD-DFT study.. IUPAC CCCE 2021, Aug 2021, Ottawa (virtual), Canada. ⟨hal-03418105⟩
  • Agathe Hubau, Alexandre Chagnes, Michel Minier, Anne-Gwenaëlle Guezennec. Metal recovery from printed circuit boards (PCBs) by acidophilic bioleaching. International Biohydrometallurgy Symposium - IBS 2019, Oct 2019, Fukuoka, Japan. ⟨hal-02274137⟩
  • Alexandre Chagnes. Recent Advances in Hydrometallurgy for the Development of a Sustainable Production of Lithium-Ion Batteries. ALTA 2019 - Lithium processing conference, May 2019, Perth, Australia. ⟨hal-02270375⟩
  • Alexandre Chagnes, Kateryna Omelchuk. Liquid-Liquid Extraction of Cobalt(II), Nickel(II) and Manganese(II) from Acidic Chloride Media. Extraction 2018: Proceedings of the First Global Conference on Extractive Metallurgy, Aug 2018, Ottawa, Canada. ⟨hal-02270376⟩
  • Kateryna Omelchuk, Moncef Stambouli, Alexandre Chagnes. Diphasic acid-basic properties of new organophosphorus extractants. The 21st International Solvent Exctraction Conference - ISEC 2017, Nov 2017, Miyazaki, Japan. ⟨hal-01814007⟩

Directions of work or proceedings1 document

  • Alexandre Chagnes. Proceedings of the First Global Conference on Extractive Metallurgy CO-EDITORS. 2019. ⟨hal-02265132⟩

Theses1 document

  • Alexandre Chagnes. PROPRIÉTÉS DE TRANSPORT DANS LES ÉLECTROLYTES CONCENTRÉS À BASE DE γ-BUTYROLACTONE. APPLICATION AUX ACCUMULATEURS RECHARGEABLES AU LITHIUM. . Autre. Université François Rabelais - Tours; Ecole nationale superieure agronomique de montpellier - AGRO M, 2002. Français. ⟨tel-00009718⟩

Habilitation à diriger des recherches1 document

  • Alexandre Chagnes. La physicochimie au service des Ressources et de l'Energie. Chimie théorique et/ou physique. Université d'Orsay, 2012. ⟨tel-02265239⟩